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大连理工大学 物理与光电工程学院
收稿:2009-11-25,
修回:1900-1-2,
网络首发:2010-04-30,
纸质出版:2010-04-30
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李庆伟, 边继明, 王经纬, 等. 水热法制备Co掺杂ZnO纳米棒及其光学性能[J]. 发光学报, 2010,31(2):253-257.
LI Qing-wei, BIAN Ji-ming, WANG Jing-wei, et al. Optical Properties of Co-doped ZnO Nanorods Synthesized by A Hydrothermal Method[J]. Chinese Journal of Luminescence, 2010, 31(2): 253-257.
采用水热法在石英衬底上以Zn(CH
3
COO)
2
·2H
2
O和Co(NO
3
)
2
·6H
2
O水溶液为源溶液
以C
6
H
12
N
4
(HMT)溶液作为催化剂
在较低温度下制备了Co掺杂的ZnO纳米棒。采用 X射线衍射(XRD)和扫描电子显微镜(SEM)对所生长ZnO纳米棒的晶体结构和表面形貌进行了表征
考察了Co掺杂对ZnO纳米棒微观结构和对发光性能影响的机制。结果表明:Co掺杂的ZnO纳米棒呈六方纤锌矿结构
具有沿(002)面择优生长特性
Co掺杂使ZnO纳米棒的直径变细;同时室温光致发光(PL)谱检测显示Co掺杂ZnO纳米棒具有很强的近带边紫外发光峰
而与深能级相关的缺陷发光峰则很弱。本研究采用水热法在石英衬底上于较低温度下生长出了具有较高光学质量的Co掺杂ZnO纳米棒。
paper
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