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重庆师范大学 物理学与信息技术学院 重庆,400047
收稿日期:2009-11-10,
修回日期:1900-01-02,
网络出版日期:2010-04-30,
纸质出版日期:2010-04-30
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牛连斌, 关云霞, 孔春阳, 等. 纳米ZnO薄膜对有机电致发光器件性能的影响[J]. 发光学报, 2010,31(2):162-166.
NIU Lian-bin, GUAN Yun-xia, KONG Chun-yang, et al. Organic Light-emitting Devices with Thin Nano-ZnO Film[J]. Chinese journal of luminescence, 2010, 31(2): 162-166.
由于有机电致发光器件(Organic light-emitting devices
OLEDs)的主动发光、高亮度等优点
在显示和照明领域有极大的应用前景。报道了纳米ZnO薄膜对这种发光器件性能的影响。在普通有机电致发光器件空穴传输层和发光层之间直接蒸镀一层纳米ZnO薄膜
当纳米ZnO薄膜的厚度为1 nm时
器件的电流效率可达3.26 cd/A
是没有纳米ZnO薄膜同类器件的1.24倍。适当厚度的纳米ZnO薄膜降低了发光层空穴的浓度
提高了电子和空穴的平衡
从而提高了器件的效率。
Organic light-emitting devices (OLEDs) have various advantageous features
such as self-emission
high luminous efficiency
full-colour capability
wide viewing angle
high contrast
low power consumption
low weight
potentially large area colour displays and flexibility. So
they have attracted considerable interest due to their promising applications in flat-panel displays. Here
the effect of ZnO nanolayer on the efficiency of OLED is reported. ZnO nanolayer was introduced between 8-hydroxyquinoline aluminum (Alq
3
) and N
N-bis-(1-naphthyl)-N
N-diphenyl-1
1-biphenyl-4
4-diamine (NPB) layers
and their influence on the device performance was investigated. When the 1.0 nm ZnO film is inserted
for an unoptimized device composed of indium-tin oxide (ITO)/NPB/ZnO/Alq
3
/LiF/Al
the current efficiency is as high as 3.26 cd·A
-1
. It is much higher than that of conventional device. The mechanism of performance enhancement was discussed. For the fabrication of the OLEDs
ITO (sheet resistance 30 Ω/□) glass
thoroughly cleaned was used. The routine cleaning procedures include ultrasonic agitation in acetone
ethanol
rinsing in de-ionized water
and isopropyl alcohol. After the oxygen plasma treatment in vacuum chamber
the substrates were loaded into a vacuum chamber with a base pressure of 4.0×10
-4
Pa. LiF
NPB
ZnO
Alq
3
and Al electrode were thermally deposited without breaking the vacuum
respectively. The deposition rate and film thickness were measured by a quartz oscillator connected to a frequency meter near the substrates during the deposition. In this study
we define the voltage as the operating voltage when emitted light is first detected. The level of light first resolved is around 1 cd/m
2
in our experimental setup. The current-voltage characteristics reported here were all measured in the forward bias voltage mode. In conclusion
it was found that the 1 nm thick ZnO layer can greatly improve the performance of the Alq
3
based organic light-emitting device. The improved efficiency of the device could be due to the ultrathin ZnO layer acting as the decreased holes injection into the emissive layer
which would made the number of electrons and holes injected into the emitter layer to be balanced.
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. Lee J, Park Y, Kim D Y, et al. High efficiency organic light-emitting devices with Al/NaF cathode [J]. Appl. Phys. Lett., 2003, 82 (2):173-175.
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. Li J, Yahiro M, Ishida K, et al. Enhanced performance of organic light emitting device by insertion of conducting/insulating WO3 anodic buffer layer [J]. Synthetic Metals, 2005, 151 (2):141-146.
. Kim Y M, Lee J W, Jung J H, et al. Enhanced brightness and efficiency of organic light-emitting diodes with an LiF in the Alq3 [J]. IEEE Electron Device Letters, 2006, 27 (7):558-561.
. Niu L B, Zhang F J. The effect of Al2O3 nanolayers on the efficiency of organic light-emitting devices [J]. Semicond. Sci. Technol., 2006, 21 (12):1639-1642.
. Brutting W, Berleb S, Muckl A G. Device physics of organic light emitting diodes based on molecular materials [J]. Org. Electron., 2001, 2 (1):1-5.
. Kim J H, Lee H. Efficient poly(p-phenylenevinylene) derivative with 1,2-diphenyl-2'-cyanoethene for single layer light-emitting diodes [J]. Synthetic Metals, 2003, 139 (4):471-474.
. Xu Z, Qu C, Teng F, et al. Why is the band model not contradictory to molecular theory in organic electroluminescence? [J]. Appl. Phys. Lett., 2005, 86 (6):061911-1-3.
. Dimitrakopoulos C D, Malenfant P R L. Organic thin film transistors for large area electronics [J]. Adv. Mater., 2002, 14 (2):99-117.
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