Tb<SUP>3+</SUP>掺杂硅酸盐闪烁玻璃发光特性

姜代武; 宋 博; 杨 旭; 肖洪亮; 吕景文

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Tb³⁺掺杂硅酸盐闪烁玻璃发光特性

论文 | 更新时间：2020-08-12

- Tb³⁺掺杂硅酸盐闪烁玻璃发光特性
- Luminescent Property of Tb³⁺ Doped Silicate Scintillating Glass
- 发光学报 2009年30卷第3期页码：363-367
- 作者机构：
  
  1. 长春理工大学材料科学与工程学院,吉林长春,130022
  2. 长春理工大学理学院, 吉林长春 130022
  3. 长春理工大学光电信息学院,吉林长春,130022
- 作者简介：
- 基金信息：
- DOI：
  中图分类号： O482.31
- 纸质出版日期：2009-6-30，
  
  网络出版日期：2009-6-30，
  
  收稿日期：2008-8-25，
  
  修回日期：1900-1-2，
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姜代武, 宋博, 杨旭, 等. Tb³⁺掺杂硅酸盐闪烁玻璃发光特性[J]. 发光学报, 2009,30(3):363-367.

JIANG Dai-wu, SONG Bo, YANG Xu, et al. Luminescent Property of Tb³⁺ Doped Silicate Scintillating Glass[J]. Chinese Journal of Luminescence, 2009,30(3):363-367.
姜代武, 宋博, 杨旭, 等. Tb³⁺掺杂硅酸盐闪烁玻璃发光特性[J]. 发光学报, 2009,30(3):363-367. DOI：

JIANG Dai-wu, SONG Bo, YANG Xu, et al. Luminescent Property of Tb³⁺ Doped Silicate Scintillating Glass[J]. Chinese Journal of Luminescence, 2009,30(3):363-367. DOI：

摘要

对Tb

掺杂的硅酸盐闪烁玻璃进行了研究。对玻璃基质、敏化剂、发光激活剂组分进行了优化

改进了熔制温度、保温时间、气氛等工艺条件。根据氟化物具有较好的稀土可溶性

具有相对较低的声子能量

调整了闪烁玻璃中的氟化物含量。讨论了Tb

离子和Gd

离子对闪烁玻璃发光性能的影响。闪烁玻璃样品的激发和发射光谱、光衰减时间谱等结果显示:闪烁玻璃基质中由Gd

和Dy

离子向发光中心Tb

离子的无辐射能量共振转移以及在一定浓度范围内Tb

离子之间的交叉弛豫过程对玻璃的发光性能有重要影响。Tb

离子在一定浓度范围内具有自敏化效应

随着Tb

离子浓度的增加

绿色荧光得到增强

蓝紫色荧光减弱

掺杂硅酸盐闪烁玻璃的发光性能有明显的提高。

Abstract

doped silicate scintillating glass was studied in this paper

we optimized Tb

doped silicate scintillating glass matrix

sensitizer

activator contents

improved the melting temperature

holding time

the atmosphere and so on. According to that fluorides have a better rare earth solubility and a relatively lower phonon energy

the fluoride content in the scintillating glass was adjusted. The energy transfer between Tb

and Gd

was studied according to excitation and emission spectra. The results showed that energy transfer occurs from Gd

and Dy

ions towards Tb

emssion centers as well as the cross relaxation among Tb

ions within a certain concentration range exert tremendous effects on the emission intensity of glass. The Tb

under the certain concentration range contributes to the enhanced Tb

green emission and the weakened Tb

blue emission. Therefore

the luminescent property of Tb

doped silicate scintillating glass has been noticeably improved.

关键词

铽离子氟化物发光性能

Keywords

Tb3+fluoridesluminescent property

references

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Tb3+掺杂硅酸盐闪烁玻璃发光特性

Luminescent Property of Tb3+ Doped Silicate Scintillating Glass

DOI：

摘要

Abstract

关键词

Keywords

references

Tb³⁺掺杂硅酸盐闪烁玻璃发光特性

Luminescent Property of Tb³⁺ Doped Silicate Scintillating Glass