Preparation and Luminescent Properties of ZnAl2O4/CaAl12O19∶Mn4+ Phosphors

Gui LIN; Qi LUO; Qian CHEN; Yan-ting LIU; Li-li MENG

doi:10.37188/CJL.20210395

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Preparation and Luminescent Properties of ZnAl₂O₄/CaAl₁₂O₁₉∶Mn⁴⁺ Phosphors

Synthesis and Properties of Materials | Updated：2022-04-20

- Preparation and Luminescent Properties of ZnAl₂O₄/CaAl₁₂O₁₉∶Mn⁴⁺ Phosphors Enhanced Publication
- Chinese Journal of Luminescence Vol.43, Issue 4, (2022)
- Affiliations：
  
  Guangxi Key Laboratory of Natural Polymer Chemistry and Physics, College of Chemistry and Materials, Nanning Normal University,Nanning,China,530001
- Author bio：
- Funds：
  
  National Natural Science Foundation of China(51762008)
- DOI：10.37188/CJL.20210395 CLC： O482.31
- Published：01 April 2022，
  
  Received：16 December 2021，
  
  Revised：29 December 2021，
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Gui LIN, Qi LUO, Qian CHEN, et al. Preparation and Luminescent Properties of ZnAl₂O₄/CaAl₁₂O₁₉∶Mn⁴⁺ Phosphors. [J]. Chinese Journal of Luminescence 43(4):536-544(2022)
DOI：

Gui LIN, Qi LUO, Qian CHEN, et al. Preparation and Luminescent Properties of ZnAl₂O₄/CaAl₁₂O₁₉∶Mn⁴⁺ Phosphors. [J]. Chinese Journal of Luminescence 43(4):536-544(2022) DOI： 10.37188/CJL.20210395.

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"text", "data": "x" } ] }, { "name": "text", "data": "ZnAl" }, { "name": "sub", "data": [ { "name": "text", "data": "2" } ] }, { "name": "text", "data": "O" }, { "name": "sub", "data": [ { "name": "text", "data": "4" } ] }, { "name": "text", "data": "/CaAl" }, { "name": "sub", "data": [ { "name": "text", "data": "12" } ] }, { "name": "text", "data": "O" }, { "name": "sub", "data": [ { "name": "text", "data": "19" } ] }, { "name": "text", "data": "∶Mn" }, { "name": "sup", "data": [ { "name": "text", "data": "4+" } ] }, { "name": "text", "data": "(" }, { "name": "italic", "data": [ { "name": "text", "data": "x" } ] }, { "name": "text", "data": "ZAO/CAO∶Mn" }, { "name": "sup", "data": [ { "name": "text", "data": "4+" } ] }, { "name": "text", "data": ")混合相红光荧光粉，研究了ZnAl" }, { "name": "sub", "data": [ { "name": "text", "data": "2" } ] }, { "name": "text", "data": "O" }, { "name": "sub", "data": [ { "name": "text", "data": "4" } ] }, { "name": "text", "data": "掺杂对CaAl" }, { "name": "sub", "data": [ { "name": "text", "data": "12" } ] }, { "name": "text", "data": "O" }, { "name": "sub", "data": [ { "name": "text", "data": "19" } ] }, { "name": "text", "data": "∶Mn" }, { "name": "sup", "data": [ { "name": "text", "data": "4+" } ] }, { "name": "text", "data": "形貌和发光性能的影响。X射线衍射(XRD)表征结果表明，在1 723 K下煅烧6 h成功合成了" }, { "name": "italic", "data": [ { "name": "text", "data": "x" } ] }, { "name": "text", "data": "ZAO/CAO∶Mn" }, { "name": "sup", "data": [ { "name": "text", "data": "4+" } ] }, { "name": "text", "data": "混合相荧光粉，随着ZnAl" }, { "name": "sub", "data": [ { "name": "text", "data": "2" } ] }, { "name": "text", "data": "O" }, { "name": "sub", "data": [ { "name": "text", "data": "4" } ] }, { "name": "text", "data": "掺杂量的增加依然保持两相共存。荧光光谱分析表明，当" }, { "name": "italic", "data": [ { "name": "text", "data": "x" } ] }, { "name": "text", "data": "=1时，ZAO/CAO∶Mn" }, { "name": "sup", "data": [ { "name": "text", "data": "4+" } ] }, { "name": "text", "data": "具有最大的荧光强度，其值比CaAl" }, { "name": "sub", "data": [ { "name": "text", "data": "12" } ] }, { "name": "text", "data": "O" }, { "name": "sub", "data": [ { "name": "text", "data": "19" } ] }, { "name": "text", "data": "∶Mn" }, { "name": "sup", "data": [ { "name": "text", "data": "4+" } ] }, { "name": "text", "data": "的荧光强度提高了203%。相对于CaAl" }, { "name": "sub", "data": [ { "name": "text", "data": "12" } ] }, { "name": "text", "data": "O" }, { "name": "sub", "data": [ { "name": "text", "data": "19" } ] }, { "name": "text", "data": "∶Mn" }, { "name": "sup", "data": [ { "name": "text", "data": "4+" } ] }, { "name": "text", "data": "荧光粉，ZAO/CAO∶Mn" }, { "name": "sup", "data": [ { "name": "text", "data": "4+" } ] }, { "name": "text", "data": "荧光粉具有更长的荧光寿命，其内量子效率提高了211%。在298~418 K温度范围内，ZAO/CAO∶Mn" }, { "name": "sup", "data": [ { "name": "text", "data": "4+" } ] }, { "name": "text", "data": "荧光粉的绝对灵敏度(" }, { "name": "italic", "data": [ { "name": "text", "data": "S" } ] }, { "name": "sub", "data": [ { "name": "text", "data": "a" } ] }, { "name": "text", "data": ")为4.32×10" }, { "name": "sup", "data": [ { "name": "text", "data": "-3" } ] }, { "name": "text", "data": " K" }, { "name": "sup", "data": [ { "name": "text", "data": "-1" } ] }, { "name": "text", "data": "；在418 K时，最大相对灵敏度(" }, { "name": "italic", "data": [ { "name": "text", "data": "S" } ] }, { "name": "sub", "data": [ { "name": "text", "data": "r" } ] }, { "name": "text", "data": ")为3.65×10" }, { "name": "sup", "data": [ { "name": "text", "data": "-3" } ] }, { "name": "text", "data": " K" }, { "name": "sup", "data": [ { "name": "text", "data": "-1" } ] }, { "name": "text", "data": "。该荧光粉在光学测温方面具有潜在应用价值。" } ] } ] }, { "lang": "en", "data": [ { "name": "p", "data": [ { "name": "text", "data": "A series of " }, { "name": "italic", "data": [ { "name": "text", "data": "x" } ] }, { "name": "text", "data": "ZnAl" }, { "name": "sub", "data": [ { "name": "text", "data": "2" } ] }, { "name": "text", "data": "O" }, { "name": "sub", "data": [ { "name": "text", "data": "4" } ] }, { "name": "text", "data": "/CaAl" }, { "name": "sub", "data": [ { "name": "text", "data": "12" } ] }, { "name": "text", "data": "O" }, { "name": "sub", "data": [ { "name": "text", "data": "19" } ] }, { "name": "text", "data": "∶Mn" }, { "name": "sup", "data": [ { "name": "text", "data": "4+" } ] }, { "name": "text", "data": " (" }, { "name": "italic", "data": [ { "name": "text", "data": "x" } ] }, { "name": "text", "data": "ZAO/CAO∶Mn" }, { "name": "sup", "data": [ { "name": "text", "data": "4+" } ] }, { "name": "text", "data": ") mixed-phase red-emit phosphors were prepared by traditional high-temperature solid-state method. The influence of ZnAl" }, { "name": "sub", "data": [ { "name": "text", "data": "2" } ] }, { "name": "text", "data": "O" }, { "name": "sub", "data": [ { "name": "text", "data": "4" } ] }, { "name": "text", "data": " doping on the morphology and luminescence properties of CaAl" }, { "name": "sub", "data": [ { "name": "text", "data": "12" } ] }, { "name": "text", "data": "O" }, { "name": "sub", "data": [ { "name": "text", "data": "19" } ] }, { "name": "text", "data": "∶Mn" }, { "name": "sup", "data": [ { "name": "text", "data": "4+" } ] }, { "name": "text", "data": " was investigated. The X-ray diffraction(XRD) characterization results show that the mixed-phase phosphors were successfully synthesized after sintered at 1 723 K for 6 h, and the two-phase coexistence is maintained with the increase of ZnAl" }, { "name": "sub", "data": [ { "name": "text", "data": "2" } ] }, { "name": "text", "data": "O" }, { "name": "sub", "data": [ { "name": "text", "data": "4" } ] }, { "name": "text", "data": " doping amount. Fluorescence spectrum shows that ZAO/CAO∶Mn" }, { "name": "sup", "data": [ { "name": "text", "data": "4+" } ] }, { "name": "text", "data": " has the largest fluorescence intensity when " }, { "name": "italic", "data": [ { "name": "text", "data": "x" } ] }, { "name": "text", "data": "=1, which is 203% higher than that of CaAl" }, { "name": "sub", "data": [ { "name": "text", "data": "12" } ] }, { "name": "text", "data": "O" }, { "name": "sub", "data": [ { "name": "text", "data": "19" } ] }, { "name": "text", "data": "∶Mn" }, { "name": "sup", "data": [ { "name": "text", "data": "4+" } ] }, { "name": "text", "data": ". Compared with CaAl" }, { "name": "sub", "data": [ { "name": "text", "data": "12" } ] }, { "name": "text", "data": "O" }, { "name": "sub", "data": [ { "name": "text", "data": "19" } ] }, { "name": "text", "data": "∶Mn" }, { "name": "sup", "data": [ { "name": "text", "data": "4+" } ] }, { "name": "text", "data": " phosphor, the lifetime of ZAO/CAO∶Mn" }, { "name": "sup", "data": [ { "name": "text", "data": "4+" } ] }, { "name": "text", "data": " is improved and internal quantum yield of ZAO/CAO∶Mn" }, { "name": "sup", "data": [ { "name": "text", "data": "4+" } ] }, { "name": "text", "data": " is 211% higher than that of CaAl" }, { "name": "sub", "data": [ { "name": "text", "data": "12" } ] }, { "name": "text", "data": "O" }, { "name": "sub", "data": [ { "name": "text", "data": "19" } ] }, { "name": "text", "data": "∶Mn" }, { "name": "sup", "data": [ { "name": "text", "data": "4+" } ] }, { "name": "text", "data": ". An absolute sensitivity(" }, { "name": "italic", "data": [ { "name": "text", "data": "S" } ] }, { "name": "sub", "data": [ { "name": "text", "data": "a" } ] }, { "name": "text", "data": ") of 4.32×10" }, { "name": "sup", "data": [ { "name": "text", "data": "-3" } ] }, { "name": "text", "data": " K" }, { "name": "sup", "data": [ { "name": "text", "data": "-1" } ] }, { "name": "text", "data": " of the ZAO/CAO∶Mn" }, { "name": "sup", "data": [ { "name": "text", "data": "4+" } ] }, { "name": "text", "data": " phosphor was obtained in the range of 298-418 K and the maximum relative sensitivity(" }, { "name": "italic", "data": [ { "name": "text", "data": "S" } ] }, { "name": "sub", "data": [ { "name": "text", "data": "r" } ] }, { "name": "text", "data": ") was 3.65×10" }, { "name": "sup", "data": [ { "name": "text", "data": "-3" } ] }, { "name": "text", "data": " K" }, { "name": "sup", "data": [ { "name": "text", "data": "-1" } ] }, { "name": "text", "data": " at 418 K, implying that it has potential application value in optical thermometry." } ] } ] } ], "keyword": [ { "lang": "zh", "data": [ [ { "name": "text", "data": "荧光粉" } ], [ { "name": "text", "data": "光学测温" } ], [ { "name": "text", "data": "发光性能" } ], [ { "name": "text", "data": "Mn" }, { "name": "sup", "data": [ { "name": "text", "data": "4+" } ] } ], [ { "name": "text", "data": "ZnAl" }, { "name": "sub", "data": [ { "name": "text", "data": "2" } ] }, { "name": "text", "data": "O" }, { "name": "sub", "data": [ { "name": "text", "data": "4" } ] }, { "name": "text", "data": "/CaAl" }, { "name": "sub", "data": [ { "name": "text", "data": "12" } ] }, { "name": "text", "data": "O" }, { "name": "sub", "data": [ { "name": "text", "data": "19" } ] } ] ] }, { "lang": "en", "data": [ [ { "name": "text", "data": "phosphor" } ], [ { "name": "text", "data": "optical thermometry" } ], [ { "name": "text", "data": "luminescent properties" } ], [ { "name": "text", "data": "Mn" }, { "name": "sup", "data": [ { "name": "text", "data": "4+" } ] } ], [ { "name": "text", "data": "ZnAl" }, { "name": "sub", "data": [ { "name": "text", "data": "2" } ] }, { "name": "text", "data": "O" }, { "name": "sub", "data": [ { "name": "text", "data": "4" } ] }, { "name": "text", "data": "/CaAl" }, { "name": "sub", "data": [ { "name": "text", "data": "12" } ] }, { "name": "text", "data": "O" }, { "name": "sub", "data": [ { "name": "text", "data": "19" } ] } ] ] } ], "highlights": [], "body": [ { "name": "sec", "data": [ { "name": "sectitle", "data": { "label": [ { "name": "text", "data": "1" } ], "title": [ { "name": "text", "data": "引言" } ], "level": "1", "id": "s1" } }, { "name": "p", "data": [ { "name": "text", "data": "温度测量在工业生产、生活和科学研究等各个领域具有重要作用，寻找快速、准确的温度测量手段尤显迫切" }, { "name": "sup", "data": [ { "name": "text", "data": "[" }, { "name": "blockXref", "data": { "data": [ { "name": "xref", "data": { "text": "1", "type": "bibr", "rid": "R1", "data": [ { "name": "text", "data": "1" } ] } }, { "name": "text", "data": "-" }, { "name": "xref", "data": { "text": "3", "type": "bibr", "rid": "R3", "data": [ { "name": "text", "data": "3" } ] } } ], "rid": [ "R1", "R2", "R3" ], "text": "1-3", "type": "bibr" } }, { "name": "text", "data": "]" } ] }, { "name": "text", "data": "。传统的接触式温度测量法效率较低且存在温度平衡过程中测量值低于真实值的问题，另外其无法在纳/微米环境中进行测温" }, { "name": "sup", "data": [ { "name": "text", "data": "[" }, { "name": "xref", "data": { "text": "4", "type": "bibr", "rid": "R4", "data": [ { "name": "text", "data": "4" } ] } }, { "name": "text", "data": "]" } ] }, { "name": "text", "data": "。近年来，具有应用前景的光学测温技术因其快速响应、空间分辨率高和非接触式等优点得到了广泛的关注" }, { "name": "sup", "data": [ { "name": "text", "data": "[" }, { "name": "blockXref", "data": { "data": [ { "name": "xref", "data": { "text": "5", "type": "bibr", "rid": "R5", "data": [ { "name": "text", "data": "5" } ] } }, { "name": "text", "data": "-" }, { "name": "xref", "data": { "text": "6", "type": "bibr", "rid": "R6", "data": [ { "name": "text", "data": "6" } ] } } ], "rid": [ "R5", "R6" ], "text": "5-6", "type": "bibr" } }, { "name": "text", "data": "]" } ] }, { "name": "text", "data": "。" } ] }, { "name": "p", "data": [ { "name": "text", "data": "光学性质中的荧光强度、半峰宽、峰位置以及荧光寿命均与温度有关，可以通过测定其与温度的变化数值确定函数关系从而实现光学测温" }, { "name": "sup", "data": [ { "name": "text", "data": "[" }, { "name": "blockXref", "data": { "data": [ { "name": "xref", "data": { "text": "7", "type": "bibr", "rid": "R7", "data": [ { "name": "text", "data": "7" } ] } }, { "name": "text", "data": "-" }, { "name": "xref", "data": { "text": "10", "type": "bibr", "rid": "R10", "data": [ { "name": "text", "data": "10" } ] } } ], "rid": [ "R7", "R8", "R9", "R10" ], "text": "7-10", "type": "bibr" } }, { "name": "text", "data": "]" } ] }, { "name": "text", "data": "。在荧光强度比(FIR)光学测温中，FIR值主要依赖于温度，与激发光源功率等非温度因素无关且具有自校准机制，已经成为光学测温的首选手段。FIR测温要求光学材料的发射谱中存在热响应不同可区分的发射峰。光学测温核心的光学材料通常采用稀土离子单掺或稀土和过渡金属离子共掺杂的无机荧光粉" }, { "name": "sup", "data": [ { "name": "text", "data": "[" }, { "name": "blockXref", "data": { "data": [ { "name": "xref", "data": { "text": "11", "type": "bibr", "rid": "R11", "data": [ { "name": "text", "data": "11" } ] } }, { "name": "text", "data": "-" }, { "name": "xref", "data": { "text": "12", "type": "bibr", "rid": "R12", "data": [ { "name": "text", "data": "12" } ] } } ], "rid": [ "R11", "R12" ], "text": "11-12", "type": "bibr" } }, { "name": "text", "data": "]" } ] }, { "name": "text", "data": "。稀土离子单掺杂荧光粉利用稀土离子相邻热耦合能级的FIR随温度变化的函数关系进行光学测温，但其存在信号难于识别和相对灵敏度较低等问题" }, { "name": "sup", "data": [ { "name": "text", "data": "[" }, { "name": "blockXref", "data": { "data": [ { "name": "xref", "data": { "text": "13", "type": "bibr", "rid": "R13", "data": [ { "name": "text", "data": "13" } ] } }, { "name": "text", "data": "-" }, { "name": "xref", "data": { "text": "15", "type": "bibr", "rid": "R15", "data": [ { "name": "text", "data": "15" } ] } } ], "rid": [ "R13", "R14", "R15" ], "text": "13-15", "type": "bibr" } }, { "name": "text", "data": "]" } ] }, { "name": "text", "data": "；稀土和过渡金属离子共掺杂的荧光粉通过两个独立发射中心的双发射热响应实现测温，过渡金属常选用Mn" }, { "name": "sup", "data": [ { "name": "text", "data": "4+" } ] }, { "name": "text", "data": "离子，但由于缺乏满足Mn" }, { "name": "sup", "data": [ { "name": "text", "data": "4+" } ] }, { "name": "text", "data": "窄峰发射的基质，限制了该类材料在光学测温的应用" }, { "name": "sup", "data": [ { "name": "text", "data": "[" }, { "name": "blockXref", "data": { "data": [ { "name": "xref", "data": { "text": "16", "type": "bibr", "rid": "R16", "data": [ { "name": "text", "data": "16" } ] } }, { "name": "text", "data": "-" }, { "name": "xref", "data": { "text": "18", "type": "bibr", "rid": "R18", "data": [ { "name": "text", "data": "18" } ] } } ], "rid": [ "R16", "R17", "R18" ], "text": "16-18", "type": "bibr" } }, { "name": "text", "data": "]" } ] }, { "name": "text", "data": "。Mn" }, { "name": "sup", "data": [ { "name": "text", "data": "4+" } ] }, { "name": "text", "data": "单掺杂荧光粉的发射谱中通常包含多组发射峰，且每组峰在温度变化时通常表现不同的发射行为，因此过渡金属离子Mn" }, { "name": "sup", "data": [ { "name": "text", "data": "4+" } ] }, { "name": "text", "data": "单掺荧光粉具有光学测温应用的潜力。Yang等" }, { "name": "sup", "data": [ { "name": "text", "data": "[" }, { "name": "xref", "data": { "text": "19", "type": "bibr", "rid": "R19", "data": [ { "name": "text", "data": "19" } ] } }, { "name": "text", "data": "]" } ] }, { "name": "text", "data": "采用共沉淀法合成了SrAl" }, { "name": "sub", "data": [ { "name": "text", "data": "12" } ] }, { "name": "text", "data": "O" }, { "name": "sub", "data": [ { "name": "text", "data": "19" } ] }, { "name": "text", "data": "∶Mn" }, { "name": "sup", "data": [ { "name": "text", "data": "4+" } ] }, { "name": "text", "data": "荧光粉，并基于FIR研究了其在光学测温的应用，其在293~393 K范围内的" }, { "name": "italic", "data": [ { "name": "text", "data": "S" } ] }, { "name": "sub", "data": [ { "name": "text", "data": "a" } ] }, { "name": "text", "data": "为4.17×10" }, { "name": "sup", "data": [ { "name": "text", "data": "-3" } ] }, { "name": "text", "data": " K" }, { "name": "sup", "data": [ { "name": "text", "data": "-1" } ] }, { "name": "text", "data": ";Cai等" }, { "name": "sup", "data": [ { "name": "text", "data": "[" }, { "name": "xref", "data": { "text": "20", "type": "bibr", "rid": "R20", "data": [ { "name": "text", "data": "20" } ] } }, { "name": "text", "data": "]" } ] }, { "name": "text", "data": "通过两步湿化学法成功地合成了新型的Cs" }, { "name": "sub", "data": [ { "name": "text", "data": "2" } ] }, { "name": "text", "data": "WO" }, { "name": "sub", "data": [ { "name": "text", "data": "2" } ] }, { "name": "text", "data": "F" }, { "name": "sub", "data": [ { "name": "text", "data": "4" } ] }, { "name": "text", "data": "∶Mn" }, { "name": "sup", "data": [ { "name": "text", "data": "4+" } ] }, { "name": "text", "data": "红光荧光粉，在10~500 K温度范围内讨论了其在光学测温的应用。