水热法制备MgWO<SUB>4</SUB> 及其发光性质

李锦清; 杨创涛; 孟建新

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水热法制备MgWO₄ 及其发光性质

论文 | 更新时间：2020-08-12

- 水热法制备MgWO₄ 及其发光性质
- Hydrothermal Synthesis of MgWO₄ and Its Luminescence
- 发光学报 2009年30卷第3期页码：327-331
- 作者机构：
  
  1. 暨南大学化学系,广东广州,510632
  2. 暨南大学纳米化学研究所,广东广州,510632
- 作者简介：
- 基金信息：
- DOI：
  中图分类号： O482.31
- 收稿：2008-09-04，
  
  修回：1900-1-2，
  
  网络出版：2009-06-30，
  
  纸质出版：2009-06-30
- 稿件说明：
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李锦清, 杨创涛, 孟建新. 水热法制备MgWO₄ 及其发光性质[J]. 发光学报, 2009,30(3):327-331.

LI Jin-qing, YANG Chuang-tao, MENG Jian-xin. Hydrothermal Synthesis of MgWO₄ and Its Luminescence[J]. Chinese Journal of Luminescence, 2009, 30(3): 327-331.
李锦清, 杨创涛, 孟建新. 水热法制备MgWO₄ 及其发光性质[J]. 发光学报, 2009,30(3):327-331. DOI：

LI Jin-qing, YANG Chuang-tao, MENG Jian-xin. Hydrothermal Synthesis of MgWO₄ and Its Luminescence[J]. Chinese Journal of Luminescence, 2009, 30(3): 327-331. DOI：

摘要

以硝酸镁、钨酸钠为原料

氢氧化钠和硝酸作为pH调节剂

在180~230 ℃水热条件制备纯相的MgWO

。探讨了水热反应温度对MgWO

纯相形成以及煅烧温度对其晶型、发光性质的影响。分别用粉末X射线衍射、荧光光谱、扫描电子显微镜和综合热分析等手段对样品进行表征。结果表明

水热法可以直接制得不含结晶水MgWO

晶体

属于四方晶系

形貌呈片状

厚度约为几个纳米。样品热重分析和高温煅烧的结果表明

水热法所得MgWO

晶体在850 ℃附近出现晶型转化

由四方晶系转变为单斜晶系

并导致发光性质的明显变化。SEM显示煅烧前的样品形貌为片状

不同温度煅烧后由片状逐渐向棒状转变。

Abstract

MgWO

is a self-activated luminescent material

chemical and luminous properties are stable. It has high quantum efficiency and has been used as lamp phosphor for a long-term. MgWO

is usually prepared by solid-phase method using high purity MgO or MgCO

mixture with WO

then sintered at about 1 200 ℃ for several hours. Solid-phase approach leads to unhomogeneous distribution of sample size

the particles easily reunion

and the particle size is difficult to control

but hydrothermal method can overcome these shortco-mings. In recent years

hydrothermal method has been used to synthesis some kinds of tungstate samples

such as BaWO

NaLa(WO

)

PbWO

and so on

but to synthesis MgWO

it has not been reported.Amberg and John.R synthesized pure MgWO

·H

O and MgWO

·2H

O by mild hydrothermal method

but without studying on their luminescent properties. This article reports about using hydrothermal method to synthesis MgWO

crystal without crystalline H

O. A pure phase MgWO

was synthesized by hydrothermal method from Mg(NO

)

and Na

solutions. The effects of hydrothermal temperatures on lattice phase

sintering temperatures on the morphology

structure and fluorescence intensity of MgWO

powder were investigated. Samples were characterized by X-ray diffraction (XRD)

fluorescence spectrometer

scanning electron microscope(SEM) and TG-DSC. The results showed that MgWO

without crystalline H

O molecule can be synthesized at 180~230 ℃ hydrothermal temperatures. The as-prepared sample has a tetragonal structure and transfer to monocline structure when sintered at 850 ℃ or higher temperature. Fluorescence spectra showed that MgWO

has a broad emission band peaked at 480 nm. The emission intensity becomes stronger as the sintering temperature increases from 750 ℃ to 1 050 ℃. SEM images showed that the size of MgWO

particles increases with the sintering temperature.

关键词

Keywords

references

. Zhang Zhongtai, Zhang Junying. Photoluminescence Inorganic Materials and Applications [M]. Beijing: Chemical Industry Press, 2005,128.

. Guo Qiti, Ole Jakob Kleppa. Enthalpies of formation from the component oxides of MgWO4, CaWO4(scheelite), SrWO4 and BaWO4,determined by high-temperature direct synthesis calorimetry [J].Thermochimica Acta, 1996, 288 (1-2):53-61.

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. Zhang Fan, Yang Shiping, Chen Hongmei, et al. The effect of an anionic starburst dendrimer on the crystallization of BaWO4 under hydrothermal reaction conditions [J]. J. Crystal Growth, 2004, 267 (3-4):569-573.

. Wang Feng, Fan Xianping, Pi Daibo, et al. Hydrothermal synthesis and luminescence behavior of rare-earth-doped NaLa(WO4)2 powders [J]. J. Solid State Chem., 2005, 178 (3):825-830.

. An Changhua, Tang Kaibin, Shen Guozhen, et al. Hydrothermal preparation of luminescent PbWO4 nanocrystallites [J]. Materials Lett., 2002, 57 (3):565-568.

. Fu Hongbo, Lin Jie, Zhang Liwu, et al. Photocatalytic activities of a novel ZnWO4 catalyst prepared by a hydrothermal process [J]. Appl. Catalysis A: General, 2006, 306 (7):58-67.

. John R, Günter, Marcel Amberg. Crystal structure and topotactic dehydration of magnesium tungstate dihydrate, MgWO4·2H2O [J]. Solid State Ionics, 1989, 32-33 (Part 1):141-146.

. Amberg M, Günter J R, Schmalle H, et al. Preparation, crystal structure, and luminescence of magnesium molybdate and tungstate monohydrates, MgMoO4·H2O and MgWO4·H2O [J]. J. Solid State Chem., 1988, 77 (1):162-169.

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水热法制备MgWO4 及其发光性质

Hydrothermal Synthesis of MgWO4 and Its Luminescence

DOI：

摘要

Abstract

关键词

Keywords

references

水热法制备MgWO₄ 及其发光性质

Hydrothermal Synthesis of MgWO₄ and Its Luminescence