含稀土化合物透明树脂的合成与光学性质

王冬梅; 刘青云; 姜建壮; 杨 柏

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含稀土化合物透明树脂的合成与光学性质

论文 | 更新时间：2020-08-12

- 含稀土化合物透明树脂的合成与光学性质
- Synthesis and Optical Properties of Transparent Resins Containing Rare Earth Compounds
- 发光学报 2009年30卷第4期页码：427-435
- 作者机构：
  
  1. 山东科技大学化学与环境工程学院,山东青岛,266510
  2. 山东大学化学与化工学院胶体与界面化学教育部重点实验室,山东济南,250100
  3. 吉林大学化学学院超分子结构与材料教育部重点实验室,吉林长春,130023
- 作者简介：
- 基金信息：
- DOI：
  中图分类号： O482.31;O631.2+4
- 收稿日期：2008-10-25，
  
  修回日期：1900-01-02，
  
  网络出版日期：2009-08-30，
  
  纸质出版日期：2009-08-30
- 稿件说明：
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王冬梅, 刘青云, 姜建壮, 等. 含稀土化合物透明树脂的合成与光学性质[J]. 发光学报, 2009,30(4):427-435.

WANG Dong-mei, LIU Qing-yun, JIANG Jian-zhuang, et al. Synthesis and Optical Properties of Transparent Resins Containing Rare Earth Compounds[J]. Chinese journal of luminescence, 2009, 30(4): 427-435.
王冬梅, 刘青云, 姜建壮, 等. 含稀土化合物透明树脂的合成与光学性质[J]. 发光学报, 2009,30(4):427-435. DOI：

WANG Dong-mei, LIU Qing-yun, JIANG Jian-zhuang, et al. Synthesis and Optical Properties of Transparent Resins Containing Rare Earth Compounds[J]. Chinese journal of luminescence, 2009, 30(4): 427-435. DOI：

摘要

我们采用三种不同方法制备了含稀土化合物的光学树脂。第一种是含稀土甲基丙烯酸盐的透明树脂

第二种是采用直接掺杂法制备的含稀土配合物透明树脂

第三种是采用原位复合法制备的含稀土配合物透明树脂。通过对三种透明树脂的热稳定性、抗冲击性、紫外-可见吸收光谱、红外光谱、荧光光谱及核磁等方面的表征

结果表明获得的第二、第三种透明树脂具有非常好的透明性、发光性和相关物理机械性能

进一步比较三种透明树脂的发光性质发现第三种采用原位复合法制备的含稀土配合物透明树脂最好

这说明原位复合法是一种简便快捷合成透明荧光高分子材料的好方法。

Abstract

Three kinds of transparent resins were prepared by three different synthesis methods. Sample 1 is transparent resins formed by RE(MA)

salt polymerizing

Sample 2 is transparent resins containing rare earth(RE) complexes by doping method

and Sample 3 is transparent resins containing rare earth complexes by in situ compo-site method. The transparent resins were characterized by TGA

impact energy

UV-Vis

FT-IR

H-NMR and fluorescence spectra. The fluorescence data indicated that the optical resins display intense and narrow-band emission

highly visible transparency

and good mechanics performance in Sample 2 and Sample 3. The photoluminescence intensity enhanced and lifetitne is raised in doping or in situ method after introducing RE complexes into copolymer system

by comparing with RE complexes powder. The fluorescence data revealed that the fluorescence intensity of Sample 3

which synthesized by in situ method

is the strongest among the three samples. It was revealed that the in situ synthesis method

as a novel method

can be quickly and simply employed to synthesize transparent optical resins. Comparing with the resins by doping method

these composite resins possess better luminescent property at the same RE concentration.

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Keywords

references

. Yan B, Zhang H, Wang S, et al. Luminescence properties of rare-earth (Eu3+ and Tb3+) complexes with paraaminobenzoic acid and 1,10-phenanthroline incorporated into a silica matrix by sol-gel method [J]. Mater. Res. Bull., 1998, 33 (10):1517-1525.

. Lin Quan, Zhuang Rutian, Zhang Xiannain, et al. Copolymerization of Cd(MA)2 and the studies optical properties [J]. Acta. Polym. Sinca (高分子学报), 1999, (2):189-193 (in Chinese).

. Ida K. Resin composition containing rare earth element and production thereof: US, 83548444 . 1983-10-12.

. Liu Li, Zhang Liqun, Zhao Suhe, et al. Review on rare earth /polymer composite [J]. J. Rare Earth, 2002, 20 (4):241-245.

. Ida K. Synthetic resin composition and process for producing the same: EP, 108622 . 1984-05-16.

. Maruyama T, Azzopardi D V Edwards, Kageyama T, et al. Laser transmissiion phto-scanner:clinical application in breast tumor detection [J]. IEEE Transaction on Consumer Electronics, 1987, CE-33(3):256-260.

. Gao Changyou, Yangbai, Shen Jiacong. The preparation of transparent resins containing rare earth and their properties of absorbance and fluorescence [J]. J. Functional Polym (功能高分子学报) , 1995, 8 (4):461-466 (in Chinese).

. Wang Dongmei, Lin Quan, Li Huanrong, et al. Preparation and optical properties of transparent resins containing europium complexes [J]. Chin. J. Lumin. (发光学报), 2000, 21 (3):261-264 (in Chinese).

. Wang Dongmei, Lin Quan, Li Huanrong, et al. The preparation and property studies of transparent resins containing terbium(Ⅲ) complex [J]. Chem. J. Chin. Univer.(高等学校化学学报), 2001, 22 (4):695-697 (in Chinese).

. Wang Dongmei, Lin Quan, Yang Bai. The preparation and property studies of transparent resins containing terbium (Ⅲ) complex [J]. Chem. J. Chin. Univer.(高等学校化学学报), 2003, 24 (5):940-942 (in Chinese).

. Wang Dongmei, Zhang Junhu, Lin Quan, et al. Lanthanide complex/polymer composite optical resin with intense narrow band emission, high transparency and good mechanical performance [J]. J. Mater. Chem., 2003, 13 (9):2279-2284.

. Melby L R, Rose N J, Abramson E, et al. Synthesis and fluorescence of some trivalent lanthanide complexes [J]. J. Am. Chem. Soc., 1964, 86 (23):5117-5125.

. Ji Xiangling, Li Bin, Jiang Shichu, et al. Luminescent properties of organic-inorganic hybrid monoliths containing rare-earth complexes [J]. J. Non-Crystalline Solids, 2000, 275 (1-2):52-58.

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