对于CaAl" }, { "name": "sub", "data": [ { "name": "text", "data": "12" } ] }, { "name": "text", "data": "O" }, { "name": "sub", "data": [ { "name": "text", "data": "19" } ] }, { "name": "text", "data": "∶Mn" }, { "name": "sup", "data": [ { "name": "text", "data": "4+" } ] }, { "name": "text", "data": "发射峰中主峰是源于Mn" }, { "name": "sup", "data": [ { "name": "text", "data": "4+" } ] }, { "name": "text", "data": "的" }, { "name": "sup", "data": [ { "name": "text", "data": "2" } ] }, { "name": "text", "data": "E" }, { "name": "sub", "data": [ { "name": "text", "data": "g" } ] }, { "name": "text", "data": "→" }, { "name": "sup", "data": [ { "name": "text", "data": "4" } ] }, { "name": "text", "data": "A" }, { "name": "sub", "data": [ { "name": "text", "data": "2" } ] }, { "name": "text", "data": "电子跃迁而产生，而两侧的肩峰为声子副带发射，这组峰的发射强度受温度影响不同，因此CaAl" }, { "name": "sub", "data": [ { "name": "text", "data": "12" } ] }, { "name": "text", "data": "O" }, { "name": "sub", "data": [ { "name": "text", "data": "19" } ] }, { "name": "text", "data": "∶Mn" }, { "name": "sup", "data": [ { "name": "text", "data": "4+" } ] }, { "name": "text", "data": "荧光粉可作为光学测温材料。CaAl" }, { "name": "sub", "data": [ { "name": "text", "data": "12" } ] }, { "name": "text", "data": "O" }, { "name": "sub", "data": [ { "name": "text", "data": "19" } ] }, { "name": "text", "data": "∶Mn" }, { "name": "sup", "data": [ { "name": "text", "data": "4+" } ] }, { "name": "text", "data": "发光强度不高，影响其在光学测温上的响应信号，因此，提高CaAl" }, { "name": "sub", "data": [ { "name": "text", "data": "12" } ] }, { "name": "text", "data": "O" }, { "name": "sub", "data": [ { "name": "text", "data": "19" } ] }, { "name": "text", "data": "∶Mn" }, { "name": "sup", "data": [ { "name": "text", "data": "4+" } ] }, { "name": "text", "data": "的发光强度是解决其在光学测温上应用的关键问题。基于Wu等" }, { "name": "sup", "data": [ { "name": "text", "data": "[" }, { "name": "xref", "data": { "text": "21", "type": "bibr", "rid": "R21", "data": [ { "name": "text", "data": "21" } ] } }, { "name": "text", "data": "]" } ] }, { "name": "text", "data": "通过CaAl" }, { "name": "sub", "data": [ { "name": "text", "data": "12" } ] }, { "name": "text", "data": "-O" }, { "name": "sub", "data": [ { "name": "text", "data": "19" } ] }, { "name": "text", "data": "∶Mn" }, { "name": "sup", "data": [ { "name": "text", "data": "4+" } ] }, { "name": "text", "data": "掺杂MgAl" }, { "name": "sub", "data": [ { "name": "text", "data": "2" } ] }, { "name": "text", "data": "O" }, { "name": "sub", "data": [ { "name": "text", "data": "4" } ] }, { "name": "text", "data": "相增强其发光强度工作的启发，本课题组研究了掺杂ZnAl" }, { "name": "sub", "data": [ { "name": "text", "data": "2" } ] }, { "name": "text", "data": "O" }, { "name": "sub", "data": [ { "name": "text", "data": "4" } ] }, { "name": "text", "data": "相对CaAl" }, { "name": "sub", "data": [ { "name": "text", "data": "12" } ] }, { "name": "text", "data": "O" }, { "name": "sub", "data": [ { "name": "text", "data": "19" } ] }, { "name": "text", "data": "∶Mn" }, { "name": "sup", "data": [ { "name": "text", "data": "4+" } ] }, { "name": "text", "data": "荧光粉发光性能的影响，并对ZnAl" }, { "name": "sub", "data": [ { "name": "text", "data": "2" } ] }, { "name": "text", "data": "O" }, { "name": "sub", "data": [ { "name": "text", "data": "4" } ] }, { "name": "text", "data": "/CaAl" }, { "name": "sub", "data": [ { "name": "text", "data": "12" } ] }, { "name": "text", "data": "O" }, { "name": "sub", "data": [ { "name": "text", "data": "19" } ] }, { "name": "text", "data": "∶Mn" }, { "name": "sup", "data": [ { "name": "text", "data": "4+" } ] }, { "name": "text", "data": "在光学测温方面的应用进行了探讨。" } ] }, { "name": "p", "data": [ { "name": "text", "data": "本文采用传统的高温固相法合成了" }, { "name": "italic", "data": [ { "name": "text", "data": "x" } ] }, { "name": "text", "data": "ZnAl" }, { "name": "sub", "data": [ { "name": "text", "data": "2" } ] }, { "name": "text", "data": "O" }, { "name": "sub", "data": [ { "name": "text", "data": "4" } ] }, { "name": "text", "data": "/CaAl" }, { "name": "sub", "data": [ { "name": "text", "data": "12" } ] }, { "name": "text", "data": "O" }, { "name": "sub", "data": [ { "name": "text", "data": "19" } ] }, { "name": "text", "data": "∶Mn" }, { "name": "sup", "data": [ { "name": "text", "data": "4+" } ] }, { "name": "text", "data": "系列红光荧光粉，并对其形貌、晶体结构、发光性能以及浓度猝灭机理进行了研究，同时讨论了其在298~418 K范围内实现光学测温的可行性。" } ] } ] }, { "name": "sec", "data": [ { "name": "sectitle", "data": { "label": [ { "name": "text", "data": "2" } ], "title": [ { "name": "text", "data": "实验" } ], "level": "1", "id": "s2" } }, { "name": "sec", "data": [ { "name": "sectitle", "data": { "label": [ { "name": "text", "data": "2.1" } ], "title": [ { "name": "text", "data": "样品制备" } ], "level": "2", "id": "s2a" } }, { "name": "p", "data": [ { "name": "text", "data": "采用高温固相法制备了系列" }, { "name": "italic", "data": [ { "name": "text", "data": "x" } ] }, { "name": "text", "data": "ZnAl" }, { "name": "sub", "data": [ { "name": "text", "data": "2" } ] }, { "name": "text", "data": "O" }, { "name": "sub", "data": [ { "name": "text", "data": "4" } ] }, { "name": "text", "data": "/CaAl" }, { "name": "sub", "data": [ { "name": "text", "data": "12" } ] }, { "name": "text", "data": "-O" }, { "name": "sub", "data": [ { "name": "text", "data": "19" } ] }, { "name": "text", "data": "∶0.04Mn" }, { "name": "sup", "data": [ { "name": "text", "data": "4+" } ] }, { "name": "text", "data": "(" }, { "name": "italic", "data": [ { "name": "text", "data": "x" } ] }, { "name": "text", "data": "=0,0.5,1,2,3)和ZnAl" }, { "name": "sub", "data": [ { "name": "text", "data": "2" } ] }, { "name": "text", "data": "O" }, { "name": "sub", "data": [ { "name": "text", "data": "4" } ] }, { "name": "text", "data": "/CaAl" }, { "name": "sub", "data": [ { "name": "text", "data": "12" } ] }, { "name": "text", "data": "-O" }, { "name": "sub", "data": [ { "name": "text", "data": "19" } ] }, { "name": "text", "data": "∶" }, { "name": "italic", "data": [ { "name": "text", "data": "z" } ] }, { "name": "text", "data": "Mn" }, { "name": "sup", "data": [ { "name": "text", "data": "4+" } ] }, { "name": "text", "data": "(" }, { "name": "italic", "data": [ { "name": "text", "data": "z" } ] }, { "name": "text", "data": "=0.02,0.04,0.06,0.08,0.1)荧光粉(缩写为：" }, { "name": "italic", "data": [ { "name": "text", "data": "x" } ] }, { "name": "text", "data": "ZAO/CAO∶Mn" }, { "name": "sup", "data": [ { "name": "text", "data": "4+" } ] }, { "name": "text", "data": "," }, { "name": "italic", "data": [ { "name": "text", "data": "x" } ] }, { "name": "text", "data": "为ZAO和CAO的物质的量比，" }, { "name": "italic", "data": [ { "name": "text", "data": "z" } ] }, { "name": "text", "data": "为Mn" }, { "name": "sup", "data": [ { "name": "text", "data": "4+" } ] }, { "name": "text", "data": "的浓度)。以分析纯ZnO、CaCO" }, { "name": "sub", "data": [ { "name": "text", "data": "3" } ] }, { "name": "text", "data": "、Al" }, { "name": "sub", "data": [ { "name": "text", "data": "2" } ] }, { "name": "text", "data": "O" }, { "name": "sub", "data": [ { "name": "text", "data": "3" } ] }, { "name": "text", "data": "、MnCO" }, { "name": "sub", "data": [ { "name": "text", "data": "3" } ] }, { "name": "text", "data": "为原料，按照" }, { "name": "italic", "data": [ { "name": "text", "data": "x" } ] }, { "name": "text", "data": "ZAO/CAO∶0.04Mn" }, { "name": "sup", "data": [ { "name": "text", "data": "4+" } ] }, { "name": "text", "data": "和ZAO/CAO∶" }, { "name": "italic", "data": [ { "name": "text", "data": "z" } ] }, { "name": "text", "data": "Mn" }, { "name": "sup", "data": [ { "name": "text", "data": "4+" } ] }, { "name": "text", "data": "产物的化学计量比称取原料，以质量百分比5%加入H" }, { "name": "sub", "data": [ { "name": "text", "data": "3" } ] }, { "name": "text", "data": "BO" }, { "name": "sub", "data": [ { "name": "text", "data": "3" } ] }, { "name": "text", "data": "作为助溶剂，将以上原料在玛瑙研钵中研磨40 min，转移至刚玉坩埚后放置于马弗炉，在空气氛围下于1 723 K下煅烧6 h。样品自然冷却至室温，再次研磨，以备后续表征使用。" } ] } ] }, { "name": "sec", "data": [ { "name": "sectitle", "data": { "label": [ { "name": "text", "data": "2.2" } ], "title": [ { "name": "text", "data": "样品表征" } ], "level": "2", "id": "s2b" } }, { "name": "p", "data": [ { "name": "text", "data": "采用荷兰帕纳科公司 X’Pert PRO 型多晶X射线衍射仪测试样品10°~80°范围内的XRD谱，管电流为40 mA，管电压为40 kV，辐射源为Cu 靶(" }, { "name": "italic", "data": [ { "name": "text", "data": "λ" } ] }, { "name": "text", "data": "=0.154 060 nm)，采集步长为0.013°，每步停留时间40 s；采用日本日立公司 F-4600 荧光光谱仪测试样品的荧光性质，激发光源为150 W氙灯；通过 Orient KOJI 300 ℃ 高温荧光(热猝灭)分析仪测试样品的变温光谱；采用日本日立公司S4800冷场发射扫描电镜显微镜进行样品形貌表征；采用英国爱丁堡仪器公司 FLS980 全功能型稳态/瞬态荧光光谱仪测试样品的荧光寿命和内量子效率。" } ] } ] } ] }, { "name": "sec", "data": [ { "name": "sectitle", "data": { "label": [ { "name": "text", "data": "3" } ], "title": [ { "name": "text", "data": "结果与讨论" } ], "level": "1", "id": "s3" } }, { "name": "sec", "data": [ { "name": "sectitle", "data": { "label": [ { "name": "text", "data": "3.1" } ], "title": [ { "name": "text", "data": "晶体结构与形貌分析" } ], "level": "2", "id": "s3a" } }, { "name": "p", "data": [ { "name": "xref", "data": { "text": "图1", "type": "fig", "rid": "F1", "data": [ { "name": "text", "data": "图1" } ] } }, { "name": "text", "data": "为采用Diamond程序绘制CAO和ZAO的晶胞结构图。从图中看到，CAO具有六方晶体结构，空间群为" }, { "name": "italic", "data": [ { "name": "text", "data": "P" } ] }, { "name": "text", "data": "63/" }, { "name": "italic", "data": [ { "name": "text", "data": "mmc" } ] }, { "name": "text", "data": "，其中Al" }, { "name": "sup", "data": [ { "name": "text", "data": "3+" } ] }, { "name": "text", "data": "分布在5种不同的配位环境，包括3种不同的八面体配位、1种四面体配位和1种五配位三角双锥位" }, { "name": "sup", "data": [ { "name": "text", "data": "[" }, { "name": "blockXref", "data": { "data": [ { "name": "xref", "data": { "text": "22", "type": "bibr", "rid": "R22", "data": [ { "name": "text", "data": "22" } ] } }, { "name": "text", "data": "-" }, { "name": "xref", "data": { "text": "23", "type": "bibr", "rid": "R23", "data": [ { "name": "text", "data": "23" } ] } } ], "rid": [ "R22", "R23" ], "text": "22-23", "type": "bibr" } }, { "name": "text", "data": "]" } ] }, { "name": "text", "data": "。ZAO具有尖晶石结构，属于立方晶体结构，空间群为" }, { "name": "italic", "data": [ { "name": "text", "data": "Fd" } ] }, { "name": "text", "data": "-3" }, { "name": "italic", "data": [ { "name": "text", "data": "m" } ] }, { "name": "text", "data": "，其中Zn" }, { "name": "sup", "data": [ { "name": "text", "data": "2+" } ] }, { "name": "text", "data": "占据四面体位置、Al" }, { "name": "sup", "data": [ { "name": "text", "data": "3+" } ] }, { "name": "text", "data": "占据八面体位置" }, { "name": "sup", "data": [ { "name": "text", "data": "[" }, { "name": "blockXref", "data": { "data": [ { "name": "xref", "data": { "text": "24", "type": "bibr", "rid": "R24", "data": [ { "name": "text", "data": "24" } ] } }, { "name": "text", "data": "-" }, { "name": "xref", "data": { "text": "25", "type": "bibr", "rid": "R25", "data": [ { "name": "text", "data": "25" } ] } } ], "rid": [ "R24", "R25" ], "text": "24-25", "type": "bibr" } }, { "name": "text", "data": "]" } ] }, { "name": "text", "data": "。" } ] }, { "name": "fig", "data": { "id": "F1", "caption": [ { "lang": "zh", "label": [ { "name": "text", "data": "图1" } ], "title": [ { "name": "text", "data": "CAO和ZAO的晶胞结构示意图" } ] }, { "lang": "en", "label": [ { "name": "text", "data": "Fig. 1" } ], "title": [ { "name": "text", "data": "Schematic illustration of crystal structure of the CAO and the ZAO host" } ] } ], "subcaption": [], "note": [], "graphics": [ { "print": "http://html.publish.founderss.cn/rc-pub/api/common/picture?pictureId=26724499&type=", "small": "http://html.publish.founderss.cn/rc-pub/api/common/picture?pictureId=26724509&type=", "big": "http://html.publish.founderss.cn/rc-pub/api/common/picture?pictureId=26724489&type=" } ] } }, { "name": "p", "data": [ { "name": "italic", "data": [ { "name": "text", "data": "x" } ] }, { "name": "text", "data": "ZAO/CAO∶0.04Mn" }, { "name": "sup", "data": [ { "name": "text", "data": "4+" } ] }, { "name": "text", "data": " (" }, { "name": "italic", "data": [ { "name": "text", "data": "x" } ] }, { "name": "text", "data": "=0,0.5,1,2,3) 荧光粉的XRD图谱见" }, { "name": "xref", "data": { "text": "图2(a)", "type": "fig", "rid": "F2", "data": [ { "name": "text", "data": "图2(a)" } ] } }, { "name": "text", "data": "。由" }, { "name": "xref", "data": { "text": "图2", "type": "fig", "rid": "F2", "data": [ { "name": "text", "data": "图2" } ] } }, { "name": "text", "data": "可以看到，CAO∶Mn" }, { "name": "sup", "data": [ { "name": "text", "data": "4+" } ] }, { "name": "text", "data": " (" }, { "name": "italic", "data": [ { "name": "text", "data": "x" } ] }, { "name": "text", "data": "=0)的所有衍射峰数目及位置与CaAl" }, { "name": "sub", "data": [ { "name": "text", "data": "12" } ] }, { "name": "text", "data": "O" }, { "name": "sub", "data": [ { "name": "text", "data": "19" } ] }, { "name": "text", "data": "标准卡(PDF#38-0470)一致，说明合成了CAO样品；不同物质的量的ZAO掺入后，XRD谱图中除了CaAl" }, { "name": "sub", "data": [ { "name": "text", "data": "12" } ] }, { "name": "text", "data": "O" }, { "name": "sub", "data": [ { "name": "text", "data": "19" } ] }, { "name": "text", "data": "衍射峰外，新的衍射峰与ZnAl" }, { "name": "sub", "data": [ { "name": "text", "data": "2" } ] }, { "name": "text", "data": "O" }, { "name": "sub", "data": [ { "name": "text", "data": "4" } ] }, { "name": "text", "data": "标准卡(PDF#05-0669)的衍射峰一致。" }, { "name": "xref", "data": { "text": "图2(b)", "type": "fig", "rid": "F2", "data": [ { "name": "text", "data": "图2(b)" } ] } }, { "name": "text", "data": "为混合相" }, { "name": "italic", "data": [ { "name": "text", "data": "x" } ] }, { "name": "text", "data": "ZAO/CAO∶Mn" }, { "name": "sup", "data": [ { "name": "text", "data": "4+" } ] }, { "name": "text", "data": "的Rietveld精修XRD图谱，精修结果见" }, { "name": "xref", "data": { "text": "表1", "type": "table", "rid": "T1", "data": [ { "name": "text", "data": "表1" } ] } }, { "name": "text", "data": "。由" }, { "name": "xref", "data": { "text": "表1", "type": "table", "rid": "T1", "data": [ { "name": "text", "data": "表1" } ] } }, { "name": "text", "data": "可以看到，精修结果得到的混合相样品物质的量比值与理论物质的量比值接近，说明合成了不同物质的量比的混合相荧光粉。" }, { "name": "xref", "data": { "text": "图2(c)", "type": "fig", "rid": "F2", "data": [ { "name": "text", "data": "图2(c)" } ] } }, { "name": "text", "data": "为" }, { "name": "italic", "data": [ { "name": "text", "data": "x" } ] }, { "name": "text", "data": "ZAO/CAO∶Mn" }, { "name": "sup", "data": [ { "name": "text", "data": "4+" } ] }, { "name": "text", "data": " (" }, { "name": "italic", "data": [ { "name": "text", "data": "x" } ] }, { "name": "text", "data": "=0, 0.5, 1, 2, 3) 的扫描电子显微镜(SEM)图，可以看到CAO呈六方片状，层层堆叠在一起；掺杂ZAO后，无规则颗粒状的晶粒无序堆积在六方片状的表面上，增大ZAO的掺杂量，颗粒状晶粒增多，部分穿插在六方片的层之间，部分六方片状晶体被晶粒所包覆。" } ] }, { "name": "fig", "data": { "id": "F2", "caption": [ { "lang": "zh", "label": [ { "name": "text", "data": "图2" } ], "title": [ { "name": "text", "data": "　" }, { "name": "italic", "data": [ { "name": "text", "data": "x" } ] }, { "name": "text", "data": "ZAO/CAO∶0.04Mn" }, { "name": "sup", "data": [ { "name": "text", "data": "4+" } ] }, { "name": "text", "data": "荧光粉的XRD(a)、Rietveld精修XRD(b)及SEM(c)图谱。" } ] }, { "lang": "en", "label": [ { "name": "text", "data": "Fig. 2" } ], "title": [ { "name": "text", "data": "(a)Powder XRD patterns of " }, { "name": "italic", "data": [ { "name": "text", "data": "x" } ] }, { "name": "text", "data": "ZAO/CAO∶0.04Mn" }, { "name": "sup", "data": [ { "name": "text", "data": "4+" } ] }, { "name": "text", "data": " (" }, { "name": "italic", "data": [ { "name": "text", "data": "x" } ] }, { "name": "text", "data": "=0, 0.5, 1, 2, 3) phosphors. (b)Rietveld refinement XRD patterns of " }, { "name": "italic", "data": [ { "name": "text", "data": "x" } ] }, { "name": "text", "data": "ZAO/CAO∶0.04Mn" }, { "name": "sup", "data": [ { "name": "text", "data": "4+" } ] }, { "name": "text", "data": " (" }, { "name": "italic", "data": [ { "name": "text", "data": "x" } ] }, { "name": "text", "data": "=0.5, 1, 2, 3) phosphors.