
浏览全部资源
扫码关注微信
北京交通大学 光电子技术研究所, 发光与光信息教育部重点实验室
收稿:2011-05-13,
修回:2011-7-21,
网络首发:2011-10-22,
纸质出版:2011-10-22
移动端阅览
鞠长滨, 王永生, 何大伟, 董雪, 梁燕, 宋鹏, 富鸣. 盐酸掺杂聚苯胺薄膜的隐身性能[J]. 发光学报, 2011,32(10): 998-1003
JU Chang-bin, WANG Yong-sheng, HE Da-wei, DONG Xue, LIANG Yan, SONG Peng, FU Ming. Stealthy Property of Polyaniline Film Doped by Hydrochloric Acid[J]. Chinese Journal of Luminescence, 2011,32(10): 998-1003
将本征态聚苯胺的N-甲基吡咯烷酮溶液浇铸在玻璃基板上
烘干脱去基板后得到自支持本征态聚苯胺薄膜
用HCl气体对薄膜进行掺杂
通过控制掺杂时间来控制掺杂浓度。红外反射率测试结果表明:在大气窗口内
掺杂浓度较低时
薄膜的红外反射率随着掺杂浓度的提高而增加;到达一定掺杂浓度后
反射率会随着掺杂浓度的提高有所降低
最终趋于稳定。其中
3~5 μm波段的最高反射率为53.1%
8~14 μm波段的最高反射率为57.6%
两个波段内达到最大反射率时的掺杂程度不相同。膜厚引起的干涉作用对红外反射性能也有一定影响。在所研究的掺杂范围内
聚苯胺薄膜对微波的透射性能良好
在某些波段对微波还有一定的吸收作用。
paper
Shirakawa H, Louis E J, MacDiarmid A G, et al. Synthesis of electrically conducting organic polymers: halogen derivatives of polyacetylene, (CH)x [J]. J. Chem. Soc., Chem. Commun., 1977(16):578-580.[2] Wallace G G, Spinks G M, Kane-Maguire L A P, et al. Conductive Electroactive Polymers: Intelligent Materials Systems (导电活性聚合物-智能材料体系) [M]. The Second Edition, Beijing: Science Press, 2007:7-8.[3] Bhadra S, Khastgir D, Singha N K, et al. Progress in preparation, processing and applications of polyaniline [J]. Prog. Polym. Sci., 2009, 34 (1):783-810.[4] Wan M X. Conducting Polymers with Micro or Nanometer Structure [M]. Beijing: Tsinghua University Press, 2008:16.[5] Schoch K F Jr, Byers W A, Buckley L J. Deposition and characterization of conducting polymer thin films on insulating substrates [J]. Synth. Met., 1995, 72 (1):13-23.[6] Kulkarni V G, Campbell J C, Mathew W R. Transparent conductive coatings [J]. Synth. Met., 1993, 57 (1):3780-3785.[7] Kaneto K, Kaneko M, Min Y, et al. "Artificial muscle": Electromechanical actuators using polyaniline films [J]. Synth. Met., 1995, 71 (1-3):2211-2212.[8] Irimia V M, Fergus J W. Suitability of emeraldine base polyaniline-PVA composite film for carbon dioxide sensing [J]. Synth. Met., 2006, 156 (21-24):1401-1407.[9] Nohria R, Khillan R K, Su Y, et al. Humidity sensor based on ultrathin polyaniline film deposited using layer-by-layer nano-assembly [J]. Sensor Actuat. B-Chem., 2006, 114 (1):218-222.[10] Chen Showan, Chuang Kuenru, Chao Chingian, et al. White-light emission from electroluminescence diode with polyaniline as the emitting layer [J]. Synth. Met., 1996, 82 (3):207-210.[11] Gaponik Nikolai P, Talapin Dmitri V, Rogach Andrey L. A light-emitting device based on a CdTe nanocrystal/polyaniline composite [J]. Phys. Chem. Chem. Phys., 1999, 1 (8):1787-1789.[12] Teng Feng, Zheng Min, Bai Fenglian, et al. Emeraldine base form of polyaniline in organic light emitting diodes as hole-transport materials [J]. Chin. J. Lumin. (发光学报), 2003, 24 (6):588-591 (in Chinese).[13] Stakhira P Y, Vertsimaha Y I, Aksimentyeva O I, et al. Hybrid solar cells based on dispersed InSe-polyaniline composites [J]. Phys. Chem. Solid State, 2005, 6 (1):96-98.