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1. 中南大学 材料科学与工程学院
2. 中南大学 物理科学与技术学院
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收稿日期:2009-03-30,
修回日期:1900-01-02,
网络出版日期:2010-02-20,
纸质出版日期:2010-02-20
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王俊西, 李宏建, 熊志勇, 等. LiF修饰阴极的双层有机电致发光器件的延时效应[J]. 发光学报, 2010,31(1):17-24.
WANG Jun-xi, LI Hong-jian, XIONG Zhi-yong, et al. Study on Electroluminescent Delay Time in Bilayer Organic Light-emitting Diodes with LiF/Ag Cathode[J]. Chinese journal of luminescence, 2010, 31(1): 17-24.
基于载流子的注入、传输和复合过程
建立了双层有机发光器件的电致发光延时理论模型; 讨论了电致发光延时随电压、注入势垒、内界面势垒、阳极区厚度及LiF缓冲层(BL)厚度的变化关系。 结果表明:(1)低电压下
EL延时由复合过程主导
而高电压下
输运过程起着更重要的作用;(2)当
δ
e
/
δ
h
<2时
M/O界面属于欧姆接触
电流是空间电荷限制的
注入势垒的变化对复合时间
t
rec
影响较大
当
δ
e
/
δ
h
>2时
M/O界面成为接触限制
注入势垒的变化对
t
rec
几乎没有影响;(3)当内界面势垒超过0.3 eV
H'
h
对t
rec
的影响明显变弱
复合延迟时间基本上由电压和其它因素控制; (4)当电压较小时
随L
h
/L的增大
t
rec
增大;当电压超过某一值后
t
rec
几乎不随L
h
/L的变化而变化;(5)对于LiF/Ag阴极
在不同的偏压下
LiF的厚度在3.1 nm左右时的复合时间最短
对应的EL延迟时间也最短
这与实验中从电致发光效率的角度得出的LiF最佳厚度一致。
paper
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