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1. 南京工业大学, 材料科学与工程学院
2. 南京工业大学, 电光源研究所
3. 浙江工业大学, 化学与材料学院
收稿:2007-07-04,
修回:2007-10-24,
纸质出版:2008-03-20
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沈静飞, 王海波, 黄如喜, 朱月华, 钟金环, 井艳军. BaMgAl<sub>10</sub>O<sub>17</sub>:Eu<sup>2+</sup>的MgF<sub>2</sub>表面包覆[J]. 发光学报, 2008,29(2): 264-268
SHEN Jing-fei, WANG Hai-bo, HUANG Ru-xi, ZHU Yue-hua, ZHONG Jin-huan, JING Yan-jun. Surface Coating of BAM Phosphors with MgF<sub>2</sub>[J]. Chinese Journal of Luminescence, 2008,29(2): 264-268
沈静飞, 王海波, 黄如喜, 朱月华, 钟金环, 井艳军. BaMgAl<sub>10</sub>O<sub>17</sub>:Eu<sup>2+</sup>的MgF<sub>2</sub>表面包覆[J]. 发光学报, 2008,29(2): 264-268 DOI:
SHEN Jing-fei, WANG Hai-bo, HUANG Ru-xi, ZHU Yue-hua, ZHONG Jin-huan, JING Yan-jun. Surface Coating of BAM Phosphors with MgF<sub>2</sub>[J]. Chinese Journal of Luminescence, 2008,29(2): 264-268 DOI:
采用溶胶-凝胶法对蓝色荧光粉BaMgAl
10
O
17
:Eu
2+
(BAM)进行表面包膜处理
获得了表面均匀包覆MgF
2
膜层的BAM荧光粉。并用SEM、XRD和IR手段对其表面形貌、晶格结构性能进行了表征;用EDS对BAM粉体的表面元素进行了定性分析;用荧光光谱测试对荧光粉的发光性能进行了研究。结果表明
在BAM粉体表面均匀包覆MgF
2
层后
BAM的晶格结构
发光性能没有改变
初始亮度较未包覆的荧光粉有所降低
经过相同条件的热处理后
包覆MgF
2
荧光粉的亮度热衰减程度明显低于未包覆的荧光粉
且色坐标偏移现象不明显。
Wu Zhisen,Liu Kai,Liang Buqing,et al.The research situation of BAM blue phosphor's deterioration phenomenon[J].Jiangsu Metallurgy (江苏冶金),2006,34(2):4-7 (in Chinese).
Valerie Pike,Samuel Patraw,Anthony L Diaz,et al.Defect chemistry and VUV optical properties of the BaMgAl10O17:Eu2+-Ba0.75Al11O17.25:Eu2+ solid solution[J].J.Solid State Chemistry,2003,173(2):359-366.
Kim Kwang-Bok,Koo Kyung-Wan,Cho Tong-Yui,et al.Effect of heat treatment on photoluminescence behavior of BaMgAl10O17:Eu phosphors[J].Materials Chem.and Phys.,2003,80(3):682-689.
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Yu Zhijian,Zhuang Weidong,Zhao Chunlei,et al.Study on barium magnesium aluminate blue phosphors doped with Sr2+ and Ca2+[J].J.Chin.Rare Earth Society (中国稀土学报),2001,19(6):590-593 (in Chinese).
Kazuyoshi Yokota,Zhang Shuxiu,Katsuaki Kimura,et al.Eu2+-activeted barium magnesium aluminate phosphor for plasma displays-phase relation and mechanism of thermal degradation[J].J.Lumin.,2001,92(3):223-227.
Jung Kyeong Youl,Lee Dong Youl,Kang Yun Chan.Improved thermal resistance of spherical BaMgAl10O17:Eu blue phosphor by spray pyrolysis[J].J.Lumin.,2005,115(3-4):91-96.
Zhang Shiying,Li Deyi,Wei Kun.Study on sol-gel method preparation nanocrystalline phosphor[J].China Ceramic Industry (中国陶瓷工业),2003,10(2):36-38 (in Chinese).
Teng Xiaoming,Zhang Weidong,Huang Xiaowei.Luminescent properties of BaMgAl10O17:Eu2+ phosphors coated with Y2SiO5[J].J.Rare Earths,2006,24(2):143-145.
Ma Lin,Hu Jianguo,Wang Huipin,et al.Study of coating on phosphor surface[J].J.Fudan University(Natural Science)(复旦学报(自然科学版)),2002,41(4):449-452 (in Chinese).
Zhu Hongyang,Yang Haibin,Fu Wuyou,et al.The improvement of thermal stability of BaMgAl10O17:Eu2+ coated with MgO[J].Matherials Lett.,2008,62(4-5):784-786.
Zhu Peifen,Zhu Qiren,Zhu Hongyang,et al.Effect of SiO2 coating on photoluminescence and thermal stability of BaMgAl10O17:Eu2+ under VUV and UV excitation[J].Optical Materials,2008,30(6):930-934.
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