(c)SEM images of " }, { "name": "italic", "data": [ { "name": "text", "data": "x" } ] }, { "name": "text", "data": "ZAO/CAO∶0.04Mn" }, { "name": "sup", "data": [ { "name": "text", "data": "4+" } ] }, { "name": "text", "data": " (" }, { "name": "italic", "data": [ { "name": "text", "data": "x" } ] }, { "name": "text", "data": "=0, 0.5, 1, 2, 3) phosphors." } ] } ], "subcaption": [], "note": [], "graphics": [ { "print": "http://html.publish.founderss.cn/rc-pub/api/common/picture?pictureId=26724504&type=", "small": "http://html.publish.founderss.cn/rc-pub/api/common/picture?pictureId=26724524&type=", "big": "http://html.publish.founderss.cn/rc-pub/api/common/picture?pictureId=26724506&type=" } ] } }, { "name": "table", "data": { "id": "T1", "caption": [ { "lang": "zh", "label": [ { "name": "text", "data": "表1" } ], "title": [ { "name": "italic", "data": [ { "name": "text", "data": "x" } ] }, { "name": "text", "data": "ZAO/CAO∶0.04Mn" }, { "name": "sup", "data": [ { "name": "text", "data": "4+" } ] }, { "name": "text", "data": "荧光粉的Rietveld精修XRD结果" } ] }, { "lang": "en", "label": [ { "name": "text", "data": "Tab. 1" } ], "title": [ { "name": "text", "data": "Rietveld XRD results of " }, { "name": "italic", "data": [ { "name": "text", "data": "x" } ] }, { "name": "text", "data": "ZAO/CAO∶0.04Mn" }, { "name": "sup", "data": [ { "name": "text", "data": "4+" } ] } ] } ], "note": [], "table": [ { "head": [ [ { "colspan": "1", "rowspan": "1", "align": "center", "style": "border-top:1px solid #000;border-bottom:1px solid #000;", "data": [ { "name": "text", "data": "样品编号" } ] }, { "colspan": "1", "rowspan": "1", "align": "center", "style": "border-top:1px solid #000;border-bottom:1px solid #000;", "data": [ { "name": "text", "data": "理论物质的量比(" }, { "name": "italic", "data": [ { "name": "text", "data": "n" } ] }, { "name": "sub", "data": [ { "name": "text", "data": "ZAO" } ] }, { "name": "text", "data": "/" }, { "name": "italic", "data": [ { "name": "text", "data": "n" } ] }, { "name": "sub", "data": [ { "name": "text", "data": "CAO" } ] }, { "name": "text", "data": ")" } ] }, { "colspan": "1", "rowspan": "1", "align": "center", "style": "border-top:1px solid #000;border-bottom:1px solid #000;", "data": [ { "name": "text", "data": "Rietveld精修后物质的量比(" }, { "name": "italic", "data": [ { "name": "text", "data": "n" } ] }, { "name": "sub", "data": [ { "name": "text", "data": "ZAO" } ] }, { "name": "text", "data": "/" }, { "name": "italic", "data": [ { "name": "text", "data": "n" } ] }, { "name": "sub", "data": [ { "name": "text", "data": "CAO" } ] }, { "name": "text", "data": ")" } ] }, { "colspan": "1", "rowspan": "1", "align": "center", "style": "border-top:1px solid #000;border-bottom:1px solid #000;", "data": [ { "name": "italic", "data": [ { "name": "text", "data": "R" } ] }, { "name": "sub", "data": [ { "name": "text", "data": "wp" } ] }, { "name": "text", "data": "/%" } ] }, { "colspan": "1", "rowspan": "1", "align": "center", "style": "border-top:1px solid #000;border-bottom:1px solid #000;", "data": [ { "name": "italic", "data": [ { "name": "text", "data": "R" } ] }, { "name": "sub", "data": [ { "name": "text", "data": "P" } ] }, { "name": "text", "data": "/%" } ] } ] ], "body": [ [ { "colspan": "1", "rowspan": "1", "align": "center", "data": [ { "name": "text", "data": "1" } ] }, { "colspan": "1", "rowspan": "1", "align": "center", "data": [ { "name": "text", "data": "0.5∶1" } ] }, { "colspan": "1", "rowspan": "1", "align": "center", "data": [ { "name": "text", "data": "0.49∶1.00" } ] }, { "colspan": "1", "rowspan": "1", "align": "center", "data": [ { "name": "text", "data": "9.19" } ] }, { "colspan": "1", "rowspan": "1", "align": "center", "data": [ { "name": "text", "data": "6.02" } ] } ], [ { "colspan": "1", "rowspan": "1", "align": "center", "data": [ { "name": "text", "data": "2" } ] }, { "colspan": "1", "rowspan": "1", "align": "center", "data": [ { "name": "text", "data": "1∶1" } ] }, { "colspan": "1", "rowspan": "1", "align": "center", "data": [ { "name": "text", "data": "1.06∶1.00" } ] }, { "colspan": "1", "rowspan": "1", "align": "center", "data": [ { "name": "text", "data": "8.99" } ] }, { "colspan": "1", "rowspan": "1", "align": "center", "data": [ { "name": "text", "data": "6.06" } ] } ], [ { "colspan": "1", "rowspan": "1", "align": "center", "data": [ { "name": "text", "data": "3" } ] }, { "colspan": "1", "rowspan": "1", "align": "center", "data": [ { "name": "text", "data": "2∶1" } ] }, { "colspan": "1", "rowspan": "1", "align": "center", "data": [ { "name": "text", "data": "1.90∶1.00" } ] }, { "colspan": "1", "rowspan": "1", "align": "center", "data": [ { "name": "text", "data": "10.88" } ] }, { "colspan": "1", "rowspan": "1", "align": "center", "data": [ { "name": "text", "data": "7.88" } ] } ], [ { "colspan": "1", "rowspan": "1", "align": "center", "style": "border-bottom:1px solid #000;", "data": [ { "name": "text", "data": "4" } ] }, { "colspan": "1", "rowspan": "1", "align": "center", "style": "border-bottom:1px solid #000;", "data": [ { "name": "text", "data": "3: 1" } ] }, { "colspan": "1", "rowspan": "1", "align": "center", "style": "border-bottom:1px solid #000;", "data": [ { "name": "text", "data": "2.91∶1.00" } ] }, { "colspan": "1", "rowspan": "1", "align": "center", "style": "border-bottom:1px solid #000;", "data": [ { "name": "text", "data": "8.29" } ] }, { "colspan": "1", "rowspan": "1", "align": "center", "style": "border-bottom:1px solid #000;", "data": [ { "name": "text", "data": "5.69" } ] } ] ], "foot": [] } ] } } ] }, { "name": "sec", "data": [ { "name": "sectitle", "data": { "label": [ { "name": "text", "data": "3.2" } ], "title": [ { "name": "text", "data": "ZAO/CAO∶Mn" }, { "name": "sup", "data": [ { "name": "text", "data": "4+" } ] }, { "name": "text", "data": "发光性能" } ], "level": "2", "id": "s3b" } }, { "name": "p", "data": [ { "name": "text", "data": "通常认为Mn" }, { "name": "sup", "data": [ { "name": "text", "data": "4+" } ] }, { "name": "text", "data": "占据八面体格位会产生红光发射，Mn" }, { "name": "sup", "data": [ { "name": "text", "data": "4+" } ] }, { "name": "text", "data": "(" }, { "name": "italic", "data": [ { "name": "text", "data": "r" } ] }, { "name": "text", "data": "=53.0 pm)和Al" }, { "name": "sup", "data": [ { "name": "text", "data": "3+" } ] }, { "name": "text", "data": "(" }, { "name": "italic", "data": [ { "name": "text", "data": "r" } ] }, { "name": "text", "data": "=53.5 pm)的离子半径近似，根据半径相似占据原则，所以Mn" }, { "name": "sup", "data": [ { "name": "text", "data": "4+" } ] }, { "name": "text", "data": "倾向于占据基质中Al" }, { "name": "sup", "data": [ { "name": "text", "data": "3+" } ] }, { "name": "text", "data": "的八面体格位。从" }, { "name": "xref", "data": { "text": "图1", "type": "fig", "rid": "F1", "data": [ { "name": "text", "data": "图1" } ] } }, { "name": "text", "data": "晶胞结构图可知，ZAO和CAO基质中都含有Al" }, { "name": "sup", "data": [ { "name": "text", "data": "3+" } ] }, { "name": "text", "data": "的八面体格位，为此进行了Mn" }, { "name": "sup", "data": [ { "name": "text", "data": "4+" } ] }, { "name": "text", "data": "选择性替代探究实验。在相同的实验条件下，分别合成ZAO、CAO、ZAO/CAO为基质的锰离子掺杂荧光粉。" }, { "name": "xref", "data": { "text": "图3(a)~(c)", "type": "fig", "rid": "F3", "data": [ { "name": "text", "data": "图3(a)~(c)" } ] } }, { "name": "text", "data": "分别为以上三种基质的激发和发射谱图。由" }, { "name": "xref", "data": { "text": "图3(a)", "type": "fig", "rid": "F3", "data": [ { "name": "text", "data": "图3(a)" } ] } }, { "name": "text", "data": "可以看到，锰离子掺杂ZAO的发射峰位于520 nm，说明在该基质中锰离子以Mn" }, { "name": "sup", "data": [ { "name": "text", "data": "2+" } ] }, { "name": "text", "data": "存在。由" }, { "name": "xref", "data": { "text": "图3(b)、(c)", "type": "fig", "rid": "F3", "data": [ { "name": "text", "data": "图3(b)、(c)" } ] } }, { "name": "text", "data": "可以看到，锰离子激活的CAO和ZAO/CAO荧光粉发射峰的形状和峰位置一致，与Zhu等" }, { "name": "sup", "data": [ { "name": "text", "data": "[" }, { "name": "blockXref", "data": { "data": [ { "name": "xref", "data": { "text": "26", "type": "bibr", "rid": "R26", "data": [ { "name": "text", "data": "26" } ] } }, { "name": "text", "data": "-" }, { "name": "xref", "data": { "text": "27", "type": "bibr", "rid": "R27", "data": [ { "name": "text", "data": "27" } ] } } ], "rid": [ "R26", "R27" ], "text": "26-27", "type": "bibr" } }, { "name": "text", "data": "]" } ] }, { "name": "text", "data": "报道的CAO∶Mn" }, { "name": "sup", "data": [ { "name": "text", "data": "4+" } ] }, { "name": "text", "data": "相符，并且在454 nm的激发下，ZAO/CAO∶Mn" }, { "name": "sup", "data": [ { "name": "text", "data": "4+" } ] }, { "name": "text", "data": "的发射谱图中没有检测到520 nm处的发射峰。由此判断，在ZnAl" }, { "name": "sub", "data": [ { "name": "text", "data": "2" } ] }, { "name": "text", "data": "O" }, { "name": "sub", "data": [ { "name": "text", "data": "4" } ] }, { "name": "text", "data": "/CaAl" }, { "name": "sub", "data": [ { "name": "text", "data": "12" } ] }, { "name": "text", "data": "O" }, { "name": "sub", "data": [ { "name": "text", "data": "19" } ] }, { "name": "text", "data": "∶Mn" }, { "name": "sup", "data": [ { "name": "text", "data": "4+" } ] }, { "name": "text", "data": "混合相中，红色荧光源于CaAl" }, { "name": "sub", "data": [ { "name": "text", "data": "12" } ] }, { "name": "text", "data": "O" }, { "name": "sub", "data": [ { "name": "text", "data": "19" } ] }, { "name": "text", "data": "∶Mn" }, { "name": "sup", "data": [ { "name": "text", "data": "4+" } ] }, { "name": "text", "data": "。由Chen等" }, { "name": "sup", "data": [ { "name": "text", "data": "[" }, { "name": "xref", "data": { "text": "28", "type": "bibr", "rid": "R28", "data": [ { "name": "text", "data": "28" } ] } }, { "name": "text", "data": "]" } ] }, { "name": "text", "data": "计算结果得到，当ZAO基质中Mn" }, { "name": "sup", "data": [ { "name": "text", "data": "2+" } ] }, { "name": "text", "data": "氧化成Mn" }, { "name": "sup", "data": [ { "name": "text", "data": "4+" } ] }, { "name": "text", "data": "时，吉布斯自由能的变化值为正值，说明在该基质中Mn" }, { "name": "sup", "data": [ { "name": "text", "data": "2+" } ] }, { "name": "text", "data": "无法自发氧化成Mn" }, { "name": "sup", "data": [ { "name": "text", "data": "4+" } ] }, { "name": "text", "data": "。综上所述，我们认为样品中的锰离子以Mn" }, { "name": "sup", "data": [ { "name": "text", "data": "4+" } ] }, { "name": "text", "data": "形式存在并占据CAO中Al" }, { "name": "sup", "data": [ { "name": "text", "data": "3+" } ] }, { "name": "text", "data": "的八面体格位，而非占据ZAO中Al" }, { "name": "sup", "data": [ { "name": "text", "data": "3+" } ] }, { "name": "text", "data": "的八面体格位。" } ] }, { "name": "fig", "data": { "id": "F3", "caption": [ { "lang": "zh", "label": [ { "name": "text", "data": "图3" } ], "title": [ { "name": "text", "data": "Mn离子掺杂不同基质荧光粉的激发和发射光谱。(a)ZAO;(b)CAO;(c)ZAO/CAO。" } ] }, { "lang": "en", "label": [ { "name": "text", "data": "Fig. 3" } ], "title": [ { "name": "text", "data": "The excitation and emission spectra of Mn ion-doped phosphors with different substrates.(a)ZAO.(b)CAO.(c)ZAO/CAO." } ] } ], "subcaption": [], "note": [], "graphics": [ { "print": "http://html.publish.founderss.cn/rc-pub/api/common/picture?pictureId=26724527&type=", "small": "http://html.publish.founderss.cn/rc-pub/api/common/picture?pictureId=26724534&type=", "big": "http://html.publish.founderss.cn/rc-pub/api/common/picture?pictureId=26724519&type=" } ] } }, { "name": "p", "data": [ { "name": "xref", "data": { "text": "图4(a)", "type": "fig", "rid": "F4", "data": [ { "name": "text", "data": "图4(a)" } ] } }, { "name": "text", "data": "给出了ZAO/CAO∶0.04Mn" }, { "name": "sup", "data": [ { "name": "text", "data": "4+" } ] }, { "name": "text", "data": "的激发和发射光谱，经分峰拟合，该激发谱包含345,400,471 nm三组激发峰。其中，位于345 nm(28 986 cm" }, { "name": "sup", "data": [ { "name": "text", "data": "-1" } ] }, { "name": "text", "data": ")的激发峰是由自旋允许的Mn" }, { "name": "sup", "data": [ { "name": "text", "data": "4+" } ] }, { "name": "text", "data": "的" }, { "name": "sup", "data": [ { "name": "text", "data": "4" } ] }, { "name": "text", "data": "A" }, { "name": "sub", "data": [ { "name": "text", "data": "2" } ] }, { "name": "text", "data": "→ " }, { "name": "sup", "data": [ { "name": "text", "data": "4" } ] }, { "name": "text", "data": "T" }, { "name": "sub", "data": [ { "name": "text", "data": "1" } ] }, { "name": "text", "data": "能级跃迁产生；而400 nm以及471 nm(21 231 cm" }, { "name": "sup", "data": [ { "name": "text", "data": "-1" } ] }, { "name": "text", "data": ")处的激发峰分别由Mn" }, { "name": "sup", "data": [ { "name": "text", "data": "4+" } ] }, { "name": "text", "data": "的 " }, { "name": "inlineformula", "data": [ { "name": "math", "data": { "graphicsData": { "print": "http://html.publish.founderss.cn/rc-pub/api/common/picture?pictureId=26724536&type=", "small": "http://html.publish.founderss.cn/rc-pub/api/common/picture?pictureId=26724556&type=", "big": "http://html.publish.founderss.cn/rc-pub/api/common/picture?pictureId=26724542&type=" } } } ] }, { "name": "text", "data": "T" }, { "name": "sub", "data": [ { "name": "text", "data": "2" } ] }, { "name": "text", "data": "和" }, { "name": "sup", "data": [ { "name": "text", "data": "4" } ] }, { "name": "text", "data": "A" }, { "name": "sub", "data": [ { "name": "text", "data": "2" } ] }, { "name": "text", "data": "→" }, { "name": "sup", "data": [ { "name": "text", "data": "4" } ] }, { "name": "text", "data": "T" }, { "name": "sub", "data": [ { "name": "text", "data": "2" } ] }, { "name": "text", "data": "能级跃迁产生" }, { "name": "sup", "data": [ { "name": "text", "data": "[" }, { "name": "xref", "data": { "text": "29", "type": "bibr", "rid": "R29", "data": [ { "name": "text", "data": "29" } ] } }, { "name": "text", "data": "]" } ] }, { "name": "text", "data": "。在345 nm光激发下， 659 nm(15 175 cm" }, { "name": "sup", "data": [ { "name": "text", "data": "-1" } ] }, { "name": "text", "data": ")处的最强发射峰以及648,667 nm处的两个肩峰均可归属为Mn" }, { "name": "sup", "data": [ { "name": "text", "data": "4+" } ] }, { "name": "text", "data": "离子的" }, { "name": "sup", "data": [ { "name": "text", "data": "2" } ] }, { "name": "text", "data": "E" }, { "name": "sub", "data": [ { "name": "text", "data": "g" } ] }, { "name": "text", "data": "→" }, { "name": "sup", "data": [ { "name": "text", "data": "4" } ] }, { "name": "text", "data": "A" }, { "name": "sub", "data": [ { "name": "text", "data": "2" } ] }, { "name": "text", "data": "电子跃迁" }, { "name": "sup", "data": [ { "name": "text", "data": "[" }, { "name": "xref", "data": { "text": "30", "type": "bibr", "rid": "R30", "data": [ { "name": "text", "data": "30" } ] } }, { "name": "text", "data": "]" } ] }, { "name": "text", "data": "。Mn" }, { "name": "sup", "data": [ { "name": "text", "data": "4+" } ] }, { "name": "text", "data": "是一种过渡金属离子，具有3d" }, { "name": "sup", "data": [ { "name": "text", "data": "3" } ] }, { "name": "text", "data": "电子结构，由于缺少最外层电子的屏蔽作用，其很容易受晶场环境的影响。