共沉淀法制备NaYF4 : Tm3+,Yb3+的上转换发光

孙家跃; 杨志萍; 杜海燕

doi:null

您当前的位置：

首页 >

文章列表页 >

共沉淀法制备NaYF₄ : Tm³⁺,Yb³⁺的上转换发光

论文 | 更新时间：2020-08-12

- 共沉淀法制备NaYF₄ : Tm³⁺,Yb³⁺的上转换发光
- Upconversion Luminescence Properties of NaYF₄ : Tm³⁺,Yb³⁺Synthesized by Co-precipitation Method
- 发光学报 2009年30卷第2期页码：195-200
- 作者机构：
  
  北京工商大学化工学院
- 作者简介：
- 基金信息：
- DOI：
  中图分类号： O482.31
- 收稿：2008-08-25，
  
  修回：1900-1-2，
  
  网络首发：2009-04-30，
  
  纸质出版：2009-04-30
- 稿件说明：
移动端阅览
孙家跃, 杨志萍, 杜海燕. 共沉淀法制备NaYF₄ : Tm³⁺,Yb³⁺的上转换发光[J]. 发光学报, 2009,30(2):195-200.

SUN Jia-yue, YANG Zhi-ping, DU Hai-yan. Upconversion Luminescence Properties of NaYF₄ : Tm³⁺,Yb³⁺Synthesized by Co-precipitation Method[J]. Chinese Journal of Luminescence, 2009, 30(2): 195-200.
孙家跃, 杨志萍, 杜海燕. 共沉淀法制备NaYF₄ : Tm³⁺,Yb³⁺的上转换发光[J]. 发光学报, 2009,30(2):195-200. DOI：

SUN Jia-yue, YANG Zhi-ping, DU Hai-yan. Upconversion Luminescence Properties of NaYF₄ : Tm³⁺,Yb³⁺Synthesized by Co-precipitation Method[J]. Chinese Journal of Luminescence, 2009, 30(2): 195-200. DOI：

摘要

通过共沉淀法制备Tm

和Yb

掺杂的NaYF

上转换发光材料。其中Tm

和Yb

的摩尔分数分别为0.01%

0.1%。在室温下测试了NaYF

: Tm

材料在300~1 100 nm的吸收光谱。利用X射线衍射(XRD)

扫描电镜(SEM)测试了合成材料的物相结构和微观形貌。结果表明:NaYF

: Tm

材料为六方相晶体

其颗粒大小约为50~60 nm

产物结晶良好

含有少量杂相。在798 nm近红外光激发下

测试了样品的上转换发光光谱。观察到了蓝、绿色上转换发光。讨论了上转换发光的可能机理

蓝光主要来源于Tm

的激发态

到基态

的跃迁

绿光来源于Tm

的

→

跃迁。

Abstract

paper

关键词

Keywords

references

. Zhao Suling, Hou Yanbing, Xu Zheng. Emission of YLiF4 : Er3+, Tm3+, Yb3+ excited with different wavelength [J]. Chin. J. Lumin. (发光学报), 2006, 27 (2):191-195 (in Chinese).

. Li Baozheng, Guo Hai, Chen Xuesheng, et al. Up-conversion luminescence of Er3+/Yb3+ ions doped PLZT for active electrooptical applications [J]. Chin. J. Lumin. (发光学报), 2007, 28 (1):62-66 (in Chinese).

. Yan Bin, Zhang Xiangqing, Lai Huasheng, et al. Luminescent properties of YP1-xVxO4 : Tm3+ and YP1-xVxO4 : Tm3+,Dy3+ phoshors [J]. Chin. J. Lumin. (发光学报), 2007, 28 (4):531-536 (in English).

. Tu Weiwei, Liu Yichun, Liu Yuxue, et al. The effect of heat treatment on the optical properties of SiO2 : Er3+ film [J]. Chin. J. Lumin. (发光学报), 2008, 28 (1):97-101 (in Chinese).

. Rapaport A, Milliez J, Bass M, et al. Numerical model of the temperature dependence of the up-conversion efficient of fluoride crystals codoped with ytterbium and thulium [J]. J. Appl. Phys., 2005, 97 (12):123527-1-6.

. Zheng Qi, Sun Junfang, Liu Lingzhi, et al. Preparation of upconversion luminescence materials of NaYF4 : Yb,Er [J]. Technology and Development of Chemical Industry (化工技术与开发), 2007, 36 (6):1-3 (in Chinese).

. Yi Guangshun, Chow Ganmoog . Synthesis of hexagonal-phase NaYF4 : Yb, Er and NaYF4 : Yb,Tm nanocrystals with efficient up-conversion fluorescence [J]. Advanced Function Materials, 2006, 16 (18):2324-2329.

