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1. 中国科学技术大学, 物理系, 安徽, 合肥, 230026
2. Institut f&uuml
3. r Experimentalphysikder Uuniversitt Hamburg, Luruper Chaussee 149, 22761 Hamburg, German
收稿:2004-08-22,
修回:2004-12-15,
纸质出版:2006-01-20
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陈永虎, 施朝淑, KIRM M, TRUE M, VIELHAUER S, ZIMMERER G. 长余辉材料Sr<sub>2</sub>MgSi<sub>2</sub>O<sub>7</sub>:Eu<sup>2+</sup>,Dy<sup>3+</sup>中稀土离子的发光特性[J]. 发光学报, 2006,27(1): 41-46
CHEN Yong-hu, SHI Chao-shu, KIRM M, TRUE M, VIELHAUER S, ZIMMERER G. Luminescent Properties of the Rare Earth Ions in Long Afterglow Phosphor Sr<sub>2</sub>MgSi<sub>2</sub>O<sub>7</sub>:Eu<sup>2+</sup>,Dy<sup>3+</sup>[J]. Chinese Journal of Luminescence, 2006,27(1): 41-46
陈永虎, 施朝淑, KIRM M, TRUE M, VIELHAUER S, ZIMMERER G. 长余辉材料Sr<sub>2</sub>MgSi<sub>2</sub>O<sub>7</sub>:Eu<sup>2+</sup>,Dy<sup>3+</sup>中稀土离子的发光特性[J]. 发光学报, 2006,27(1): 41-46 DOI:
CHEN Yong-hu, SHI Chao-shu, KIRM M, TRUE M, VIELHAUER S, ZIMMERER G. Luminescent Properties of the Rare Earth Ions in Long Afterglow Phosphor Sr<sub>2</sub>MgSi<sub>2</sub>O<sub>7</sub>:Eu<sup>2+</sup>,Dy<sup>3+</sup>[J]. Chinese Journal of Luminescence, 2006,27(1): 41-46 DOI:
利用同步辐射光源(德国HASYLAB实验室的SUPERLUMI实验站)和真空紫外激光(157.6nm)对新型蓝光发射长余辉材料Sr
2
MgSi
2
O
7
:Eu
2+
(0.2%)
Dy
3+
(8%)进行了光谱研究。在170nm同步辐射光源激发下
观察到对应Eu
2+
:5d-4f跃迁的477nm发射带和对应Dy
3+
:4f-4f跃迁的两组线谱发射
其中只有来自Eu
2+
的5d-4f发射对长余辉光谱有贡献。在157.6nm激光激发下
除了上述发射外
还明显观察到对应Eu
3+
的红色线谱(590
614
626nm)。结合这些光谱特性
对Sr
2
MgSi
2
O
7
:Eu
2+
Dy
3+
中稀土离子的发光特性以及长余辉发光机理进行了讨论
并提出了Eu
2+
充当空穴陷阱的可能性。
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