根据晶场理论和哈密顿矩阵元方程，可以得到" }, { "name": "dispformula", "data": { "label": [ { "name": "text", "data": "(1)" } ], "data": [ { "name": "math", "data": { "graphicsData": { "print": "http://html.publish.founderss.cn/rc-pub/api/common/picture?pictureId=26724547&type=", "small": "http://html.publish.founderss.cn/rc-pub/api/common/picture?pictureId=26724561&type=", "big": "http://html.publish.founderss.cn/rc-pub/api/common/picture?pictureId=26724549&type=" } } } ], "id": "DF1" } }, { "name": "dispformula", "data": { "label": [ { "name": "text", "data": "(2)" } ], "data": [ { "name": "math", "data": { "graphicsData": { "print": "http://html.publish.founderss.cn/rc-pub/api/common/picture?pictureId=26724567&type=", "small": "http://html.publish.founderss.cn/rc-pub/api/common/picture?pictureId=26724570&type=", "big": "http://html.publish.founderss.cn/rc-pub/api/common/picture?pictureId=26724586&type=" } } } ], "id": "DF2" } }, { "name": "dispformula", "data": { "label": [ { "name": "text", "data": "(3)" } ], "data": [ { "name": "math", "data": { "graphicsData": { "print": "http://html.publish.founderss.cn/rc-pub/api/common/picture?pictureId=26724588&type=", "small": "http://html.publish.founderss.cn/rc-pub/api/common/picture?pictureId=26724580&type=", "big": "http://html.publish.founderss.cn/rc-pub/api/common/picture?pictureId=26724598&type=" } } } ], "id": "DF3" } }, { "name": "dispformula", "data": { "label": [ { "name": "text", "data": "(4)" } ], "data": [ { "name": "math", "data": { "graphicsData": { "print": "http://html.publish.founderss.cn/rc-pub/api/common/picture?pictureId=26724600&type=", "small": "http://html.publish.founderss.cn/rc-pub/api/common/picture?pictureId=26724595&type=", "big": "http://html.publish.founderss.cn/rc-pub/api/common/picture?pictureId=26724606&type=" } } } ], "id": "DF4" } }, { "name": "text", "data": "根据公式(1)~(4)计算出ZnAl" }, { "name": "sub", "data": [ { "name": "text", "data": "2" } ] }, { "name": "text", "data": "O" }, { "name": "sub", "data": [ { "name": "text", "data": "4" } ] }, { "name": "text", "data": "/CaAl" }, { "name": "sub", "data": [ { "name": "text", "data": "12" } ] }, { "name": "text", "data": "O" }, { "name": "sub", "data": [ { "name": "text", "data": "19" } ] }, { "name": "text", "data": "∶0.04Mn" }, { "name": "sup", "data": [ { "name": "text", "data": "4+" } ] }, { "name": "text", "data": "荧光粉中位于八面体场的Mn" }, { "name": "sup", "data": [ { "name": "text", "data": "4+" } ] }, { "name": "text", "data": "离子晶体场强度数值，" }, { "name": "italic", "data": [ { "name": "text", "data": "Dq" } ] }, { "name": "text", "data": "、" }, { "name": "italic", "data": [ { "name": "text", "data": "B" } ] }, { "name": "text", "data": "和" }, { "name": "italic", "data": [ { "name": "text", "data": "C" } ] }, { "name": "text", "data": "的数值分别为2 123,757,3 175 cm" }, { "name": "sup", "data": [ { "name": "text", "data": "-1" } ] }, { "name": "text", "data": "；由于" }, { "name": "italic", "data": [ { "name": "text", "data": "Dq/B" } ] }, { "name": "text", "data": "=2.8" }, { "name": "text", "data": ">" }, { "name": "text", "data": "2.2，该晶体场属于强场。" }, { "name": "xref", "data": { "text": "图4(b)", "type": "fig", "rid": "F4", "data": [ { "name": "text", "data": "图4(b)" } ] } }, { "name": "text", "data": "为Mn" }, { "name": "sup", "data": [ { "name": "text", "data": "4+" } ] }, { "name": "text", "data": "的简单能级图，在八面体晶体场中，Mn" }, { "name": "sup", "data": [ { "name": "text", "data": "4+" } ] }, { "name": "text", "data": "的3d电子组态可以劈裂为两重简并态T" }, { "name": "sub", "data": [ { "name": "text", "data": "2g" } ] }, { "name": "text", "data": "和三重简并态E" }, { "name": "sub", "data": [ { "name": "text", "data": "g" } ] }, { "name": "text", "data": "，电子吸收能量后跃迁到激发态能级" }, { "name": "sup", "data": [ { "name": "text", "data": "4" } ] }, { "name": "text", "data": "T" }, { "name": "sub", "data": [ { "name": "text", "data": "1" } ] }, { "name": "text", "data": "、" }, { "name": "sup", "data": [ { "name": "text", "data": "2" } ] }, { "name": "text", "data": "T" }, { "name": "sub", "data": [ { "name": "text", "data": "2" } ] }, { "name": "text", "data": "和" }, { "name": "sup", "data": [ { "name": "text", "data": "4" } ] }, { "name": "text", "data": "T" }, { "name": "sub", "data": [ { "name": "text", "data": "2" } ] }, { "name": "text", "data": "，激发态电子通过非辐射跃迁弛豫到" }, { "name": "sup", "data": [ { "name": "text", "data": "2" } ] }, { "name": "text", "data": "E" }, { "name": "sub", "data": [ { "name": "text", "data": "g" } ] }, { "name": "text", "data": "能级，并通过发射光子的方式释放剩余能量回到基态。" } ] }, { "name": "fig", "data": { "id": "F4", "caption": [ { "lang": "zh", "label": [ { "name": "text", "data": "图4" } ], "title": [ { "name": "text", "data": "(a)ZAO/CAO∶0.04Mn" }, { "name": "sup", "data": [ { "name": "text", "data": "4+" } ] }, { "name": "text", "data": "荧光粉的激发和发射光谱及高斯拟合曲线；(b)Mn" }, { "name": "sup", "data": [ { "name": "text", "data": "4+" } ] }, { "name": "text", "data": "的简单能级图。" } ] }, { "lang": "en", "label": [ { "name": "text", "data": "Fig. 4" } ], "title": [ { "name": "text", "data": "(a)The excitation and emission spectra and Gaussian fitting of ZAO/CAO∶0.04Mn" }, { "name": "sup", "data": [ { "name": "text", "data": "4+" } ] }, { "name": "text", "data": " phosphor.(b)The simple energy level diagram of Mn" }, { "name": "sup", "data": [ { "name": "text", "data": "4+" } ] }, { "name": "text", "data": "." } ] } ], "subcaption": [], "note": [], "graphics": [ { "print": "http://html.publish.founderss.cn/rc-pub/api/common/picture?pictureId=26724614&type=", "small": "http://html.publish.founderss.cn/rc-pub/api/common/picture?pictureId=26724630&type=", "big": "http://html.publish.founderss.cn/rc-pub/api/common/picture?pictureId=26724618&type=" } ] } }, { "name": "p", "data": [ { "name": "text", "data": "　" }, { "name": "italic", "data": [ { "name": "text", "data": "x" } ] }, { "name": "text", "data": "ZAO/CAO∶0.04Mn" }, { "name": "sup", "data": [ { "name": "text", "data": "4+" } ] }, { "name": "text", "data": "在室温下的发射谱图如" }, { "name": "xref", "data": { "text": "图5(a)", "type": "fig", "rid": "F5", "data": [ { "name": "text", "data": "图5(a)" } ] } }, { "name": "text", "data": "所示，相对于CAO∶0.04Mn" }, { "name": "sup", "data": [ { "name": "text", "data": "4+" } ] }, { "name": "text", "data": "荧光粉，掺杂不同物质的量的ZAO样品的荧光强度明显增强，发射光谱的形状和峰位置与CAO∶0.04Mn" }, { "name": "sup", "data": [ { "name": "text", "data": "4+" } ] }, { "name": "text", "data": "保持一致。随着ZAO掺杂量的增大，样品的荧光强度先增大后减小；当ZAO与CAO物质的量比值为1时，ZAO/CAO∶Mn" }, { "name": "sup", "data": [ { "name": "text", "data": "4+" } ] }, { "name": "text", "data": "荧光粉的荧光强度最大，其荧光强度为CAO∶Mn" }, { "name": "sup", "data": [ { "name": "text", "data": "4+" } ] }, { "name": "text", "data": "荧光强度的303%。产生上述现象的原因有两个，首先CAO基质中掺杂ZAO改变了Mn" }, { "name": "sup", "data": [ { "name": "text", "data": "4+" } ] }, { "name": "text", "data": "的晶场环境；其次由于Mn" }, { "name": "sup", "data": [ { "name": "text", "data": "4+" } ] }, { "name": "text", "data": "取代Al" }, { "name": "sup", "data": [ { "name": "text", "data": "3+" } ] }, { "name": "text", "data": "引起的电荷失衡通过少量Zn" }, { "name": "sup", "data": [ { "name": "text", "data": "2+" } ] }, { "name": "text", "data": "代基质中的Al" }, { "name": "sup", "data": [ { "name": "text", "data": "3+" } ] }, { "name": "text", "data": "，起到电荷补偿的作用" }, { "name": "sup", "data": [ { "name": "text", "data": "[" }, { "name": "xref", "data": { "text": "31", "type": "bibr", "rid": "R31", "data": [ { "name": "text", "data": "31" } ] } }, { "name": "text", "data": "]" } ] }, { "name": "text", "data": "。继续增大ZAO加入量，荧光强度开始下降，原因是过多的ZAO包覆了CAO∶Mn" }, { "name": "sup", "data": [ { "name": "text", "data": "4+" } ] }, { "name": "text", "data": "，阻碍激活离子Mn" }, { "name": "sup", "data": [ { "name": "text", "data": "4+" } ] }, { "name": "text", "data": "对光的吸收。" } ] }, { "name": "fig", "data": { "id": "F5", "caption": [ { "lang": "zh", "label": [ { "name": "text", "data": "图5" } ], "title": [ { "name": "text", "data": "(a)" }, { "name": "italic", "data": [ { "name": "text", "data": "x" } ] }, { "name": "text", "data": "ZAO/CAO∶0.04Mn" }, { "name": "sup", "data": [ { "name": "text", "data": "4+" } ] }, { "name": "text", "data": " (" }, { "name": "italic", "data": [ { "name": "text", "data": "x" } ] }, { "name": "text", "data": "=0,0.5,1,2,3) 荧光粉的发射光谱，插图是荧光强度与物质的量的比值关系；(b)" }, { "name": "italic", "data": [ { "name": "text", "data": "x" } ] }, { "name": "text", "data": "ZAO/CAO∶0.04Mn" }, { "name": "sup", "data": [ { "name": "text", "data": "4+" } ] }, { "name": "text", "data": " (" }, { "name": "italic", "data": [ { "name": "text", "data": "x" } ] }, { "name": "text", "data": "=0,0.5,1,2,3) 荧光粉的荧光衰减曲线；(c)CAO∶0.04Mn" }, { "name": "sup", "data": [ { "name": "text", "data": "4+" } ] }, { "name": "text", "data": "和ZAO/CAO∶0.04Mn" }, { "name": "sup", "data": [ { "name": "text", "data": "4+" } ] }, { "name": "text", "data": "荧光粉的内量子效率。" } ] }, { "lang": "en", "label": [ { "name": "text", "data": "Fig. 5" } ], "title": [ { "name": "text", "data": "(a)Emission spectra for a series of " }, { "name": "italic", "data": [ { "name": "text", "data": "x" } ] }, { "name": "text", "data": "ZAO/CAO∶0.04Mn" }, { "name": "sup", "data": [ { "name": "text", "data": "4+" } ] }, { "name": "text", "data": " (" }, { "name": "italic", "data": [ { "name": "text", "data": "x" } ] }, { "name": "text", "data": "=0, 0.5, 1, 2, 3) phosphors and inset shows the fluorescence intensity as a function of " }, { "name": "italic", "data": [ { "name": "text", "data": "x" } ] }, { "name": "text", "data": " value. (b)Normalized decay curves of " }, { "name": "italic", "data": [ { "name": "text", "data": "x" } ] }, { "name": "text", "data": "ZAO/CAO∶0.04Mn" }, { "name": "sup", "data": [ { "name": "text", "data": "4+" } ] }, { "name": "text", "data": " (" }, { "name": "italic", "data": [ { "name": "text", "data": "x" } ] }, { "name": "text", "data": "=0, 0.5, 1, 2, 3) phosphors. (c)Internal quantum yield of " }, { "name": "italic", "data": [ { "name": "text", "data": "x" } ] }, { "name": "text", "data": "ZAO/CAO∶0.04Mn" }, { "name": "sup", "data": [ { "name": "text", "data": "4+" } ] }, { "name": "text", "data": " (" }, { "name": "italic", "data": [ { "name": "text", "data": "x" } ] }, { "name": "text", "data": "=0, 1) phosphors." } ] } ], "subcaption": [], "note": [], "graphics": [ { "print": "http://html.publish.founderss.cn/rc-pub/api/common/picture?pictureId=26724622&type=", "small": "http://html.publish.founderss.cn/rc-pub/api/common/picture?pictureId=26724626&type=", "big": "http://html.publish.founderss.cn/rc-pub/api/common/picture?pictureId=26724634&type=" } ] } }, { "name": "p", "data": [ { "name": "xref", "data": { "text": "图5(b)", "type": "fig", "rid": "F5", "data": [ { "name": "text", "data": "图5(b)" } ] } }, { "name": "text", "data": "为345 nm激发、659 nm检测下，" }, { "name": "italic", "data": [ { "name": "text", "data": "x" } ] }, { "name": "text", "data": "ZAO/CAO∶0.04Mn" }, { "name": "sup", "data": [ { "name": "text", "data": "4+" } ] }, { "name": "text", "data": " (" }, { "name": "italic", "data": [ { "name": "text", "data": "x" } ] }, { "name": "text", "data": "=0, 0.5, 1, 2, 3) 的荧光衰减曲线。所有样品的荧光寿命为双指数方式衰减，符合下列公式：" }, { "name": "dispformula", "data": { "label": [ { "name": "text", "data": "(5)" } ], "data": [ { "name": "math", "data": { "graphicsData": { "print": "http://html.publish.founderss.cn/rc-pub/api/common/picture?pictureId=26724644&type=", "small": "http://html.publish.founderss.cn/rc-pub/api/common/picture?pictureId=26724640&type=", "big": "http://html.publish.founderss.cn/rc-pub/api/common/picture?pictureId=26724642&type=" } } } ], "id": "DF5" } }, { "name": "italic", "data": [ { "name": "text", "data": "I" } ] }, { "name": "text", "data": "(" }, { "name": "italic", "data": [ { "name": "text", "data": "t" } ] }, { "name": "text", "data": ")表示时间" }, { "name": "italic", "data": [ { "name": "text", "data": "t" } ] }, { "name": "text", "data": "时的发光强度，" }, { "name": "italic", "data": [ { "name": "text", "data": "τ" } ] }, { "name": "sub", "data": [ { "name": "text", "data": "1" } ] }, { "name": "text", "data": "、" }, { "name": "italic", "data": [ { "name": "text", "data": "τ" } ] }, { "name": "sub", "data": [ { "name": "text", "data": "2" } ] }, { "name": "text", "data": "为荧光寿命，" }, { "name": "italic", "data": [ { "name": "text", "data": "A" } ] }, { "name": "sub", "data": [ { "name": "text", "data": "1" } ] }, { "name": "text", "data": "、" }, { "name": "italic", "data": [ { "name": "text", "data": "A" } ] }, { "name": "sub", "data": [ { "name": "text", "data": "2" } ] }, { "name": "text", "data": "为拟合常数，有效寿命常数" }, { "name": "italic", "data": [ { "name": "text", "data": "τ" } ] }, { "name": "text", "data": "可以用公式(6)来计算：" }, { "name": "dispformula", "data": { "label": [ { "name": "text", "data": "(6)" } ], "data": [ { "name": "math", "data": { "graphicsData": { "print": "http://html.publish.founderss.cn/rc-pub/api/common/picture?pictureId=26724659&type=", "small": "http://html.publish.founderss.cn/rc-pub/api/common/picture?pictureId=26724661&type=", "big": "http://html.publish.founderss.cn/rc-pub/api/common/picture?pictureId=26724651&type=" } } } ], "id": "DF6" } }, { "name": "text", "data": "通过公式(5)和(6)计算得到" }, { "name": "italic", "data": [ { "name": "text", "data": "x" } ] }, { "name": "text", "data": "ZAO/CAO∶Mn" }, { "name": "sup", "data": [ { "name": "text", "data": "4+" } ] }, { "name": "text", "data": " (" }, { "name": "italic", "data": [ { "name": "text", "data": "x" } ] }, { "name": "text", "data": "=0, 0.5, 1, 2, 3) 样品的荧光寿命分别为730.42,861.48,1 011.36,1 093.53,1 173.09 μs，样品的荧光寿命随着ZAO掺杂量的增加而增大，其原因由公式(7)可知：" }, { "name": "dispformula", "data": { "label": [ { "name": "text", "data": "(7)" } ], "data": [ { "name": "math", "data": { "graphicsData": { "print": "http://html.publish.founderss.cn/rc-pub/api/common/picture?pictureId=26724653&type=", "small": "http://html.publish.founderss.cn/rc-pub/api/common/picture?pictureId=26724667&type=", "big": "http://html.publish.founderss.cn/rc-pub/api/common/picture?pictureId=26724669&type=" } } } ], "id": "DF7" } }, { "name": "text", "data": "其中，" }, { "name": "italic", "data": [ { "name": "text", "data": "A" } ] }, { "name": "sub", "data": [ { "name": "text", "data": "r" } ] }, { "name": "text", "data": "为辐射跃迁速率，" }, { "name": "italic", "data": [ { "name": "text", "data": "A" } ] }, { "name": "sub", "data": [ { "name": "text", "data": "nr" } ] }, { "name": "text", "data": "为非辐射跃迁速率。ZAO的加入降低了非辐射跃迁速率" }, { "name": "italic", "data": [ { "name": "text", "data": "A" } ] }, { "name": "sub", "data": [ { "name": "text", "data": "nr" } ] }, { "name": "text", "data": "，从而增加了荧光寿命。非辐射跃迁速率降低的可能原因有两个，首先，ZAO相的存在降低了混合相荧光粉缺陷，减少了非辐射跃迁渠道；其次，由于Zn" }, { "name": "sup", "data": [ { "name": "text", "data": "2+" } ] }, { "name": "text", "data": "存在而形成的 Zn" }, { "name": "sup", "data": [ { "name": "text", "data": "2+" } ] }, { "name": "text", "data": "-Mn" }, { "name": "sup", "data": [ { "name": "text", "data": "4+" } ] }, { "name": "text", "data": "离子对的存在减少了Mn" }, { "name": "sup", "data": [ { "name": "text", "data": "4+" } ] }, { "name": "text", "data": "-Mn" }, { "name": "sup", "data": [ { "name": "text", "data": "4+" } ] }, { "name": "text", "data": "离子对，降低了非辐射跃迁。" }, { "name": "xref", "data": { "text": "图5(c)", "type": "fig", "rid": "F5", "data": [ { "name": "text", "data": "图5(c)" } ] } }, { "name": "text", "data": "为345 nm激发下，CAO∶0.04Mn" }, { "name": "sup", "data": [ { "name": "text", "data": "4+" } ] }, { "name": "text", "data": "和ZAO/CAO∶0.04Mn" }, { "name": "sup", "data": [ { "name": "text", "data": "4+" } ] }, { "name": "text", "data": "的内量子效率(IQE)柱形图，内量子效率值可以通过公式(8)进行计算：" }, { "name": "dispformula", "data": { "label": [ { "name": "text", "data": "(8)" } ], "data": [ { "name": "math", "data": { "graphicsData": { "print": "http://html.publish.founderss.cn/rc-pub/api/common/picture?pictureId=26724674&type=", "small": "http://html.publish.founderss.cn/rc-pub/api/common/picture?pictureId=26724677&type=", "big": "http://html.publish.founderss.cn/rc-pub/api/common/picture?pictureId=26724679&type=" } } } ], "id": "DF8" } }, { "name": "text", "data": "其中，" }, { "name": "italic", "data": [ { "name": "text", "data": "L" } ] }, { "name": "sub", "data": [ { "name": "text", "data": "S" } ] }, { "name": "text", "data": "是荧光粉的发射谱线，" }, { "name": "italic", "data": [ { "name": "text", "data": "E" } ] }, { "name": "sub", "data": [ { "name": "text", "data": "S" } ] }, { "name": "text", "data": "和" }, { "name": "italic", "data": [ { "name": "text", "data": "E" } ] }, { "name": "sub", "data": [ { "name": "text", "data": "R" } ] }, { "name": "text", "data": "分别是样品和BaSO" }, { "name": "sub", "data": [ { "name": "text", "data": "4" } ] }, { "name": "text", "data": "的激发谱线。由此算得CAO∶0.04Mn" }, { "name": "sup", "data": [ { "name": "text", "data": "4+" } ] }, { "name": "text", "data": "的IQE值为11.03%,ZAO/CAO∶0.04Mn" }, { "name": "sup", "data": [ { "name": "text", "data": "4+" } ] }, { "name": "text", "data": "的IQE值为34.26%,ZAO/CAO∶0.04Mn" }, { "name": "sup", "data": [ { "name": "text", "data": "4+" } ] }, { "name": "text", "data": "的内量子效率比纯相CAO∶0.04Mn" }, { "name": "sup", "data": [ { "name": "text", "data": "4+" } ] }, { "name": "text", "data": "的内量子效率提高了211%。综上所述，ZAO的加入对改善ZAO/CAO∶Mn" }, { "name": "sup", "data": [ { "name": "text", "data": "4+" } ] }, { "name": "text", "data": "的荧光寿命和提高内量子效率起到了积极的作用。" } ] }, { "name": "p", "data": [ { "name": "xref", "data": { "text": "图6(a)、(c)", "type": "fig", "rid": "F6", "data": [ { "name": "text", "data": "图6(a)、(c)" } ] } }, { "name": "text", "data": "分别为不同浓度Mn" }, { "name": "sup", "data": [ { "name": "text", "data": "4+" } ] }, { "name": "text", "data": "掺杂ZAO/CAO和CAO荧光粉的发射谱图。由图可知，随着Mn" }, { "name": "sup", "data": [ { "name": "text", "data": "4+" } ] }, { "name": "text", "data": "掺杂浓度的增加，ZAO/CAO和CAO荧光粉的荧光强度逐渐增强，当Mn" }, { "name": "sup", "data": [ { "name": "text", "data": "4+" } ] }, { "name": "text", "data": "掺杂浓度为0.04时，样品的荧光强度达到最大，继续增大掺杂浓度，荧光强度降低，发生了浓度猝灭现象。由于以上两种基质中Mn" }, { "name": "sup", "data": [ { "name": "text", "data": "4+" } ] }, { "name": "text", "data": "最佳掺杂浓度均为0.04，说明相对于CAO∶Mn" }, { "name": "sup", "data": [ { "name": "text", "data": "4+" } ] }, { "name": "text", "data": "荧光粉，ZAO/CAO∶Mn" }, { "name": "sup", "data": [ { "name": "text", "data": "4+" } ] }, { "name": "text", "data": "发光增强并不是因为Mn" }, { "name": "sup", "data": [ { "name": "text", "data": "4+" } ] }, { "name": "text", "data": "浓度的改变。