[14] Liu Ziran, Zhou Jingran, Xue Hailin, et al. Polyaniline/TiO2 solar cells [J]. Synth. Met., 2006, 156 (9-10):721-723.[15] Saini Parveen, Choudhary Veena, Singh B P, et al. Polyaniline-MWCNT nanocomposites for microwave absorption and EMI shielding [J]. Mater. Chem. Phys., 2009, 113 (2-3):919-926.[16] Bhadra S, Singha N K, Khastgir D. Dielectric properties and EMI shielding efficiency of polyaniline and ethylene 1-octene based semi-conducting composites [J]. Curr. Appl. Phys., 2009, 9 (2):396-403.[17] Liao Haixing, Yu Kexiong, Liu Min. Studies on microwave absorption properties of different proton acid doped polyaniline [J]. Journal of Xiangfan University (襄樊学院学报), 2005, 26 (2):32-35 (in Chinese).[18] Vhanakhande B B, Jadhav S V, Kulkarni D C, et al. Investigations on the microwave properties of electropolymerised polyaniline thin film [J]. Microw. Opt. Techn. Let., 2008, 50 (3):761-766.[19] Jadhav S, Jamadade S, Puri V. Microwave properties of polyaniline thin film coated on alumina //Proceedings of International Conferdence on Microwave:Recent Advances in Microwave Theory and Applications. Jaipur, India: IEEE, 2008:130-131.[20] Zhao Donglin, Zeng Xianwei, Shen Zengmin. Synthesis of carbon nanotube/polyaniline composite nanotube and its microwave permittivity [J]. Acta Physica Sinica (物理学报), 2005, 54 (8):3878-3883 (in Chinese).[21] Wang Zhongzhu, Sun Tao, Li Minquan. IR and microwave absorption properties of conductive polyaniline (PANI)/γ-Fe2O3 nanocomposite [J]. J. Magn. Mater. Devices (磁性材料及器件), 2008, 39 (1):14-17 (in Chinese).[22] Tang Xin, Yang Yuanguang, Surface modification of M-Ba-ferrite powders by polyaniline Towards improving microwave electromagnetic response [J]. Appl. Sur. Sci., 2009, 255 (23):9381-9385.[23] Yang Chunming, Li Haiyin, Xiong Dongbai, et al. Hollow polyaniline/Fe3O4 microsphere composites: Preparation, characterization, and applications in microwave absorption [J]. React. Funct. Polym., 2009, 69 (2):137-144.[24] Chandrasekhar, P, Zay B J, McQueeney T, et al. Conducting Polymer (CP) infrared electrochromics in spacecraft thermal control and military applications [J]. Synth. Met., 2003, 135-136 (1):23-24.[25] Topart P, Hourquebie P. Infrared switching electroemissive devices based on highly conducting polymers [J]. Thin Solid Films, 1999, 352 (1-2):243-248.[26] Lee Kwanghee, Heeger A J, Cao Y. Reflectance spectra of polyaniline [J]. Synth. Met., 1995, 72 (1):25-34.[27] Yuan Tongsuo, Xie Minggui, Song Wenhua, et al. Study of the Influence of different proprotion dopping on the Infrared Reflection Properties of Conducting Polyaniline [J]. Acta Scientiarum Naturalium Universitatis Nankaiensis (Natural Science Edition) (南开大学学报:自然科学版), 2002, 35 (4):99-102 (in Chinese).[28] Hu Chuanxin. Stealth Coating Technology (隐身涂层技术) [M]. Beijing: Chemical Industry Press, 2004:121.[29] Fang Rongchuan. Solid Spectroscopy (固体光谱学) [M]. Hefei: University of Science and Technology of China Press, 2001:29.
0
浏览量
601
下载量
2
CSCD
关联资源
相关文章
相关作者
相关机构
京公网安备11010802024621