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湖南师范大学 化学化工学院 资源精细化与先进材料湖南省高校重点实验室, 湖南 长沙 410081
收稿:2009-07-16,
修回:2009-9-27,
网络首发:2010-09-21,
纸质出版:2010-09-21
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周 文, 余丽萍, 廉世勋, 祁 媛, 朱爱玲, 荣春英. 前驱溶液的pH值对制备Ca<sub>2</sub>Zn<sub>4</sub>Ti<sub>16</sub>O<sub>38</sub> ∶ Pr<sup>3+</sup>,Na<sup>+</sup> 发光粉物相、形貌和发光性质的影响[J]. 发光学报, 2010,31(5): 712-718
ZHOU Wen, YU Li-ping, LIAN Shi-xun, QI Yuan, ZHU Ai-ling, RONG Chun-ying. Influence of pH Value in Precursor Solution on the Component, Morphology and Photoluminescence of Ca<sub>2</sub>Zn<sub>4</sub>Ti<sub>16</sub>O<sub>38</sub> ∶ Pr<sup>3+</sup>, Na<sup>+</sup> Phosphor[J]. 发光学报, 2010,31(5): 712-718
周 文, 余丽萍, 廉世勋, 祁 媛, 朱爱玲, 荣春英. 前驱溶液的pH值对制备Ca<sub>2</sub>Zn<sub>4</sub>Ti<sub>16</sub>O<sub>38</sub> ∶ Pr<sup>3+</sup>,Na<sup>+</sup> 发光粉物相、形貌和发光性质的影响[J]. 发光学报, 2010,31(5): 712-718 DOI:
ZHOU Wen, YU Li-ping, LIAN Shi-xun, QI Yuan, ZHU Ai-ling, RONG Chun-ying. Influence of pH Value in Precursor Solution on the Component, Morphology and Photoluminescence of Ca<sub>2</sub>Zn<sub>4</sub>Ti<sub>16</sub>O<sub>38</sub> ∶ Pr<sup>3+</sup>, Na<sup>+</sup> Phosphor[J]. 发光学报, 2010,31(5): 712-718 DOI:
以钛酸丁酯、醋酸钙、醋酸锌、柠檬酸和乙二醇为原料
采用溶胶-凝胶法制备Ca
2
Zn
4
Ti
16
O
38
∶ Pr
3+
Na
+
发光粉。研究了前驱溶液的pH值对溶胶-凝胶转变过程、发光粉物相组成、样品形貌和发光性质的影响。通过热重-差热分析(TG/DTA)、X射线衍射(XRD)分析、扫描电子显微镜(SEM)对前驱物分解、发光粉物相和颗粒大小进行了研究。采用荧光光谱对材料的光谱性质进行了表征。研究发现前驱溶液pH
&
le; 3时
所得发光粉样品为蓬松的、颗粒均匀的单相Ca
2
Zn
4
Ti
16
O
38
粉末
红色余辉时间较长;随着pH值增大
逐渐有杂质相TiO
2
、CaTiO
3
和Zn
2
TiO
4
生成
并且样品颗粒逐渐变大
颗粒团聚呈现不规则形状
余辉时间变短。结果表明
只有在pH
&
le; 3条件下以溶胶-凝胶法制备Ca
2
Zn
4
Ti
16
O
38
∶ Pr
3+
Na
+
发光粉下才能获得被日光有效激发
并呈现余辉衰减慢的红色长余辉(644 nm)发光。
paper
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