为了进一步了解混合相中Mn" }, { "name": "sup", "data": [ { "name": "text", "data": "4+" } ] }, { "name": "text", "data": "浓度猝灭机理，由公式(9)计算Mn" }, { "name": "sup", "data": [ { "name": "text", "data": "4+" } ] }, { "name": "text", "data": "浓度猝灭的临界距离(" }, { "name": "italic", "data": [ { "name": "text", "data": "R" } ] }, { "name": "sub", "data": [ { "name": "text", "data": "c" } ] }, { "name": "text", "data": "):" }, { "name": "dispformula", "data": { "label": [ { "name": "text", "data": "(9)" } ], "data": [ { "name": "math", "data": { "graphicsData": { "print": "http://html.publish.founderss.cn/rc-pub/api/common/picture?pictureId=26724682&type=", "small": "http://html.publish.founderss.cn/rc-pub/api/common/picture?pictureId=26724683&type=", "big": "http://html.publish.founderss.cn/rc-pub/api/common/picture?pictureId=26724684&type=" } } } ], "id": "DF9" } }, { "name": "text", "data": "其中" }, { "name": "italic", "data": [ { "name": "text", "data": "R" } ] }, { "name": "sub", "data": [ { "name": "text", "data": "c" } ] }, { "name": "text", "data": "是临界距离，" }, { "name": "italic", "data": [ { "name": "text", "data": "V" } ] }, { "name": "text", "data": "是晶胞体积，" }, { "name": "italic", "data": [ { "name": "text", "data": "y" } ] }, { "name": "sub", "data": [ { "name": "text", "data": "c" } ] }, { "name": "text", "data": "是最佳掺杂浓度，" }, { "name": "italic", "data": [ { "name": "text", "data": "N" } ] }, { "name": "text", "data": "为晶胞中阳离子的数量。在基质CAO中" }, { "name": "italic", "data": [ { "name": "text", "data": "V" } ] }, { "name": "text", "data": "=0.586 nm" }, { "name": "sup", "data": [ { "name": "text", "data": "3" } ] }, { "name": "text", "data": "," }, { "name": "italic", "data": [ { "name": "text", "data": "N" } ] }, { "name": "text", "data": "=2，计算出" }, { "name": "italic", "data": [ { "name": "text", "data": "R" } ] }, { "name": "sub", "data": [ { "name": "text", "data": "c" } ] }, { "name": "text", "data": "的值为2.41 nm，大于0.5 nm，临界距离较大，所以Mn" }, { "name": "sup", "data": [ { "name": "text", "data": "4+" } ] }, { "name": "text", "data": "浓度猝灭机制是属于多极相互作用。相互作用的类型可用公式(10)推算：" }, { "name": "dispformula", "data": { "label": [ { "name": "text", "data": "(10)" } ], "data": [ { "name": "math", "data": { "graphicsData": { "print": "http://html.publish.founderss.cn/rc-pub/api/common/picture?pictureId=26724697&type=", "small": "http://html.publish.founderss.cn/rc-pub/api/common/picture?pictureId=26724699&type=", "big": "http://html.publish.founderss.cn/rc-pub/api/common/picture?pictureId=26724701&type=" } } } ], "id": "DF10" } }, { "name": "italic", "data": [ { "name": "text", "data": "I" } ] }, { "name": "text", "data": "表示发射光谱的积分强度，" }, { "name": "italic", "data": [ { "name": "text", "data": "K" } ] }, { "name": "text", "data": "和" }, { "name": "italic", "data": [ { "name": "text", "data": "β" } ] }, { "name": "text", "data": "为常数，" }, { "name": "italic", "data": [ { "name": "text", "data": "y" } ] }, { "name": "text", "data": "为Mn" }, { "name": "sup", "data": [ { "name": "text", "data": "4+" } ] }, { "name": "text", "data": "离子浓度(大于等于猝灭浓度)," }, { "name": "italic", "data": [ { "name": "text", "data": "θ" } ] }, { "name": "text", "data": "值为6,8,10时分别表示电偶极-电偶极、电偶极-电四极和电四极-电四极相互作用。对公式(10)取对数作图并线性拟合如" }, { "name": "xref", "data": { "text": "图6(b)", "type": "fig", "rid": "F6", "data": [ { "name": "text", "data": "图6(b)" } ] } }, { "name": "text", "data": "所示，拟合直线的斜率为-2.256，算得" }, { "name": "italic", "data": [ { "name": "text", "data": "θ" } ] }, { "name": "text", "data": "值为6.768，最接近于6，所以Mn" }, { "name": "sup", "data": [ { "name": "text", "data": "4+" } ] }, { "name": "text", "data": "之间的相互作用为电偶极-电偶极相互作用。" } ] }, { "name": "fig", "data": { "id": "F6", "caption": [ { "lang": "zh", "label": [ { "name": "text", "data": "图6" } ], "title": [ { "name": "text", "data": "(a)不同掺杂浓度ZAO/CAO∶" }, { "name": "italic", "data": [ { "name": "text", "data": "z" } ] }, { "name": "text", "data": "Mn" }, { "name": "sup", "data": [ { "name": "text", "data": "4+" } ] }, { "name": "text", "data": " (" }, { "name": "italic", "data": [ { "name": "text", "data": "z" } ] }, { "name": "text", "data": "=0.02,0.04,0.06,0.08,0.1) 荧光粉的发射光谱；(b)ZAO/CAO∶" }, { "name": "italic", "data": [ { "name": "text", "data": "y" } ] }, { "name": "text", "data": "Mn" }, { "name": "sup", "data": [ { "name": "text", "data": "4+" } ] }, { "name": "text", "data": " (" }, { "name": "italic", "data": [ { "name": "text", "data": "y" } ] }, { "name": "text", "data": "=0.04,0.06,0.08,0.1) 荧光粉的lg(" }, { "name": "italic", "data": [ { "name": "text", "data": "I" } ] }, { "name": "text", "data": "/" }, { "name": "italic", "data": [ { "name": "text", "data": "y" } ] }, { "name": "text", "data": ")随lg" }, { "name": "italic", "data": [ { "name": "text", "data": "y" } ] }, { "name": "text", "data": "变化关系；(c)不同掺杂浓度CAO∶" }, { "name": "italic", "data": [ { "name": "text", "data": "k" } ] }, { "name": "text", "data": "Mn" }, { "name": "sup", "data": [ { "name": "text", "data": "4+" } ] }, { "name": "text", "data": " (" }, { "name": "italic", "data": [ { "name": "text", "data": "k" } ] }, { "name": "text", "data": "=0.02,0.04,0.06,0.08) 荧光粉的发射光谱。" } ] }, { "lang": "en", "label": [ { "name": "text", "data": "Fig. 6" } ], "title": [ { "name": "text", "data": "(a)Emission spectra of the ZAO/CAO∶" }, { "name": "italic", "data": [ { "name": "text", "data": "z" } ] }, { "name": "text", "data": "Mn" }, { "name": "sup", "data": [ { "name": "text", "data": "4+" } ] }, { "name": "text", "data": " phosphors with various Mn" }, { "name": "sup", "data": [ { "name": "text", "data": "4+" } ] }, { "name": "text", "data": " concentration(" }, { "name": "italic", "data": [ { "name": "text", "data": "z" } ] }, { "name": "text", "data": "=0.02,0.04,0.06,0.08,0.1). (b)The dependence of lg(" }, { "name": "italic", "data": [ { "name": "text", "data": "I" } ] }, { "name": "text", "data": "/" }, { "name": "italic", "data": [ { "name": "text", "data": "y" } ] }, { "name": "text", "data": ") " }, { "name": "italic", "data": [ { "name": "text", "data": "versus" } ] }, { "name": "text", "data": " lg" }, { "name": "italic", "data": [ { "name": "text", "data": "y" } ] }, { "name": "text", "data": " for ZAO/CAO∶" }, { "name": "italic", "data": [ { "name": "text", "data": "y" } ] }, { "name": "text", "data": "Mn" }, { "name": "sup", "data": [ { "name": "text", "data": "4+" } ] }, { "name": "text", "data": "(" }, { "name": "italic", "data": [ { "name": "text", "data": "y" } ] }, { "name": "text", "data": "=0.04, 0.06, 0.08, 0.1) phosphors. (c)Emission spectra of the CAO∶" }, { "name": "italic", "data": [ { "name": "text", "data": "k" } ] }, { "name": "text", "data": "Mn" }, { "name": "sup", "data": [ { "name": "text", "data": "4+" } ] }, { "name": "text", "data": " phosphors with various Mn" }, { "name": "sup", "data": [ { "name": "text", "data": "4+" } ] }, { "name": "text", "data": " concentration(" }, { "name": "italic", "data": [ { "name": "text", "data": "k" } ] }, { "name": "text", "data": "=0.02, 0.04, 0.06, 0.08)." } ] } ], "subcaption": [], "note": [], "graphics": [ { "print": "http://html.publish.founderss.cn/rc-pub/api/common/picture?pictureId=26724718&type=", "small": "http://html.publish.founderss.cn/rc-pub/api/common/picture?pictureId=26724706&type=", "big": "http://html.publish.founderss.cn/rc-pub/api/common/picture?pictureId=26724719&type=" } ] } } ] }, { "name": "sec", "data": [ { "name": "sectitle", "data": { "label": [ { "name": "text", "data": "3.3" } ], "title": [ { "name": "text", "data": "ZAO/CAO∶Mn" }, { "name": "sup", "data": [ { "name": "text", "data": "4+" } ] }, { "name": "text", "data": "在光学测温上的应用" } ], "level": "2", "id": "s3c" } }, { "name": "p", "data": [ { "name": "xref", "data": { "text": "图7(a)", "type": "fig", "rid": "F7", "data": [ { "name": "text", "data": "图7(a)" } ] } }, { "name": "text", "data": "为ZAO/CAO∶0.04Mn" }, { "name": "sup", "data": [ { "name": "text", "data": "4+" } ] }, { "name": "text", "data": "在298~418 K范围的变温发射谱图。从图中可以看出，荧光强度与温度有依赖性，随着温度的升高，荧光强度开始降低。定义主峰(659 nm)荧光强度为" }, { "name": "italic", "data": [ { "name": "text", "data": "I" } ] }, { "name": "sub", "data": [ { "name": "text", "data": "1" } ] }, { "name": "text", "data": "，左肩峰(648 nm)荧光强度为" }, { "name": "italic", "data": [ { "name": "text", "data": "I" } ] }, { "name": "sub", "data": [ { "name": "text", "data": "2" } ] }, { "name": "text", "data": "，其中FIR(" }, { "name": "italic", "data": [ { "name": "text", "data": "R" } ] }, { "name": "sub", "data": [ { "name": "text", "data": "FI" } ] }, { "name": "text", "data": ")、" }, { "name": "italic", "data": [ { "name": "text", "data": "S" } ] }, { "name": "sub", "data": [ { "name": "text", "data": "a" } ] }, { "name": "text", "data": "以及" }, { "name": "italic", "data": [ { "name": "text", "data": "S" } ] }, { "name": "sub", "data": [ { "name": "text", "data": "r" } ] }, { "name": "text", "data": "的定义如下：" }, { "name": "dispformula", "data": { "label": [ { "name": "text", "data": "(11)" } ], "data": [ { "name": "math", "data": { "graphicsData": { "print": "http://html.publish.founderss.cn/rc-pub/api/common/picture?pictureId=26724708&type=", "small": "http://html.publish.founderss.cn/rc-pub/api/common/picture?pictureId=26724724&type=", "big": "http://html.publish.founderss.cn/rc-pub/api/common/picture?pictureId=26724726&type=" } } } ], "id": "DF11" } }, { "name": "dispformula", "data": { "label": [ { "name": "text", "data": "(12)" } ], "data": [ { "name": "math", "data": { "graphicsData": { "print": "http://html.publish.founderss.cn/rc-pub/api/common/picture?pictureId=26724715&type=", "small": "http://html.publish.founderss.cn/rc-pub/api/common/picture?pictureId=26724729&type=", "big": "http://html.publish.founderss.cn/rc-pub/api/common/picture?pictureId=26724731&type=" } } } ], "id": "DF12" } }, { "name": "dispformula", "data": { "label": [ { "name": "text", "data": "(13)" } ], "data": [ { "name": "math", "data": { "graphicsData": { "print": "http://html.publish.founderss.cn/rc-pub/api/common/picture?pictureId=26724734&type=", "small": "http://html.publish.founderss.cn/rc-pub/api/common/picture?pictureId=26724749&type=", "big": "http://html.publish.founderss.cn/rc-pub/api/common/picture?pictureId=26724751&type=" } } } ], "id": "DF13" } }, { "name": "xref", "data": { "text": "图7(b)", "type": "fig", "rid": "F7", "data": [ { "name": "text", "data": "图7(b)" } ] } }, { "name": "text", "data": "为荧光强度随温度变化曲线图以及相对灵敏度随温度变化图。通过拟合曲线，得到" }, { "name": "italic", "data": [ { "name": "text", "data": "R" } ] }, { "name": "sub", "data": [ { "name": "text", "data": "FI" } ] }, { "name": "text", "data": "与温度的线性关系函数为：" }, { "name": "italic", "data": [ { "name": "text", "data": "R" } ] }, { "name": "sub", "data": [ { "name": "text", "data": "FI" } ] }, { "name": "text", "data": " =-4.32×10" }, { "name": "sup", "data": [ { "name": "text", "data": "-3" } ] }, { "name": "italic", "data": [ { "name": "text", "data": "T" } ] }, { "name": "text", "data": "+3.01。" }, { "name": "xref", "data": { "text": "图7(c)", "type": "fig", "rid": "F7", "data": [ { "name": "text", "data": "图7(c)" } ] } }, { "name": "text", "data": "为ZAO/CAO∶0.04Mn" }, { "name": "sup", "data": [ { "name": "text", "data": "4+" } ] }, { "name": "text", "data": "荧光粉" }, { "name": "italic", "data": [ { "name": "text", "data": "S" } ] }, { "name": "sub", "data": [ { "name": "text", "data": "r" } ] }, { "name": "text", "data": " 和 " }, { "name": "italic", "data": [ { "name": "text", "data": "S" } ] }, { "name": "sub", "data": [ { "name": "text", "data": "a" } ] }, { "name": "text", "data": "与温度的关系。" }, { "name": "italic", "data": [ { "name": "text", "data": "R" } ] }, { "name": "sub", "data": [ { "name": "text", "data": "FI" } ] }, { "name": "text", "data": "与温度为线性关系，所以ZAO/CAO∶0.04Mn" }, { "name": "sup", "data": [ { "name": "text", "data": "4+" } ] }, { "name": "text", "data": "在298~418 K温度范围内的" }, { "name": "italic", "data": [ { "name": "text", "data": "S" } ] }, { "name": "sub", "data": [ { "name": "text", "data": "a" } ] }, { "name": "text", "data": "为4.32×10" }, { "name": "sup", "data": [ { "name": "text", "data": "-3" } ] }, { "name": "text", "data": "K" }, { "name": "sup", "data": [ { "name": "text", "data": "-1" } ] }, { "name": "text", "data": "，优于Yang等" }, { "name": "sup", "data": [ { "name": "text", "data": "[" }, { "name": "xref", "data": { "text": "19", "type": "bibr", "rid": "R19", "data": [ { "name": "text", "data": "19" } ] } }, { "name": "text", "data": "]" } ] }, { "name": "text", "data": "报道的SrAl" }, { "name": "sub", "data": [ { "name": "text", "data": "12" } ] }, { "name": "text", "data": "O" }, { "name": "sub", "data": [ { "name": "text", "data": "19" } ] }, { "name": "text", "data": "∶Mn" }, { "name": "sup", "data": [ { "name": "text", "data": "4+" } ] }, { "name": "text", "data": "(" }, { "name": "italic", "data": [ { "name": "text", "data": "S" } ] }, { "name": "sub", "data": [ { "name": "text", "data": "a" } ] }, { "name": "text", "data": "=4.17×10" }, { "name": "sup", "data": [ { "name": "text", "data": "-3" } ] }, { "name": "text", "data": " K" }, { "name": "sup", "data": [ { "name": "text", "data": "-1" } ] }, { "name": "text", "data": ")；相对灵敏度随温度升高而增大，在418 K时达到最大值，" }, { "name": "italic", "data": [ { "name": "text", "data": "S" } ] }, { "name": "sub", "data": [ { "name": "text", "data": "r" } ] }, { "name": "text", "data": "为3.65×10" }, { "name": "sup", "data": [ { "name": "text", "data": "-3" } ] }, { "name": "text", "data": "K" }, { "name": "sup", "data": [ { "name": "text", "data": "-1" } ] }, { "name": "text", "data": "。" }, { "name": "xref", "data": { "text": "图7(d)", "type": "fig", "rid": "F7", "data": [ { "name": "text", "data": "图7(d)" } ] } }, { "name": "text", "data": "为在298 K和418 K下连续5个周期的" }, { "name": "italic", "data": [ { "name": "text", "data": "R" } ] }, { "name": "sub", "data": [ { "name": "text", "data": "FI" } ] }, { "name": "text", "data": "值，该结果表现出很好的重复性。总之，该样品具有灵敏度高、重复性好等特点，在光学测温上具有应用潜力。" } ] }, { "name": "fig", "data": { "id": "F7", "caption": [ { "lang": "zh", "label": [ { "name": "text", "data": "图7" } ], "title": [ { "name": "text", "data": "(a)ZAO/CAO∶0.04Mn" }, { "name": "sup", "data": [ { "name": "text", "data": "4+" } ] }, { "name": "text", "data": "荧光粉在298~418 K下的发射光谱；(b)" }, { "name": "italic", "data": [ { "name": "text", "data": "I" } ] }, { "name": "sub", "data": [ { "name": "text", "data": "1" } ] }, { "name": "text", "data": "与" }, { "name": "italic", "data": [ { "name": "text", "data": "I" } ] }, { "name": "sub", "data": [ { "name": "text", "data": "2" } ] }, { "name": "text", "data": "的荧光强度比与温度的关系；(c)ZAO/CAO∶0.04Mn" }, { "name": "sup", "data": [ { "name": "text", "data": "4+" } ] }, { "name": "text", "data": "荧光粉" }, { "name": "italic", "data": [ { "name": "text", "data": "S" } ] }, { "name": "sub", "data": [ { "name": "text", "data": "r" } ] }, { "name": "text", "data": " 和 " }, { "name": "italic", "data": [ { "name": "text", "data": "S" } ] }, { "name": "sub", "data": [ { "name": "text", "data": "a" } ] }, { "name": "text", "data": "与温度的关系；(d)ZAO/CAO∶0.04Mn" }, { "name": "sup", "data": [ { "name": "text", "data": "4+" } ] }, { "name": "text", "data": "连续5个周期的FIR值循环变化图。" } ] }, { "lang": "en", "label": [ { "name": "text", "data": "Fig. 7" } ], "title": [ { "name": "text", "data": "(a)Emission spectra of ZAO/CAO∶0.04Mn" }, { "name": "sup", "data": [ { "name": "text", "data": "4+" } ] }, { "name": "text", "data": "phosphor in the range of 298-418 K. (b)Fluorescence intensity ratio of " }, { "name": "italic", "data": [ { "name": "text", "data": "I" } ] }, { "name": "sub", "data": [ { "name": "text", "data": "1" } ] }, { "name": "text", "data": " and " }, { "name": "italic", "data": [ { "name": "text", "data": "I" } ] }, { "name": "sub", "data": [ { "name": "text", "data": "2" } ] }, { "name": "text", "data": " as a function of temperature. (c)The " }, { "name": "italic", "data": [ { "name": "text", "data": "S" } ] }, { "name": "sub", "data": [ { "name": "text", "data": "r" } ] }, { "name": "text", "data": " and the " }, { "name": "italic", "data": [ { "name": "text", "data": "S" } ] }, { "name": "sub", "data": [ { "name": "text", "data": "a" } ] }, { "name": "text", "data": " as a function of temperature of ZAO/CAO∶0.04Mn" }, { "name": "sup", "data": [ { "name": "text", "data": "4+" } ] }, { "name": "text", "data": " phosphor. (d)Cyclic variation of the FIR value in five consecutive cycles of ZAO/CAO∶0.04Mn" }, { "name": "sup", "data": [ { "name": "text", "data": "4+" } ] }, { "name": "text", "data": "." } ] } ], "subcaption": [], "note": [], "graphics": [ { "print": "http://html.publish.founderss.cn/rc-pub/api/common/picture?pictureId=26724754&type=", "small": "http://html.publish.founderss.cn/rc-pub/api/common/picture?pictureId=26724739&type=", "big": "http://html.publish.founderss.cn/rc-pub/api/common/picture?pictureId=26724737&type=" } ] } } ] } ] }, { "name": "sec", "data": [ { "name": "sectitle", "data": { "label": [ { "name": "text", "data": "4" } ], "title": [ { "name": "text", "data": "结论" } ], "level": "1", "id": "s4" } }, { "name": "p", "data": [ { "name": "text", "data": "本文采用传统高温固相法成功合成了系列" }, { "name": "italic", "data": [ { "name": "text", "data": "x" } ] }, { "name": "text", "data": "ZAO/CAO∶Mn" }, { "name": "sup", "data": [ { "name": "text", "data": "4+" } ] }, { "name": "text", "data": "红光荧光粉。