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1. 广西师范学院 化学系
2. 华中科技大学 武汉光电国家实验室
3. 常德职业技术学院
收稿:2009-01-15,
修回:1900-1-2,
网络首发:2009-10-30,
纸质出版:2009-10-30
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高 飞, 梁利芳, 郭崇峰. LED用红色发光材料 Li3Ba2Ln3-xEux(MoO4)8的制备及性能[J]. 发光学报, 2009,30(5):610-616.
GAO Fei, LIANG Li-fang, GUO Chong-feng. Preparation and Luminescence of Red Light-emitting Phosphors Based on Li3Ba2Ln3-xEux(MoO4)8 by Sol-gel Method[J]. Chinese Journal of Luminescence, 2009, 30(5): 610-616.
高 飞, 梁利芳, 郭崇峰. LED用红色发光材料 Li3Ba2Ln3-xEux(MoO4)8的制备及性能[J]. 发光学报, 2009,30(5):610-616. DOI:
GAO Fei, LIANG Li-fang, GUO Chong-feng. Preparation and Luminescence of Red Light-emitting Phosphors Based on Li3Ba2Ln3-xEux(MoO4)8 by Sol-gel Method[J]. Chinese Journal of Luminescence, 2009, 30(5): 610-616. DOI:
采用溶胶-凝胶法合成了发光二极管(LED)用的系列红色荧光粉Li
3
Ba
2
Ln
3-x
Eu
x
(MoO
4
)
8
(Ln=La
Gd
Y)。利用差热-热重(TG-DTA)分析和粉末X 射线衍射(XRD)测定了其最佳合成温度和不同温度下所得样品的结构
发现所有样品均具有单斜结构;采用荧光光谱对所得荧光粉发光性能进行了表征
发现在相同条件下所得样品的发光强度顺序为:Li
3
Ba
2
Y
2.8
Eu
0.2
(MoO
4
)
8
>Li
3
Ba
2
Gd
2.8
Eu
0.2
(MoO
4
)
8
>Li
3
Ba
2
La
2.8
Eu
0.2
-(MoO
4
)
8
。它们在395 nm和465 nm的激发光源激发时均有强的吸收
与LED芯片发射波长相匹配。同时分析了柠檬酸及分散剂聚乙二醇(PEG-10000)的用量、Eu
3+
离子的浓度以及焙烧温度等因素对荧光粉发光性能的影响。
paper
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