. Cao Chunyan, Qin Weiping, Zhang Jisen, et al. Upconversion emission properties of Tm3+/Er3+/Yb3+ tri-doped YF3 powders depending on excitation power, annealed temperature and Tm3+ concentration [J]. Chin. J. Lumin. (发光学报), 2007, 28 (5):705-709 (in Chinese).

. Liang Lifang, Zhuang Jianle, Wu Hao, et al. White up-conversion emission of hydrothemally synthesized NaYbF4 : Er3+/Tm3+ [J]. Chin. J. Lumin. (发光学报), 2008, 29 (6):996-1002 (in Chinese).

. Shi Zhan, Feng Shouhua. Hydrothermal synthesis and characterization of complex fluorides Li2BeF4 [J]. Chem. J. Chin. Universities (高等学校化学学报), 1999, 20 (2):172-175 (in Chinese).

. Qin Guanshi, Qin Wenping, Wu Changfeng, et al. Enhancement of ultraviolet upconversion in Yb3+ and Tm3+ codoped amorphous fluoride prepared by pulsed laser deposition [J]. J. Appl. Phys., 2003, 93 (7):4328-4330.

. Luo Junming, Li Yongxiu, Deng Liping, et al. Fabrication of Er3+ : Y2O3 nanocrystalline powder of upconversion luminescence by co-precipitation [J]. Rare Meta Materials and Engineering (稀有金属材料与工程), 2007, 36 (8):1436-1439 (in Chinese).

. Yang Kuisheng, Li Yan, Yu Chaoyi, et al. Upconversion luminescence properties of Ho3+,Tm3+,Yb3+ co-doped nanocrystal NaYF4 synthesized by hydrothermal method [J]. J. Rare Earth, 2006, 24 (6):757-760.

. Yang Fengzhen, Yi Guangshun, Chen Depu, et al. Synthesis and upconversion luminescence properties of nanocrystal Yb,Ho co-dopoed sodium yttrium fluoride [J]. Chem. J. Chin. Universities (高等学校化学学报), 2004, 25 (9):1589-1592 (in Chinese).

. Meng Chao, Meng Guangzhen, Song Zengfu. An effect enhancement mechanism of upconversion luminescence-upconversion sensitization [J]. Spectroscopy and Spectral Analysis (光谱学与光谱学分析), 2001, 21 (2):142-146 (in Chinese).

. Zang Jingcun, Xu Dongyong, Zou Yulin, et al. Indirect sensitization upconversion luminescence and resonant energy transfer of Yb3+-Tm3+ in ZnWO4 [J]. J. Optoelectronics·Laser (光电子·激光), 2002, 13 (1):43-45 (in Chinese).

. Zhang Wentao, Xu Xiuting, Zhao Chunyan, et al. Hydrothermal synthesis and phase transition of hexagonal phase NaYF4 [J]. Chem. J. Chin. Uninersities (高等学校化学学报), 1998, 19 (12):1918-1919 (in Chinese).

. Feng Yan, Chen Xiaobo, SongFeng, et al. Upconversion luminescence of Tm3+,Yb3+·ZBLAN Glass under 798nm LD pumping [J]. Acta Optica Sinica (光学学报), 1999, 19 (4):552-556 (in Chinese).

. Chen Xiaobo, Zhang Guangyan, Sawanobori N. The indirect upconversion sensitization luminescence research of Tm, Yb codoped oxyfluoride glasses [J]. Acta Phys. Sinica (物理学报), 1999, 48 (5):948-954 (in Chinese).

. Lilia Coronato Courrol, Izilda Marcia Ranieri, Luís Vicente Gomes, et al. Enhancement of blue upconversion mechanism in YLiF4 : Yb,Tm,Nd crystals [J]. J. Appl. Phys., 2005, 98 (11):113504-1-3.

. Liu Chunxu, Liu Junye, Lu Shaozhe, et al. Energy migration among Gd3+ and quantum efficiencies of Gd3+-Dy3+ energy transfer in NaGdF4 : Tm3+,Dy3+ [J]. Chin. J. Lumin.(发光学报), 2007, 28 (4):526-530 (in Chinese).

. Duan Zhouchao, Zhang Junjie, He Dongbing, et al. Upconversion luminescence of Tm3+/Yb3+ codoped oxyfluoride glasses pumped at 970 nm [J]. Acta Optica Sinica (光学学报), 2005, 25 (12):1659-1663 (in Chinese).

浏览量

192

下载量

CSCD

文章被引用时，请邮件提醒。

提交

工具集

关联资源

CaMoO4：Eu3+,Bi3+,Li+红色荧光粉的共沉淀制备与表征

β-NaGd0.794 Yb0.200 Ho0.001 Tm0.005 F4 纳米颗粒的白色上转换发光

Yb3+和Er3+共掺ZnF2-AlF3-PbF2-LiF多晶和玻璃的光谱性质

铒离子在氟氧化物玻璃陶瓷中的上转换发光特性研究

手性有机长余辉材料及其圆偏振发光