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西南科技大学 材料与科学工程学院
收稿:2009-11-25,
修回:2010-2-24,
网络首发:2010-11-22,
纸质出版:2010-11-22
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杜利成, 何平, 李先红, 陈阳. 基于液体荧光法的钕元素测定[J]. 发光学报, 2010,31(6): 936-941
DU Li-cheng, HE Ping, LI Xian-hong, CHEN Yang. Determination of Neodymium Using Fluorimetric Liquid Method[J]. Chinese Journal of Luminescence, 2010,31(6): 936-941
探讨了钕与丙氨酸、咪唑形成荧光配合物的各个因素
确定了用液体荧光法测定钕元素的最佳条件。实验表明
钕与丙氨酸和咪唑形成荧光配位化合物的最佳条件为:丙氨酸和咪唑的量的比为5:1
pH=5.0;钕配位化合物荧光强度的最佳测量条件为:激发波长220nm
发射波长350nm
激发狭缝带宽5nm
发射狭缝带宽10nm;溶液钕含量的最低测量下限为0.5μg/mL。应用该方法测定了氧化钕和陶瓷产品中的钕含量。
paper
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