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中山大学 光电材料与技术国家重点实验室
收稿:2009-08-30,
修回:1900-1-2,
网络首发:2010-04-30,
纸质出版:2010-04-30
移动端阅览
李 爽, 周 翔. MoO3阳极缓冲层对有机太阳电池性能的影响[J]. 发光学报, 2010,31(2):291-295.
LI Shuang, ZHOU Xiang. Effects of Molybdenum Oxide Anode Buffer Layer on Performance of Organic Solar Cells[J]. Chinese Journal of Luminescence, 2010, 31(2): 291-295.
研究了MoO
3
阳极缓冲层对基于CuPc/C
60
异质结的有机小分子太阳电池器件性能的影响。发现:MoO
3
阳极缓冲层略微降低了器件的短路电流、开路电压及能量转换效率;MoO
3
阳极缓冲层提高了器件的整流比;具有MoO
3
阳极缓冲层的器件在持续光照条件下连续工作20 min
其主要性能参数(如短路电流、开路电压、填充因子及能量转换效率)无明显衰减
而没有MoO
3
阳极缓冲层的对比器件在相同条件下连续工作20 min
其能量转换效率衰减了大约45%。研究结果表明:MoO
3
阳极缓冲层明显提高了基于CuPc/C
60
异质结的有机小分子太阳电池器件的稳定性
可能的原因主要是MoO
3
阳极缓冲层改善了ITO阳极和CuPc界面
抑制了因持续光照连续工作引起的界面老化
从而提高了器件的稳定性。
paper
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. Tao C, Ruan S P, Zhang X D, et al. Performance improvement of inverted polymer solar cells with different top electrodes by introducing a MoO3 buffer layer [J]. Appl. Phys. Lett., 2008, 93 (19):193307-1-3.
. Li N, Lassiter B E, Lunt R R, et al. Open circuit voltage enhancement due to reduced dark current in small molecule photovoltaic cells [J]. Appl. Phys. Lett., 2009, 94 (2):023307-1-3.
. Kinoshita Y, Takenaka R, Murata H. Independent control of open-circuit voltage of organic solar cells by changing film thickness of MoO3 buffer layer [J]. Appl. Phys. Lett., 2008, 92 (24):243309-1-3.
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. Heutz S, Sullivan P, Sanderson B M, et al. Influence of molecular architecture and intermixing on the photovoltaic, morphological and spectroscopic properties of CuPc-C60 heterojunctions [J]. Sol. Energy Mater. Sol. Cells, 2004, 83 (2-3):229-245.
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. Krebs F C, Norrman K. Analysis of the failure mechanism for a stable organic photovoltaic during 10 000 h of testing [J]. Prog. Photovolt: Res. Appl., 2007, 15 (8):697-712.
. Krebs F C, Carle J E, Bagger N C, et al. Lifetimes of organic photovoltaics:photochemistry, atmosphere effects and barrier layers in ITO-MEHPPV ∶ PCBM-aluminium devices [J]. Sol. Energy Mater. Sol. Cells, 2005, 86 (4):499-516.
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. Kanai Y, Matsushima T, Murata H. Improvement of stability for organic solar cells by using molybdenum trioxide buffer layer [J]. Thin Solid Films, 2009, 518 (2):534-540.
. You H, Dai Y F, Zhang Z Q, et al. Improved performances of organic light-emitting diodes with metal oxide as anode buffer [J]. J. Appl. Phys., 2007, 101 (2):026105-1-3.
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