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同济大学, 波耳固体物理研究所, 波与材料微结构实验室, 上海, 200092
收稿:2006-08-16,
修回:2007-1-12,
纸质出版:2007-05-20
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张睿, 顾牡, 刘小林, 刘冰洁. 共掺杂效应对Y<sub>2</sub>O<sub>3</sub>:Eu<sup>3+</sup>和Gd<sub>2</sub>O<sub>3</sub>:Eu<sup>3+</sup>发光影响的理论研究[J]. 发光学报, 2007,28(3): 383-388
ZHANG Rui, GU Mu, LIU Xiao-lin, LIU Bing-jie. Theoretical Study of the Co-doped Ions on the Luminescence of Rare-earth Oxides Y<sub>2</sub>O<sub>3</sub>:Eu<sup>3+</sup> and Gd<sub>2</sub>O<sub>3</sub>:Eu<sup>3+</sup>[J]. Chinese Journal of Luminescence, 2007,28(3): 383-388
张睿, 顾牡, 刘小林, 刘冰洁. 共掺杂效应对Y<sub>2</sub>O<sub>3</sub>:Eu<sup>3+</sup>和Gd<sub>2</sub>O<sub>3</sub>:Eu<sup>3+</sup>发光影响的理论研究[J]. 发光学报, 2007,28(3): 383-388 DOI:
ZHANG Rui, GU Mu, LIU Xiao-lin, LIU Bing-jie. Theoretical Study of the Co-doped Ions on the Luminescence of Rare-earth Oxides Y<sub>2</sub>O<sub>3</sub>:Eu<sup>3+</sup> and Gd<sub>2</sub>O<sub>3</sub>:Eu<sup>3+</sup>[J]. Chinese Journal of Luminescence, 2007,28(3): 383-388 DOI:
通过在Y
2
O
3
:Eu
3+
和Gd
2
O
3
:Eu
3+
发光材料中掺入Li
+
Mg
2+
Al
3+
等离子能有效地提高材料的发光强度
根据分子动力学和密度泛函计算的结果
认为这些离子多倾向于形成
C
2
格位附近的间隙缺陷对
导致部分Y(Gd)
&
mdash;O的键长增加
提高了材料的量子效率的同时使得激发峰位出现红移
是引起材料发光增强的一个原因.
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