LIU Qing, LI You-fen. Preparation and Luminescent Properties of SrGa<sub>2</sub>O<sub>4</sub>:Eu<sup>3+</sup>[J]. Chinese Journal of Luminescence, 2007,28(6): 864-868
LIU Qing, LI You-fen. Preparation and Luminescent Properties of SrGa<sub>2</sub>O<sub>4</sub>:Eu<sup>3+</sup>[J]. Chinese Journal of Luminescence, 2007,28(6): 864-868DOI:
The development of flat panel display devices such as field emission displays (FEDs) and vacuum fluorescent displays (VFDs) requires highly efficient cathodoluminescent materials.While many efficient sulfide-based phosphors have been explored as possible low-voltage phosphors
the volatility of sulfur has prohibited their use in FEDs or VFDs.Sulfide-base phosphors often degrade under high energy electron bombardment due to dissociation of the cation-sulfur bonds.Oxide phosphors offer potential advantage because of their superior stability under electron bombardment and excellent luminescent properties.SrGa
2
O
4
is an attractive oxide phosphor for low-voltage cathodoluminscence applications in VFDs and FEDs.Like other wide bandgap semiconductors
SrGa
2
O
4
exhibits a purple emission.Activation with Eu
3+
ions
the emission shifts to red.The Eu
3+
doped SrGa
2
O
4
phosphor was prepared with the conventional solid-state reaction method.The phase composition was characterized by powder X-ray diffraction.The result shows that the producing powder belongs to monoclinic crystal system with its lattice constants:
a
=0.943 nm
b
=0.900 nm
c
=0.839 nm
β=89.06°
and with space group P2
1
/c(No.14).The excitation and emission spectra were measured.The main peak at 610 nm can be ascribed to the electric dipole transition
5
D
0
→
7
F
2
which indicates that Eu
3+
occupies a site lacking inversion symmetry.The peaks at 590
610 nm transition emission split to two peaks:
5
D
0
→
7
F
1
(586
597 nm) and
5
D
0
→
7
F
2
(609
615 nm)
respectively
due to the crystal-field in the conditions of mole fraction of Eu
3+
with more than 1%.The strength ratio of two parts for the splitting peak
7
F
2
can be changed according to the concentration of Eu