Er3+/Yb3+共掺杂磷酸盐微晶玻璃的光谱性质

王睿; 韩霈泽; 于晓晨; 王垒; 骆兰军; 宋峰

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Er³⁺/Yb³⁺共掺杂磷酸盐微晶玻璃的光谱性质

论文 | 更新时间：2020-08-12

- Er³⁺/Yb³⁺共掺杂磷酸盐微晶玻璃的光谱性质
- Properties of Er³⁺/Yb³⁺ Co-doped Phosphate Glass-ceramics
- 发光学报 2010年31卷第6期页码：800-805
- 作者机构：
  
  南开大学物理学院光子学中心天津,300071
- 作者简介：
- 基金信息：
  
  国家自然科学基金(60778038)();国家基础科学人才培养科学基金(J0730315)();国家大学生创新性实验计划(NK0714)资助项目()
- DOI：
  中图分类号： O482.31
- 收稿日期：2009-10-13，
  
  修回日期：2009-12-18，
  
  网络出版日期：2010-11-22，
  
  纸质出版日期：2010-11-22
- 稿件说明：
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王睿, 韩霈泽, 于晓晨, 王垒, 骆兰军, 宋峰. Er3+/Yb3+共掺杂磷酸盐微晶玻璃的光谱性质[J]. 发光学报, 2010,31(6): 800-805

WANG Rui, HAN Pei-ze, YU Xiao-chen, WANG Lei, LUO Lan-jun, SONG Feng. Properties of Er3+/Yb3+ Co-doped Phosphate Glass-ceramics[J]. Chinese Journal of Luminescence, 2010,31(6): 800-805
王睿, 韩霈泽, 于晓晨, 王垒, 骆兰军, 宋峰. Er3+/Yb3+共掺杂磷酸盐微晶玻璃的光谱性质[J]. 发光学报, 2010,31(6): 800-805 DOI：

WANG Rui, HAN Pei-ze, YU Xiao-chen, WANG Lei, LUO Lan-jun, SONG Feng. Properties of Er3+/Yb3+ Co-doped Phosphate Glass-ceramics[J]. Chinese Journal of Luminescence, 2010,31(6): 800-805 DOI：

摘要

采用高温熔融法生长了Er

/Yb

共掺杂的磷酸盐微晶玻璃

测量了微晶玻璃室温下的吸收光谱。由此吸收谱

根据Judd-Ofelt理论

计算了Er

/Yb

共掺杂磷酸盐微晶玻璃的强度参数、自发辐射几率、荧光分支比等光谱参数

得到了吸收截面曲线

并根据McCumber理论得到1540nm附近的积分发射截面。样品的强度参数为

=6.3310

-20

=1.4110

-20

=1.0910

-20

。1540nm对应的积分发射截面峰值为1.810

-20

。另外

还测量了Er

/Yb

共掺杂磷酸盐微晶玻璃在980nm激发下的上转换光谱

讨论了Er

/Yb

共掺杂磷酸盐微晶玻璃的上转换发光和能量传递过程。

Abstract

/Yb

co-doped phosphate glass-ceramics have been fabricated and characterized

the formation of Er(PO

)

and Yb(PO

)

nanocrystals were studied using X-ray diffraction. The intensity parameters

the spontaneous radiative transition probabilities

the branching ratios

and the radiative lifetimes of Er

in glass ceramics were calculated based on the Judd-Ofelt theory.For Er

13/2

15/2

transition

lifetime is 8.625 8 ms.Strength parameters are

=6.3310

-20

=1.4110

-20

=1.0910

-20

.According to McCumber theory

we calculated the stimulated emission cross section

the number is 3.610

-21

.We also studied the fluorescence properties of crystals

and the crystal has been pumped up in laser under the green fluorescence conversion.

关键词

Keywords

references

Yu X C, Song F, Wang W T, et al. Comparison of optical parameters and luminescence between Er3+ /Yb3+ codoped phosphate glass ceramics and precursor glasses [J]. J. Appl. Phys., 2008, 104 (11):113105-1-4.[2] Meng J, Zhao L J, Yu H, et al. Luminescent properties in Er-Yb-doped oxyfluoride glass ceramics with a nanocrystal line structure [J]. Acta Phys. Sin.(物理学报), 2005, 54 (3):1442-1446 (in Chinese).[3] Qiao X S, Fan X P, Wang M Q, et al. Spectroscopy properties of Er3+ /Yb3+ co-doped 50SiO2-20Al2O3-30CaF2 glass and glass ceramics [J]. J. Phys.: Condens Matter, 2006, 18 (29):6937-6951.[4] Zheng Z Q, Li X Y, Liu J, et al. Optical properties of Er3+/Yb3+ co-doped transparent PLZT ceramic [J]. Physica B:Condens Matter, 2008, 403 (1):44-49.[5] Liu Z P, Hu L L, Dai S X, et al. Laser properties of Er3+,Yb3+ co-doped erbium phosphate glass pumped by laser diode[J]. Chin. J. Lumin.(发光学报), 2002, 23 (3):238-242 (in Chinese).[6] Zou K S, Lu M, Xiang L B, et al. Yb3+-doped fluoride lead silicate glasses [J]. Acta Photon. Sin.(光子学报), 2008, 37 (12):2504-2507 (in Chinese).[7] Liu Z P, Hu L L, Zhang D B, et al. Judd-Ofelt parameter analysis and spectroscopic properties of Er3+-doped phosphate glasses [J]. Acta Phys. Sin. (物理学报), 2002, 51 (11):2629-2634 (in Chinese).[8] Zou X L, Izumitani T. Spectroscopic properties and mechanisms of excited state absorption and energy transfer upconversion for Er3+-doped glasses [J]. J. Non-Cryst.Solids, 1993, 162 (1-2):68-80.[9] Zhou G, Dai S X, Yu C L, et al. Spectroscopic properties of Er3+,Yb3+ co-doped tellurite glass ceramics containing nanocrystals [J]. J. Chin. Rare Society (中国稀土学报), 2005, 23 (5):518-523 (in Chinese).[10] Li T, Zhang Q Y, Feng Z M, et al. Spectroscopic properties of Er3+-doped alkaline/alkaline-earth metal modified fluorophosphate glasses [J]. Acta Phys. Sin. (物理学报), 2005, 54 (10):4926-4937 (in Chinese).[11] Peng Y, Li S F, Zhang Q Y, et al. Photoluminescence and its physical mechanism of Er/Yb co-doped borate-silicate glass [J]. Acta Phys. Sin. (物理学报), 2007, 56 (12):7286-7294 (in Chinese).

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