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1. 安徽大学 化学化工学院
2. 蚌埠学院 理学系
收稿:2009-06-16,
修回:1900-1-2,
网络首发:2010-06-30,
纸质出版:2010-06-30
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李宗群, 张 敏, 裘灵光. 发光性质可调的金属-有机骨架材料 的合成及发光性质[J]. 发光学报, 2010,31(3):421-426.
LI Zong-qun, ZHANG Min, QIU Ling-guang. Synthesis and Fluorescent Property of Metal-organic Frameworks with Tunable Fluorescence[J]. Chinese Journal of Luminescence, 2010, 31(3): 421-426.
以对苯二甲酸(H
2
BDC)为配体
以锌为中心离子
采用沉淀法合成了具有一维结构的金属配合物 纳米晶
将化合物分散到不同浓度的8-羟基喹啉(8-Hq)溶液中
得到系列配位聚合物 。分别用FT-IR和XRD对目标产物的结构进行了表征。固态发光性质研究显示: 及其配位聚合物具有强的发光
配位聚合物随着8-Hq量的增加
其发光发射光谱有规律地红移
表明该配位聚合物能够通过改变8-Hq与骨架材料间的量的比实现对材料发光性质的调控。
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