由XRD分析可知，样品在不同ZAO掺入量下依然保持ZAO和CAO两相共存；ZAO的存在改变Mn" }, { "name": "sup", "data": [ { "name": "text", "data": "4+" } ] }, { "name": "text", "data": "晶体场环境的同时少量Zn" }, { "name": "sup", "data": [ { "name": "text", "data": "2+" } ] }, { "name": "text", "data": "取代了CAO中的Al" }, { "name": "sup", "data": [ { "name": "text", "data": "3+" } ] }, { "name": "text", "data": "，起到电荷补偿的作用，从而提高了ZAO/CAO∶Mn" }, { "name": "sup", "data": [ { "name": "text", "data": "4+" } ] }, { "name": "text", "data": "的发光强度。总之，ZAO的加入对于改善ZAO/CAO∶Mn" }, { "name": "sup", "data": [ { "name": "text", "data": "4+" } ] }, { "name": "text", "data": "荧光强度和荧光寿命以及提高内量子效率方面起着重要的作用。应用FIR光学测温，ZAO/CAO∶0.04Mn" }, { "name": "sup", "data": [ { "name": "text", "data": "4+" } ] }, { "name": "text", "data": "荧光粉在298~418 K温度范围内，" }, { "name": "italic", "data": [ { "name": "text", "data": "S" } ] }, { "name": "sub", "data": [ { "name": "text", "data": "a" } ] }, { "name": "text", "data": "为4.32×10" }, { "name": "sup", "data": [ { "name": "text", "data": "-3" } ] }, { "name": "text", "data": "K" }, { "name": "sup", "data": [ { "name": "text", "data": "-1" } ] }, { "name": "text", "data": "；在418 K时，最大" }, { "name": "italic", "data": [ { "name": "text", "data": "S" } ] }, { "name": "sub", "data": [ { "name": "text", "data": "r" } ] }, { "name": "text", "data": "为3.65×10" }, { "name": "sup", "data": [ { "name": "text", "data": "-3" } ] }, { "name": "text", "data": "K" }, { "name": "sup", "data": [ { "name": "text", "data": "-1" } ] }, { "name": "text", "data": "。显然，ZAO/CAO∶Mn" }, { "name": "sup", "data": [ { "name": "text", "data": "4+" } ] }, { "name": "text", "data": "荧光粉在298~418 K温度范围内是一种有应用前景的光学测温材料。" } ] }, { "name": "p", "data": [ { "name": "text", "data": "本文专家审稿意见及作者回复内容的下载地址：http://cjl.lightpublishing.cn/thesisDetails#10.37188/CJL.20210395." } ] } ] } ], "footnote": [], "reflist": { "title": [ { "name": "text", "data": "参考文献：" } ], "data": [ { "id": "R1", "label": "[1]", "citation": [ { "lang": "en", "text": [ { "name": "text", "data": "ZHENG Z G" }, { "name": "text", "data": ", " }, { "name": "text", "data": "ZHANG J F" }, { "name": "text", "data": ", " }, { "name": "text", "data": "LIU X Y" }, { "name": "text", "data": ", " }, { "name": "text", "data": "et al" }, { "name": "text", "data": ". " }, { "name": "text", "data": "Luminescence and self-referenced optical temperature sensing performance in Ca" }, { "name": "sub", "data": [ { "name": "text", "data": "2" } ] }, { "name": "text", "data": "YZr" }, { "name": "sub", "data": [ { "name": "text", "data": "2" } ] }, { "name": "text", "data": "Al" }, { "name": "sub", "data": [ { "name": "text", "data": "3" } ] }, { "name": "text", "data": "O" }, { "name": "sub", "data": [ { "name": "text", "data": "12" } ] }, { "name": "text", "data": "∶Bi" }, { "name": "sup", "data": [ { "name": "text", "data": "3+" } ] }, { "name": "text", "data": ",Eu" }, { "name": "sup", "data": [ { "name": "text", "data": "3+" } ] }, { "name": "text", "data": " phosphors" }, { "name": "text", "data": " [J]. " }, { "name": "italic", "data": [ { "name": "text", "data": "Ceram. Int" } ] }, { "name": "text", "data": "." }, { "name": "text", "data": ", " }, { "name": "text", "data": "2020" }, { "name": "text", "data": ", " }, { "name": "text", "data": "46" }, { "name": "text", "data": "(" }, { "name": "text", "data": "5" }, { "name": "text", "data": "):" }, { "name": "text", "data": "6154" }, { "name": "text", "data": "-" }, { "name": "text", "data": "6159" }, { "name": "text", "data": "." } ], "title": "Luminescence and self-referenced optical temperature sensing performance in Ca2YZr2Al3O12∶Bi3+,Eu3+ phosphors" } ] }, { "id": "R2", "label": "[2]", "citation": [ { "lang": "en", "text": [ { "name": "text", "data": "SONG Y Y" }, { "name": "text", "data": ", " }, { "name": "text", "data": "GUO N" }, { "name": "text", "data": ", " }, { "name": "text", "data": "LI J" }, { "name": "text", "data": ", " }, { "name": "text", "data": "et al" }, { "name": "text", "data": ". " }, { "name": "text", "data": "Photoluminescence and temperature sensing of lanthanide Eu" }, { "name": "sup", "data": [ { "name": "text", "data": "3+" } ] }, { "name": "text", "data": " and transition metal Mn" }, { "name": "sup", "data": [ { "name": "text", "data": "4+" } ] }, { "name": "text", "data": " dual-doped antimoniate phosphor through site-beneficial occupation" }, { "name": "text", "data": " [J]. " }, { "name": "italic", "data": [ { "name": "text", "data": "Ceram. Int" } ] }, { "name": "text", "data": "." }, { "name": "text", "data": ", " }, { "name": "text", "data": "2020" }, { "name": "text", "data": ", " }, { "name": "text", "data": "46" }, { "name": "text", "data": "(" }, { "name": "text", "data": "14" }, { "name": "text", "data": "):" }, { "name": "text", "data": "22164" }, { "name": "text", "data": "-" }, { "name": "text", "data": "22170" }, { "name": "text", "data": "." } ], "title": "Photoluminescence and temperature sensing of lanthanide Eu3+ and transition metal Mn4+ dual-doped antimoniate phosphor through site-beneficial occupation" } ] }, { "id": "R3", "label": "[3]", "citation": [ { "lang": "zh", "text": [ { "name": "text", "data": "王艺蒙" }, { "name": "text", "data": ", " }, { "name": "text", "data": "舒浩文" }, { "name": "text", "data": ", " }, { "name": "text", "data": "韩秀友" }, { "name": "text", "data": ". " }, { "name": "text", "data": "高精度硅基集成光学温度传感器研究" }, { "name": "text", "data": " [J]. " }, { "name": "text", "data": "中国光学" }, { "name": "text", "data": ", " }, { "name": "text", "data": "2021" }, { "name": "text", "data": ", " }, { "name": "text", "data": "14" }, { "name": "text", "data": "(" }, { "name": "text", "data": "6" }, { "name": "text", "data": "):" }, { "name": "text", "data": "1355" }, { "name": "text", "data": "-" }, { "name": "text", "data": "1361" }, { "name": "text", "data": "." } ], "title": "高精度硅基集成光学温度传感器研究" }, { "lang": "en", "text": [ { "name": "text", "data": "WANG Y M" }, { "name": "text", "data": ", " }, { "name": "text", "data": "SHU H W" }, { "name": "text", "data": ", " }, { "name": "text", "data": "HAN X Y" }, { "name": "text", "data": ". " }, { "name": "text", "data": "High-precision silicon-based integrated optical temperature sensor" }, { "name": "text", "data": " [J]. " }, { "name": "italic", "data": [ { "name": "text", "data": "Chin. Opt" } ] }, { "name": "text", "data": "." }, { "name": "text", "data": ", " }, { "name": "text", "data": "2021" }, { "name": "text", "data": ", " }, { "name": "text", "data": "14" }, { "name": "text", "data": "(" }, { "name": "text", "data": "6" }, { "name": "text", "data": "):" }, { "name": "text", "data": "1355" }, { "name": "text", "data": "-" }, { "name": "text", "data": "1361" }, { "name": "text", "data": ". " }, { "name": "text", "data": "(in Chinese)" } ], "title": "High-precision silicon-based integrated optical temperature sensor" } ] }, { "id": "R4", "label": "[4]", "citation": [ { "lang": "en", "text": [ { "name": "text", "data": "BRIK M G" }, { "name": "text", "data": ", " }, { "name": "text", "data": "SRIVASTAVA A M" }, { "name": "text", "data": ", " }, { "name": "text", "data": "AVRAM N M" }, { "name": "text", "data": ". " }, { "name": "text", "data": "Comparative analysis of crystal field effects and optical spectroscopy of six-coordinated Mn" }, { "name": "sup", "data": [ { "name": "text", "data": "4+" } ] }, { "name": "text", "data": " ion in the Y" }, { "name": "sub", "data": [ { "name": "text", "data": "2" } ] }, { "name": "text", "data": "Ti" }, { "name": "sub", "data": [ { "name": "text", "data": "2" } ] }, { "name": "text", "data": "O" }, { "name": "sub", "data": [ { "name": "text", "data": "7" } ] }, { "name": "text", "data": " and Y" }, { "name": "sub", "data": [ { "name": "text", "data": "2" } ] }, { "name": "text", "data": "Sn" }, { "name": "sub", "data": [ { "name": "text", "data": "2" } ] }, { "name": "text", "data": "O" }, { "name": "sub", "data": [ { "name": "text", "data": "7" } ] }, { "name": "text", "data": " pyrochlores" }, { "name": "text", "data": " [J]. " }, { "name": "italic", "data": [ { "name": "text", "data": "Opt. Mater" } ] }, { "name": "text", "data": "." }, { "name": "text", "data": ", " }, { "name": "text", "data": "2011" }, { "name": "text", "data": ", " }, { "name": "text", "data": "33" }, { "name": "text", "data": "(" }, { "name": "text", "data": "11" }, { "name": "text", "data": "):" }, { "name": "text", "data": "1671" }, { "name": "text", "data": "-" }, { "name": "text", "data": "1676" }, { "name": "text", "data": "." } ], "title": "Comparative analysis of crystal field effects and optical spectroscopy of six-coordinated Mn4+ ion in the Y2Ti2O7 and Y2Sn2O7 pyrochlores" } ] }, { "id": "R5", "label": "[5]", "citation": [ { "lang": "en", "text": [ { "name": "text", "data": "WEI Y" }, { "name": "text", "data": ", " }, { "name": "text", "data": "YANG H" }, { "name": "text", "data": ", " }, { "name": "text", "data": "GAO Z Y" }, { "name": "text", "data": ", " }, { "name": "text", "data": "et al" }, { "name": "text", "data": ". " }, { "name": "text", "data": "Strategies for designing antithermal-quenching red phosphors" }, { "name": "text", "data": " [J]. " }, { "name": "italic", "data": [ { "name": "text", "data": "Adv. Sci" } ] }, { "name": "text", "data": "." }, { "name": "text", "data": ", " }, { "name": "text", "data": "2020" }, { "name": "text", "data": ", " }, { "name": "text", "data": "7" }, { "name": "text", "data": "(" }, { "name": "text", "data": "8" }, { "name": "text", "data": "):" }, { "name": "text", "data": "1903060-1-9" }, { "name": "text", "data": "." } ], "title": "Strategies for designing antithermal-quenching red phosphors" } ] }, { "id": "R6", "label": "[6]", "citation": [ { "lang": "en", "text": [ { "name": "text", "data": "BAO G C" }, { "name": "text", "data": ", " }, { "name": "text", "data": "WONG K L" }, { "name": "text", "data": ", " }, { "name": "text", "data": "JIN D Y" }, { "name": "text", "data": ", " }, { "name": "text", "data": "et al" }, { "name": "text", "data": ". " }, { "name": "text", "data": "A stoichiometric terbium-europium dyad molecular thermometer:energy transfer properties" }, { "name": "text", "data": " [J]. " }, { "name": "italic", "data": [ { "name": "text", "data": "Light" } ] }, { "name": "text", "data": ":" }, { "name": "italic", "data": [ { "name": "text", "data": "Sci. Appl" } ] }, { "name": "text", "data": "." }, { "name": "text", "data": ", " }, { "name": "text", "data": "2018" }, { "name": "text", "data": ", " }, { "name": "text", "data": "7" }, { "name": "text", "data": "(" }, { "name": "text", "data": "1" }, { "name": "text", "data": "):" }, { "name": "text", "data": "96-1-10" }, { "name": "text", "data": "." } ], "title": "A stoichiometric terbium-europium dyad molecular thermometer:energy transfer properties" } ] }, { "id": "R7", "label": "[7]", "citation": [ { "lang": "en", "text": [ { "name": "text", "data": "AMARASINGHE D K" }, { "name": "text", "data": ", " }, { "name": "text", "data": "RABUFFETTI F A" }, { "name": "text", "data": ". " }, { "name": "text", "data": "Bandshift luminescence thermometry using Mn" }, { "name": "sup", "data": [ { "name": "text", "data": "4+" } ] }, { "name": "text", "data": "∶Na" }, { "name": "sub", "data": [ { "name": "text", "data": "4" } ] }, { "name": "text", "data": "Mg(WO" }, { "name": "sub", "data": [ { "name": "text", "data": "4" } ] }, { "name": "text", "data": ")" }, { "name": "sub", "data": [ { "name": "text", "data": "3" } ] }, { "name": "text", "data": " phosphors" }, { "name": "text", "data": " [J]. " }, { "name": "italic", "data": [ { "name": "text", "data": "Chem. Mater" } ] }, { "name": "text", "data": "." }, { "name": "text", "data": ", " }, { "name": "text", "data": "2019" }, { "name": "text", "data": ", " }, { "name": "text", "data": "31" }, { "name": "text", "data": "(" }, { "name": "text", "data": "24" }, { "name": "text", "data": "):" }, { "name": "text", "data": "10197" }, { "name": "text", "data": "-" }, { "name": "text", "data": "10204" }, { "name": "text", "data": "." } ], "title": "Bandshift luminescence thermometry using Mn4+∶Na4Mg(WO4)3 phosphors" } ] }, { "id": "R8", "label": "[8]", "citation": [ { "lang": "en", "text": [ { "name": "text", "data": "KATUMO N" }, { "name": "text", "data": ", " }, { "name": "text", "data": "GAO G J" }, { "name": "text", "data": ", " }, { "name": "text", "data": "LAUFER F" }, { "name": "text", "data": ", " }, { "name": "text", "data": "et al" }, { "name": "text", "data": ". " }, { "name": "text", "data": "Smartphone-based luminescent thermometry via temperature-sensitive delayed fluorescence from Gd" }, { "name": "sub", "data": [ { "name": "text", "data": "2" } ] }, { "name": "text", "data": "O" }, { "name": "sub", "data": [ { "name": "text", "data": "2" } ] }, { "name": "text", "data": "S∶Eu" }, { "name": "sup", "data": [ { "name": "text", "data": "3+" } ] }, { "name": "text", "data": " [J]. " }, { "name": "italic", "data": [ { "name": "text", "data": "Adv. Opt. Mater" } ] }, { "name": "text", "data": "." }, { "name": "text", "data": ", " }, { "name": "text", "data": "2020" }, { "name": "text", "data": ", " }, { "name": "text", "data": "8" }, { "name": "text", "data": "(" }, { "name": "text", "data": "19" }, { "name": "text", "data": "):" }, { "name": "text", "data": "2000507-1-7" }, { "name": "text", "data": "." } ], "title": "Smartphone-based luminescent thermometry via temperature-sensitive delayed fluorescence from Gd2O2S∶Eu3+" } ] }, { "id": "R9", "label": "[9]", "citation": [ { "lang": "en", "text": [ { "name": "text", "data": "LUO H Y" }, { "name": "text", "data": ", " }, { "name": "text", "data": "LI X Y" }, { "name": "text", "data": ", " }, { "name": "text", "data": "WANG X" }, { "name": "text", "data": ", " }, { "name": "text", "data": "et al" }, { "name": "text", "data": ". " }, { "name": "text", "data": "Highly thermal-sensitive robust LaTiSbO" }, { "name": "sub", "data": [ { "name": "text", "data": "6" } ] }, { "name": "text", "data": "∶Mn" }, { "name": "sup", "data": [ { "name": "text", "data": "4+" } ] }, { "name": "text", "data": " with a single-band emission and its topological architecture for single/dual-mode optical thermometry" }, { "name": "text", "data": " [J]. " }, { "name": "italic", "data": [ { "name": "text", "data": "Chem. Eng. J" } ] }, { "name": "text", "data": "." }, { "name": "text", "data": ", " }, { "name": "text", "data": "2020" }, { "name": "text", "data": ", " }, { "name": "text", "data": "384" }, { "name": "text", "data": ":" }, { "name": "text", "data": "123272" }, { "name": "text", "data": "." } ], "title": "Highly thermal-sensitive robust LaTiSbO6∶Mn4+ with a single-band emission and its topological architecture for single/dual-mode optical thermometry" } ] }, { "id": "R10", "label": "[10]", "citation": [ { "lang": "en", "text": [ { "name": "text", "data": "XU M" }, { "name": "text", "data": ", " }, { "name": "text", "data": "ZOU X M" }, { "name": "text", "data": ", " }, { "name": "text", "data": "SU Q Q" }, { "name": "text", "data": ", " }, { "name": "text", "data": "et al" }, { "name": "text", "data": ". " }, { "name": "text", "data": "Ratiometric nanothermometer in vivo based on triplet sensitized upconversion" }, { "name": "text", "data": " [J]. " }, { "name": "italic", "data": [ { "name": "text", "data": "Nat. Commun" } ] }, { "name": "text", "data": "." }, { "name": "text", "data": ", " }, { "name": "text", "data": "2018" }, { "name": "text", "data": ", " }, { "name": "text", "data": "9" }, { "name": "text", "data": "(" }, { "name": "text", "data": "1" }, { "name": "text", "data": "):" }, { "name": "text", "data": "2698-1-7" }, { "name": "text", "data": "." } ], "title": "Ratiometric nanothermometer in vivo based on triplet sensitized upconversion" } ] }, { "id": "R11", "label": "[11]", "citation": [ { "lang": "en", "text": [ { "name": "text", "data": "MCLAURIN E J" }, { "name": "text", "data": ", " }, { "name": "text", "data": "BRADSHAW L R" }, { "name": "text", "data": ", " }, { "name": "text", "data": "GAMELIN D R" }, { "name": "text", "data": ". " }, { "name": "text", "data": "Dual-emitting nanoscale temperature sensors" }, { "name": "text", "data": " [J]. " }, { "name": "italic", "data": [ { "name": "text", "data": "Chem. Mater" } ] }, { "name": "text", "data": "." }, { "name": "text", "data": ", " }, { "name": "text", "data": "2013" }, { "name": "text", "data": ", " }, { "name": "text", "data": "25" }, { "name": "text", "data": "(" }, { "name": "text", "data": "8" }, { "name": "text", "data": "):" }, { "name": "text", "data": "1283" }, { "name": "text", "data": "-" }, { "name": "text", "data": "1292" }, { "name": "text", "data": "." } ], "title": "Dual-emitting nanoscale temperature sensors" } ] }, { "id": "R12", "label": "[12]", "citation": [ { "lang": "en", "text": [ { "name": "text", "data": "NIKOLI Ć M G" }, { "name": "text", "data": ", " }, { "name": "text", "data": "ANTI Ć Ž" }, { "name": "text", "data": ", " }, { "name": "text", "data": "ĆULUBRK S" }, { "name": "text", "data": ", " }, { "name": "text", "data": "et al" }, { "name": "text", "data": ". " }, { "name": "text", "data": "Temperature sensing with Eu" }, { "name": "sup", "data": [ { "name": "text", "data": "3+" } ] }, { "name": "text", "data": " doped TiO" }, { "name": "sub", "data": [ { "name": "text", "data": "2" } ] }, { "name": "text", "data": " nanoparticles" }, { "name": "text", "data": " [J]. " }, { "name": "italic", "data": [ { "name": "text", "data": "Sens. Actuators" } ] }, { "name": "text", "data": " B:" }, { "name": "italic", "data": [ { "name": "text", "data": "Chem" } ] }, { "name": "text", "data": "." }, { "name": "text", "data": ", " }, { "name": "text", "data": "2014" }, { "name": "text", "data": ", " }, { "name": "text", "data": "201" }, { "name": "text", "data": ":" }, { "name": "text", "data": "46" }, { "name": "text", "data": "-" }, { "name": "text", "data": "50" }, { "name": "text", "data": "." } ], "title": "Temperature sensing with Eu3+ doped TiO2 nanoparticles" } ] }, { "id": "R13", "label": "[13]", "citation": [ { "lang": "en", "text": [ { "name": "text", "data": "SHI R" }, { "name": "text", "data": ", " }, { "name": "text", "data": "LIN L T" }, { "name": "text", "data": ", " }, { "name": "text", "data": "DORENBOS P" }, { "name": "text", "data": ", " }, { "name": "text", "data": "et al" }, { "name": "text", "data": ". " }, { "name": "text", "data": "Development of a potential optical thermometric material through photoluminescence of Pr" }, { "name": "sup", "data": [ { "name": "text", "data": "3+" } ] }, { "name": "text", "data": " in La" }, { "name": "sub", "data": [ { "name": "text", "data": "2" } ] }, { "name": "text", "data": "MgTiO" }, { "name": "sub", "data": [ { "name": "text", "data": "6" } ] }, { "name": "text", "data": " [J]. " }, { "name": "italic", "data": [ { "name": "text", "data": "J. Mater. Chem" } ] }, { "name": "text", "data": ". C" }, { "name": "text", "data": ", " }, { "name": "text", "data": "2017" }, { "name": "text", "data": ", " }, { "name": "text", "data": "5" }, { "name": "text", "data": "(" }, { "name": "text", "data": "41" }, { "name": "text", "data": "):" }, { "name": "text", "data": "10737" }, { "name": "text", "data": "-" }, { "name": "text", "data": "10745" }, { "name": "text", "data": "." } ], "title": "Development of a potential optical thermometric material through photoluminescence of Pr3+ in La2MgTiO6" } ] }, { "id": "R14", "label": "[14]", "citation": [ { "lang": "en", "text": [ { "name": "text", "data": "MARCINIAK L" }, { "name": "text", "data": ", " }, { "name": "text", "data": "PILCH A" }, { "name": "text", "data": ", " }, { "name": "text", "data": "ARABASZ S" }, { "name": "text", "data": ", " }, { "name": "text", "data": "et al" }, { "name": "text", "data": ". " }, { "name": "text", "data": "Heterogeneously Nd" }, { "name": "sup", "data": [ { "name": "text", "data": "3+" } ] }, { "name": "text", "data": " doped single nanoparticles for NIR-induced heat conversion,luminescence,and thermometry" }, { "name": "text", "data": " [J]. " }, { "name": "italic", "data": [ { "name": "text", "data": "Nanoscale" } ] }, { "name": "text", "data": ", " }, { "name": "text", "data": "2017" }, { "name": "text", "data": ", " }, { "name": "text", "data": "9" }, { "name": "text", "data": "(" }, { "name": "text", "data": "24" }, { "name": "text", "data": "):" }, { "name": "text", "data": "8288" }, { "name": "text", "data": "-" }, { "name": "text", "data": "8297" }, { "name": "text", "data": "." } ], "title": "Heterogeneously Nd3+ doped single nanoparticles for NIR-induced heat conversion,luminescence,and thermometry" } ] }, { "id": "R15", "label": "[15]", "citation": [ { "lang": "zh", "text": [ { "name": "text", "data": "李晓晓" }, { "name": "text", "data": ", " }, { "name": "text", "data": "李蕴乾" }, { "name": "text", "data": ", " }, { "name": "text", "data": "汪欣" }, { "name": "text", "data": ", " }, { "name": "text", "data": "等" }, { "name": "text", "data": ". " }, { "name": "text", "data": "高灵敏度下转换光学测温材料∶NaGd(WO" }, { "name": "sub", "data": [ { "name": "text", "data": "4" } ] }, { "name": "text", "data": ")" }, { "name": "sub", "data": [ { "name": "text", "data": "2" } ] }, { "name": "text", "data": "∶Yb" }, { "name": "sup", "data": [ { "name": "text", "data": "3+" } ] }, { "name": "text", "data": "/Er" }, { "name": "sup", "data": [ { "name": "text", "data": "3+" } ] }, { "name": "text", "data": " [J]. " }, { "name": "text", "data": "中国光学" }, { "name": "text", "data": ", " }, { "name": "text", "data": "2019" }, { "name": "text", "data": ", " }, { "name": "text", "data": "12" }, { "name": "text", "data": "(" }, { "name": "text", "data": "3" }, { "name": "text", "data": "):" }, { "name": "text", "data": "596" }, { "name": "text", "data": "-" }, { "name": "text", "data": "605" }, { "name": "text", "data": "." } ], "title": "高灵敏度下转换光学测温材料∶NaGd(WO4)2∶Yb3+/Er3+" }, { "lang": "en", "text": [ { "name": "text", "data": "LI X X" }, { "name": "text", "data": ", " }, { "name": "text", "data": "LI Y Q" }, { "name": "text", "data": ", " }, { "name": "text", "data": "WANG X" }, { "name": "text", "data": ", " }, { "name": "text", "data": "et al" }, { "name": "text", "data": ". " }, { "name": "text", "data": "Highly sensitive down-conversion optical temperature-measurement material∶NaGd(WO" }, { "name": "sub", "data": [ { "name": "text", "data": "4" } ] }, { "name": "text", "data": ")" }, { "name": "sub", "data": [ { "name": "text", "data": "2" } ] }, { "name": "text", "data": "∶Yb" }, { "name": "sup", "data": [ { "name": "text", "data": "3+" } ] }, { "name": "text", "data": "/Er" }, { "name": "sup", "data": [ { "name": "text", "data": "3+" } ] }, { "name": "text", "data": " [J]. " }, { "name": "italic", "data": [ { "name": "text", "data": "Chin. Opt" } ] }, { "name": "text", "data": "." }, { "name": "text", "data": ", " }, { "name": "text", "data": "2019" }, { "name": "text", "data": ", " }, { "name": "text", "data": "12" }, { "name": "text", "data": "(" }, { "name": "text", "data": "3" }, { "name": "text", "data": "):" }, { "name": "text", "data": "596" }, { "name": "text", "data": "-" }, { "name": "text", "data": "605" }, { "name": "text", "data": ". " }, { "name": "text", "data": "(in Chinese)" } ], "title": "Highly sensitive down-conversion optical temperature-measurement material∶NaGd(WO4)2∶Yb3+/Er3+" } ] }, { "id": "R16", "label": "[16]", "citation": [ { "lang": "en", "text": [ { "name": "text", "data": "CAI P Q" }, { "name": "text", "data": ", " }, { "name": "text", "data": "QIN L" }, { "name": "text", "data": ", " }, { "name": "text", "data": "CHEN C L" }, { "name": "text", "data": ", " }, { "name": "text", "data": "et al" }, { "name": "text", "data": ". " }, { "name": "text", "data": "Optical thermometry based on vibration sidebands in Y" }, { "name": "sub", "data": [ { "name": "text", "data": "2" } ] }, { "name": "text", "data": "MgTiO" }, { "name": "sub", "data": [ { "name": "text", "data": "6" } ] }, { "name": "text", "data": "∶Mn" }, { "name": "sup", "data": [ { "name": "text", "data": "4+" } ] }, { "name": "text", "data": " double perovskite" }, { "name": "text", "data": " [J]. " }, { "name": "italic", "data": [ { "name": "text", "data": "Inorg. Chem" } ] }, { "name": "text", "data": "." }, { "name": "text", "data": ", " }, { "name": "text", "data": "2018" }, { "name": "text", "data": ", " }, { "name": "text", "data": "57" }, { "name": "text", "data": "(" }, { "name": "text", "data": "6" }, { "name": "text", "data": "):" }, { "name": "text", "data": "3073" }, { "name": "text", "data": "-" }, { "name": "text", "data": "3081" }, { "name": "text", "data": "." } ], "title": "Optical thermometry based on vibration sidebands in Y2MgTiO6∶Mn4+ double perovskite" } ] }, { "id": "R17", "label": "[17]", "citation": [ { "lang": "en", "text": [ { "name": "text", "data": "SEKULI ĆM" }, { "name": "text", "data": ", " }, { "name": "text", "data": "-DOR-DEVI Ć V" }, { "name": "text", "data": ", " }, { "name": "text", "data": "RISTI Ć Z" }, { "name": "text", "data": ", " }, { "name": "text", "data": "et al" }, { "name": "text", "data": ". " }, { "name": "text", "data": "Highly sensitive dual self-referencing temperature readout from the Mn" }, { "name": "sup", "data": [ { "name": "text", "data": "4+" } ] }, { "name": "text", "data": "/ Ho" }, { "name": "sup", "data": [ { "name": "text", "data": "3+" } ] }, { "name": "text", "data": " binary luminescence thermometry probe" }, { "name": "text", "data": " [J]. " }, { "name": "italic", "data": [ { "name": "text", "data": "Adv. Opt. Mater" } ] }, { "name": "text", "data": "." }, { "name": "text", "data": ", " }, { "name": "text", "data": "2018" }, { "name": "text", "data": ", " }, { "name": "text", "data": "6" }, { "name": "text", "data": "(" }, { "name": "text", "data": "17" }, { "name": "text", "data": "):" }, { "name": "text", "data": "1800552-1-7" }, { "name": "text", "data": "." } ], "title": "Highly sensitive dual self-referencing temperature readout from the Mn4+/ Ho3+ binary luminescence thermometry probe" } ] }, { "id": "R18", "label": "[18]", "citation": [ { "lang": "en", "text": [ { "name": "text", "data": "TAKEDA Y" }, { "name": "text", "data": ", " }, { "name": "text", "data": "KATO H" }, { "name": "text", "data": ", " }, { "name": "text", "data": "KOBAYASHI M" }, { "name": "text", "data": ", " }, { "name": "text", "data": "et al" }, { "name": "text", "data": ". " }, { "name": "text", "data": "Photoluminescence properties of double perovskite tantalates activated with Mn" }, { "name": "sup", "data": [ { "name": "text", "data": "4+" } ] }, { "name": "text", "data": "," }, { "name": "italic", "data": [ { "name": "text", "data": "AE" } ] }, { "name": "sub", "data": [ { "name": "text", "data": "2" } ] }, { "name": "text", "data": "LaTaO" }, { "name": "sub", "data": [ { "name": "text", "data": "6" } ] }, { "name": "text", "data": "∶Mn" }, { "name": "sup", "data": [ { "name": "text", "data": "4+" } ] }, { "name": "text", "data": " (" }, { "name": "italic", "data": [ { "name": "text", "data": "AE" } ] }, { "name": "text", "data": "=Ca,Sr,and Ba)" }, { "name": "text", "data": " [J]. " }, { "name": "italic", "data": [ { "name": "text", "data": "J. Phys. Chem." } ] }, { "name": "text", "data": " C" }, { "name": "text", "data": ", " }, { "name": "text", "data": "2017" }, { "name": "text", "data": ", " }, { "name": "text", "data": "121" }, { "name": "text", "data": "(" }, { "name": "text", "data": "34" }, { "name": "text", "data": "):" }, { "name": "text", "data": "18837" }, { "name": "text", "data": "-" }, { "name": "text", "data": "18844" }, { "name": "text", "data": "." } ], "title": "Photoluminescence properties of double perovskite tantalates activated with Mn4+,AE2LaTaO6∶Mn4+ (AE=Ca,Sr,and Ba)" } ] }, { "id": "R19", "label": "[19]", "citation": [ { "lang": "en", "text": [ { "name": "text", "data": "YANG S H" }, { "name": "text", "data": ", " }, { "name": "text", "data": "LEE Y C" }, { "name": "text", "data": ", " }, { "name": "text", "data": "HUNG Y C" }, { "name": "text", "data": ". " }, { "name": "text", "data": "Thermometry of red nanoflaked SrAl" }, { "name": "sub", "data": [ { "name": "text", "data": "12" } ] }, { "name": "text", "data": "O" }, { "name": "sub", "data": [ { "name": "text", "data": "19" } ] }, { "name": "text", "data": "∶Mn" }, { "name": "sup", "data": [ { "name": "text", "data": "4+" } ] }, { "name": "text", "data": " synthesized with boric acid flux" }, { "name": "text", "data": " [J]. " }, { "name": "italic", "data": [ { "name": "text", "data": "Ceram. Int" } ] }, { "name": "text", "data": "." }, { "name": "text", "data": ", " }, { "name": "text", "data": "2018" }, { "name": "text", "data": ", " }, { "name": "text", "data": "44" }, { "name": "text", "data": "(" }, { "name": "text", "data": "10" }, { "name": "text", "data": "):" }, { "name": "text", "data": "11665" }, { "name": "text", "data": "-" }, { "name": "text", "data": "11673" }, { "name": "text", "data": "." } ], "title": "Thermometry of red nanoflaked SrAl12O19∶Mn4+ synthesized with boric acid flux" } ] }, { "id": "R20", "label": "[20]", "citation": [ { "lang": "en", "text": [ { "name": "text", "data": "CAI P Q" }, { "name": "text", "data": ", " }, { "name": "text", "data": "QIN L" }, { "name": "text", "data": ", " }, { "name": "text", "data": "CHEN C L" }, { "name": "text", "data": ", " }, { "name": "text", "data": "et al" }, { "name": "text", "data": ". " }, { "name": "text", "data": "Luminescence,energy transfer and optical thermometry of a novel narrow red emitting phosphor:Cs" }, { "name": "sub", "data": [ { "name": "text", "data": "2" } ] }, { "name": "text", "data": "WO" }, { "name": "sub", "data": [ { "name": "text", "data": "2" } ] }, { "name": "text", "data": "F" }, { "name": "sub", "data": [ { "name": "text", "data": "4" } ] }, { "name": "text", "data": "∶Mn" }, { "name": "sup", "data": [ { "name": "text", "data": "4+" } ] }, { "name": "text", "data": " [J]. " }, { "name": "italic", "data": [ { "name": "text", "data": "Dalton Trans" } ] }, { "name": "text", "data": "." }, { "name": "text", "data": ", " }, { "name": "text", "data": "2017" }, { "name": "text", "data": ", " }, { "name": "text", "data": "46" }, { "name": "text", "data": "(" }, { "name": "text", "data": "41" }, { "name": "text", "data": "):" }, { "name": "text", "data": "14331" }, { "name": "text", "data": "-" }, { "name": "text", "data": "14340" }, { "name": "text", "data": "." } ], "title": "Luminescence,energy transfer and optical thermometry of a novel narrow red emitting phosphor:Cs2WO2F4∶Mn4+" } ] }, { "id": "R21", "label": "[21]", "citation": [ { "lang": "en", "text": [ { "name": "text", "data": "WU Y B" }, { "name": "text", "data": ", " }, { "name": "text", "data": "ZHUANG Y X" }, { "name": "text", "data": ", " }, { "name": "text", "data": "XIE R J" }, { "name": "text", "data": ", " }, { "name": "text", "data": "et al" }, { "name": "text", "data": ". " }, { "name": "text", "data": "Novel Mn" }, { "name": "sup", "data": [ { "name": "text", "data": "4+" } ] }, { "name": "text", "data": " doped red phosphors composed of MgAl" }, { "name": "sub", "data": [ { "name": "text", "data": "2" } ] }, { "name": "text", "data": "O" }, { "name": "sub", "data": [ { "name": "text", "data": "4" } ] }, { "name": "text", "data": " and CaAl" }, { "name": "sub", "data": [ { "name": "text", "data": "12" } ] }, { "name": "text", "data": "O" }, { "name": "sub", "data": [ { "name": "text", "data": "19" } ] }, { "name": "text", "data": " phases for light-emitting diodes" }, { "name": "text", "data": " [J]. " }, { "name": "italic", "data": [ { "name": "text", "data": "Dalton Trans" } ] }, { "name": "text", "data": "." }, { "name": "text", "data": ", " }, { "name": "text", "data": "2020" }, { "name": "text", "data": ", " }, { "name": "text", "data": "49" }, { "name": "text", "data": "(" }, { "name": "text", "data": "11" }, { "name": "text", "data": "):" }, { "name": "text", "data": "3606" }, { "name": "text", "data": "-" }, { "name": "text", "data": "3614" }, { "name": "text", "data": "." } ], "title": "Novel Mn4+ doped red phosphors composed of MgAl2O4 and CaAl12O19 phases for light-emitting diodes" } ] }, { "id": "R22", "label": "[22]", "citation": [ { "lang": "en", "text": [ { "name": "text", "data": "COSTA G" }, { "name": "text", "data": ", " }, { "name": "text", "data": "RIBEIRO M J" }, { "name": "text", "data": ", " }, { "name": "text", "data": "HAJJAJI W" }, { "name": "text", "data": ", " }, { "name": "text", "data": "et al" }, { "name": "text", "data": ". " }, { "name": "text", "data": "Ni-doped hibonite (CaAl" }, { "name": "sub", "data": [ { "name": "text", "data": "12" } ] }, { "name": "text", "data": "O" }, { "name": "sub", "data": [ { "name": "text", "data": "19" } ] }, { "name": "text", "data": "):a new turquoise blue ceramic pigment" }, { "name": "text", "data": " [J]. " }, { "name": "italic", "data": [ { "name": "text", "data": "J. Eur. Ceram. Soc" } ] }, { "name": "text", "data": "." }, { "name": "text", "data": ", " }, { "name": "text", "data": "2009" }, { "name": "text", "data": ", " }, { "name": "text", "data": "29" }, { "name": "text", "data": "(" }, { "name": "text", "data": "13" }, { "name": "text", "data": "):" }, { "name": "text", "data": "2671" }, { "name": "text", "data": "-" }, { "name": "text", "data": "2678" }, { "name": "text", "data": "." } ], "title": "Ni-doped hibonite (CaAl12O19):a new turquoise blue ceramic pigment" } ] }, { "id": "R23", "label": "[23]", "citation": [ { "lang": "zh", "text": [ { "name": "text", "data": "王细凤" }, { "name": "text", "data": ", " }, { "name": "text", "data": "夏威" }, { "name": "text", "data": ", " }, { "name": "text", "data": "肖志国" }, { "name": "text", "data": ". " }, { "name": "text", "data": "一种新型红色荧光粉CaAl" }, { "name": "sub", "data": [ { "name": "text", "data": "12" } ] }, { "name": "text", "data": "O" }, { "name": "sub", "data": [ { "name": "text", "data": "19" } ] }, { "name": "text", "data": "∶Eu,Mn的制备及发光性能" }, { "name": "text", "data": " [J]. " }, { "name": "text", "data": "发光学报" }, { "name": "text", "data": ", " }, { "name": "text", "data": "2009" }, { "name": "text", "data": ", " }, { "name": "text", "data": "30" }, { "name": "text", "data": "(" }, { "name": "text", "data": "3" }, { "name": "text", "data": "):" }, { "name": "text", "data": "405" }, { "name": "text", "data": "-" }, { "name": "text", "data": "408" }, { "name": "text", "data": "." } ], "title": "一种新型红色荧光粉CaAl12O19∶Eu,Mn的制备及发光性能" }, { "lang": "en", "text": [ { "name": "text", "data": "WANG X F" }, { "name": "text", "data": ", " }, { "name": "text", "data": "XIA W" }, { "name": "text", "data": ", " }, { "name": "text", "data": "XIAO Z G" }, { "name": "text", "data": ". " }, { "name": "text", "data": "Synthesis and luminescent properties of a novel red phosphor CaAl" }, { "name": "sub", "data": [ { "name": "text", "data": "12" } ] }, { "name": "text", "data": "O" }, { "name": "sub", "data": [ { "name": "text", "data": "19" } ] }, { "name": "text", "data": "∶Eu,Mn" }, { "name": "text", "data": " [J]. " }, { "name": "italic", "data": [ { "name": "text", "data": "Chin. J. Lumin" } ] }, { "name": "text", "data": "." }, { "name": "text", "data": ", " }, { "name": "text", "data": "2009" }, { "name": "text", "data": ", " }, { "name": "text", "data": "30" }, { "name": "text", "data": "(" }, { "name": "text", "data": "3" }, { "name": "text", "data": "):" }, { "name": "text", "data": "405" }, { "name": "text", "data": "-" }, { "name": "text", "data": "408" }, { "name": "text", "data": ". " }, { "name": "text", "data": "(in Chinese)" } ], "title": "Synthesis and luminescent properties of a novel red phosphor CaAl12O19∶Eu,Mn" } ] }, { "id": "R24", "label": "[24]", "citation": [ { "lang": "en", "text": [ { "name": "text", "data": "SINGH V" }, { "name": "text", "data": ", " }, { "name": "text", "data": "CHAKRADHAR R P S" }, { "name": "text", "data": ", " }, { "name": "text", "data": "RAO J L" }, { "name": "text", "data": ", " }, { "name": "text", "data": "et al" }, { "name": "text", "data": ". " }, { "name": "text", "data": "Characterization,EPR and luminescence studies of ZnAl" }, { "name": "sub", "data": [ { "name": "text", "data": "2" } ] }, { "name": "text", "data": "O" }, { "name": "sub", "data": [ { "name": "text", "data": "4" } ] }, { "name": "text", "data": "∶Mn phosphors" }, { "name": "text", "data": " [J]. " }, { "name": "italic", "data": [ { "name": "text", "data": "J. Lumin" } ] }, { "name": "text", "data": "." }, { "name": "text", "data": ", " }, { "name": "text", "data": "2008" }, { "name": "text", "data": ", " }, { "name": "text", "data": "128" }, { "name": "text", "data": "(" }, { "name": "text", "data": "3" }, { "name": "text", "data": "):" }, { "name": "text", "data": "394" }, { "name": "text", "data": "-" }, { "name": "text", "data": "402" }, { "name": "text", "data": "." } ], "title": "Characterization,EPR and luminescence studies of ZnAl2O4∶Mn phosphors" } ] }, { "id": "R25", "label": "[25]", "citation": [ { "lang": "zh", "text": [ { "name": "text", "data": "黄尚攀" }, { "name": "text", "data": ", " }, { "name": "text", "data": "魏智强" }, { "name": "text", "data": ", " }, { "name": "text", "data": "武晓娟" }, { "name": "text", "data": ", " }, { "name": "text", "data": "等" }, { "name": "text", "data": ". " }, { "name": "text", "data": "Cu" }, { "name": "sup", "data": [ { "name": "text", "data": "2+" } ] }, { "name": "text", "data": "掺杂ZnAl" }, { "name": "sub", "data": [ { "name": "text", "data": "2" } ] }, { "name": "text", "data": "O" }, { "name": "sub", "data": [ { "name": "text", "data": "4" } ] }, { "name": "text", "data": "纳米颗粒的光学性能" }, { "name": "text", "data": " [J]. " }, { "name": "text", "data": "发光学报" }, { "name": "text", "data": ", " }, { "name": "text", "data": "2019" }, { "name": "text", "data": ", " }, { "name": "text", "data": "40" }, { "name": "text", "data": "(" }, { "name": "text", "data": "11" }, { "name": "text", "data": "):" }, { "name": "text", "data": "1386" }, { "name": "text", "data": "-" }, { "name": "text", "data": "1393" }, { "name": "text", "data": "." } ], "title": "Cu2+掺杂ZnAl2O4纳米颗粒的光学性能" }, { "lang": "en", "text": [ { "name": "text", "data": "HUANG S P" }, { "name": "text", "data": ", " }, { "name": "text", "data": "WEI Z Q" }, { "name": "text", "data": ", " }, { "name": "text", "data": "WU X J" }, { "name": "text", "data": ", " }, { "name": "text", "data": "et al" }, { "name": "text", "data": ". " }, { "name": "text", "data": "Optical properties of Cu" }, { "name": "sup", "data": [ { "name": "text", "data": "2+" } ] }, { "name": "text", "data": " doped ZnAl" }, { "name": "sub", "data": [ { "name": "text", "data": "2" } ] }, { "name": "text", "data": "O" }, { "name": "sub", "data": [ { "name": "text", "data": "4" } ] }, { "name": "text", "data": " nanoparticles" }, { "name": "text", "data": " [J]. " }, { "name": "italic", "data": [ { "name": "text", "data": "Chin. J. Lumin" } ] }, { "name": "text", "data": "." }, { "name": "text", "data": ", " }, { "name": "text", "data": "2019" }, { "name": "text", "data": ", " }, { "name": "text", "data": "40" }, { "name": "text", "data": "(" }, { "name": "text", "data": "11" }, { "name": "text", "data": "):" }, { "name": "text", "data": "1386" }, { "name": "text", "data": "-" }, { "name": "text", "data": "1393" }, { "name": "text", "data": ". " }, { "name": "text", "data": "(in Chinese)" } ], "title": "Optical properties of Cu2+ doped ZnAl2O4 nanoparticles" } ] }, { "id": "R26", "label": "[26]", "citation": [ { "lang": "en", "text": [ { "name": "text", "data": "ZHU Y J" }, { "name": "text", "data": ", " }, { "name": "text", "data": "QIU Z X" }, { "name": "text", "data": ", " }, { "name": "text", "data": "AI B Y" }, { "name": "text", "data": ", " }, { "name": "text", "data": "et al" }, { "name": "text", "data": ". " }, { "name": "text", "data": "Significant improved quantum yields of CaAl" }, { "name": "sub", "data": [ { "name": "text", "data": "12" } ] }, { "name": "text", "data": "O" }, { "name": "sub", "data": [ { "name": "text", "data": "19" } ] }, { "name": "text", "data": "∶Mn" }, { "name": "sup", "data": [ { "name": "text", "data": "4+" } ] }, { "name": "text", "data": " red phosphor by co-doping Bi" }, { "name": "sup", "data": [ { "name": "text", "data": "3+" } ] }, { "name": "text", "data": " and B" }, { "name": "sup", "data": [ { "name": "text", "data": "3+" } ] }, { "name": "text", "data": " ions and dual applications for plant cultivations" }, { "name": "text", "data": " [J]. " }, { "name": "italic", "data": [ { "name": "text", "data": "J. Lumin" } ] }, { "name": "text", "data": "." }, { "name": "text", "data": ", " }, { "name": "text", "data": "2018" }, { "name": "text", "data": ", " }, { "name": "text", "data": "201" }, { "name": "text", "data": ":" }, { "name": "text", "data": "314" }, { "name": "text", "data": "-" }, { "name": "text", "data": "320" }, { "name": "text", "data": "." } ], "title": "Significant improved quantum yields of CaAl12O19∶Mn4+ red phosphor by co-doping Bi3+ and B3+ ions and dual applications for plant cultivations" } ] }, { "id": "R27", "label": "[27]", "citation": [ { "lang": "en", "text": [ { "name": "text", "data": "MURATA T" }, { "name": "text", "data": ", " }, { "name": "text", "data": "TANOUE T" }, { "name": "text", "data": ", " }, { "name": "text", "data": "IWASAKI M" }, { "name": "text", "data": ", " }, { "name": "text", "data": "et al" }, { "name": "text", "data": ". " }, { "name": "text", "data": "Fluorescence properties of Mn" }, { "name": "sup", "data": [ { "name": "text", "data": "4+" } ] }, { "name": "text", "data": " in CaAl" }, { "name": "sub", "data": [ { "name": "text", "data": "12" } ] }, { "name": "text", "data": "O" }, { "name": "sub", "data": [ { "name": "text", "data": "19" } ] }, { "name": "text", "data": " compounds as red-emitting phosphor for white LED" }, { "name": "text", "data": " [J]. " }, { "name": "italic", "data": [ { "name": "text", "data": "J. Lumin" } ] }, { "name": "text", "data": "." }, { "name": "text", "data": ", " }, { "name": "text", "data": "2005" }, { "name": "text", "data": ", " }, { "name": "text", "data": "114" }, { "name": "text", "data": "(" }, { "name": "text", "data": "3-4" }, { "name": "text", "data": "):" }, { "name": "text", "data": "207" }, { "name": "text", "data": "-" }, { "name": "text", "data": "212" }, { "name": "text", "data": "." } ], "title": "Fluorescence properties of Mn4+ in CaAl12O19 compounds as red-emitting phosphor for white LED" } ] }, { "id": "R28", "label": "[28]", "citation": [ { "lang": "en", "text": [ { "name": "text", "data": "CHEN Y B" }, { "name": "text", "data": ", " }, { "name": "text", "data": "CHEN J Q" }, { "name": "text", "data": ", " }, { "name": "text", "data": "LIANG J H" }, { "name": "text", "data": ", " }, { "name": "text", "data": "et al" }, { "name": "text", "data": ". " }, { "name": "text", "data": "Localized charge accumulation driven by Li" }, { "name": "sup", "data": [ { "name": "text", "data": "+" } ] }, { "name": "text", "data": " incorporation for efficient LED phosphors with tunable photoluminescence" }, { "name": "text", "data": " [J]. " }, { "name": "italic", "data": [ { "name": "text", "data": "Chem. Mater" } ] }, { "name": "text", "data": "." }, { "name": "text", "data": ", " }, { "name": "text", "data": "2020" }, { "name": "text", "data": ", " }, { "name": "text", "data": "32" }, { "name": "text", "data": "(" }, { "name": "text", "data": "22" }, { "name": "text", "data": "):" }, { "name": "text", "data": "9551" }, { "name": "text", "data": "-" }, { "name": "text", "data": "9559" }, { "name": "text", "data": "." } ], "title": "Localized charge accumulation driven by Li+ incorporation for efficient LED phosphors with tunable photoluminescence" } ] }, { "id": "R29", "label": "[29]", "citation": [ { "lang": "en", "text": [ { "name": "text", "data": "LU J" }, { "name": "text", "data": ", " }, { "name": "text", "data": "PAN Y X" }, { "name": "text", "data": ", " }, { "name": "text", "data": "WANG J G" }, { "name": "text", "data": ", " }, { "name": "text", "data": "et al" }, { "name": "text", "data": ". " }, { "name": "text", "data": "Reduction of Mn" }, { "name": "sup", "data": [ { "name": "text", "data": "4+" } ] }, { "name": "text", "data": " to Mn" }, { "name": "sup", "data": [ { "name": "text", "data": "2+" } ] }, { "name": "text", "data": " in CaAl" }, { "name": "sub", "data": [ { "name": "text", "data": "12" } ] }, { "name": "text", "data": "O" }, { "name": "sub", "data": [ { "name": "text", "data": "19" } ] }, { "name": "text", "data": " by co-doping charge compensators to obtain tunable photoluminescence" }, { "name": "text", "data": " [J]. " }, { "name": "italic", "data": [ { "name": "text", "data": "RSC Adv" } ] }, { "name": "text", "data": "." }, { "name": "text", "data": ", " }, { "name": "text", "data": "2013" }, { "name": "text", "data": ", " }, { "name": "text", "data": "3" }, { "name": "text", "data": "(" }, { "name": "text", "data": "14" }, { "name": "text", "data": "):" }, { "name": "text", "data": "4510" }, { "name": "text", "data": "-" }, { "name": "text", "data": "4513" }, { "name": "text", "data": "." } ], "title": "Reduction of Mn4+ to Mn2+ in CaAl12O19 by co-doping charge compensators to obtain tunable photoluminescence" } ] }, { "id": "R30", "label": "[30]", "citation": [ { "lang": "en", "text": [ { "name": "text", "data": "SINGH V" }, { "name": "text", "data": ", " }, { "name": "text", "data": "NATARAJAN V" }, { "name": "text", "data": ", " }, { "name": "text", "data": "ZHU J J" }, { "name": "text", "data": ". " }, { "name": "text", "data": "Luminescence and EPR investigations of Mn activated calcium aluminate prepared " }, { "name": "italic", "data": [ { "name": "text", "data": "via" } ] }, { "name": "text", "data": " combustion method" }, { "name": "text", "data": " [J]. " }, { "name": "italic", "data": [ { "name": "text", "data": "Opt. Mater" } ] }, { "name": "text", "data": "." }, { "name": "text", "data": ", " }, { "name": "text", "data": "2007" }, { "name": "text", "data": ", " }, { "name": "text", "data": "30" }, { "name": "text", "data": "(" }, { "name": "text", "data": "3" }, { "name": "text", "data": "):" }, { "name": "text", "data": "468" }, { "name": "text", "data": "-" }, { "name": "text", "data": "472" }, { "name": "text", "data": "." } ], "title": "Luminescence and EPR investigations of Mn activated calcium aluminate prepared via combustion method" } ] }, { "id": "R31", "label": "[31]", "citation": [ { "lang": "en", "text": [ { "name": "text", "data": "ZHAO Y" }, { "name": "text", "data": ", " }, { "name": "text", "data": "SHI L" }, { "name": "text", "data": ", " }, { "name": "text", "data": "HAN Y J" }, { "name": "text", "data": ", " }, { "name": "text", "data": "et al" }, { "name": "text", "data": ". " }, { "name": "text", "data": "Luminescent properties of Zn" }, { "name": "sup", "data": [ { "name": "text", "data": "2+" } ] }, { "name": "text", "data": "-doped CaAl" }, { "name": "sub", "data": [ { "name": "text", "data": "12" } ] }, { "name": "text", "data": "O" }, { "name": "sub", "data": [ { "name": "text", "data": "19" } ] }, { "name": "text", "data": "∶Mn" }, { "name": "sup", "data": [ { "name": "text", "data": "4+" } ] }, { "name": "text", "data": " deep-red phosphor for indoor plant cultivation" }, { "name": "text", "data": " [J]. " }, { "name": "italic", "data": [ { "name": "text", "data": "Ceram. Int" } ] }, { "name": "text", "data": "." }, { "name": "text", "data": ", " }, { "name": "text", "data": "2019" }, { "name": "text", "data": ", " }, { "name": "text", "data": "45" }, { "name": "text", "data": "(" }, { "name": "text", "data": "7" }, { "name": "text", "data": "):" }, { "name": "text", "data": "8265" }, { "name": "text", "data": "-" }, { "name": "text", "data": "8270" }, { "name": "text", "data": "." } ], "title": "Luminescent properties of Zn2+-doped CaAl12O19∶Mn4+ deep-red phosphor for indoor plant cultivation" } ] } ] }, "response": [], "contributions": [], "acknowledgements": [], "conflict": [], "supportedby": [], "articlemeta": { "doi": "10.37188/CJL.20210395", "clc": [ [ { "name": "text", "data": "O482.31" } ] ], "dc": [ { "name": "text", "data": "A" } ], "publisherid": "1000-7032(2022)04-0536-09", "citeme": [], "fundinggroup": [ { "lang": "zh", "text": [ { "name": "text", "data": "国家自然科学基金（51762008）资助项目" } ] }, { "lang": "en", "text": [ { "name": "text", "data": "Supported by National Natural Science Foundation of China (51762008)" } ] } ], "history": { "received": "2021-12-16", "revised": "2021-12-29", "ppub": "2022-04-01", "opub": "2022-04-20" }, "copyright": { "data": [], "year": "2022" } }, "appendix": [], "type": "research-article", "ethics": [], "supplementary": [], "journalTitle": "发光学报", "issue": "4", "volume": "43", "originalSource": [] }

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