碘化钾对两步法制备钙钛矿薄膜及其电池性能的影响

高领伟; 翟光美; 任锦涛; 陈青; 员政宽; 梅伏洪; 王英民; 余春燕; 许并社

doi:10.37188/CJL.20210040

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碘化钾对两步法制备钙钛矿薄膜及其电池性能的影响

材料合成及性能 | 更新时间：2021-06-18

- 碘化钾对两步法制备钙钛矿薄膜及其电池性能的影响
- Effect of Potassium Iodide on Film Quality and Photovoltaic Performance of Perovskite Solar Cells Fabricated via Two-step Method
- 发光学报 2021年42卷第6期页码：838-848
- 作者机构：
  
  1.太原理工大学新材料界面科学与工程教育部重点实验室, 山西太原　 030024
  2.中国科学院可再生能源重点实验室, 广东广州　 510640
  3.中国电子科技集团公司第二研究所, 山西太原　 030024
  4.太原理工大学材料科学与工程学院, 山西太原　 030024
- 作者简介：
  
  [ "高领伟(1994-)，女，内蒙古赤峰人，硕士研究生，2017年于内蒙古师范大学获得学士学位，主要从事钙钛矿太阳能电池器件制备及性能的研究。E-mail: 851093681@qq.com" ]
  [ "翟光美(1981-)，男，山东肥城人，博士，讲师，硕士研究生导师，2012年于华中科技大学获得博士学位，主要从事光电材料与器件的研究。E-mail:zhaiguangmei@tyut.edu.cn" ]
  [ "梅伏洪(1983-)，男，安徽合肥人，博士，讲师，硕士研究生导师，2013年于北京大学获得博士学位，从事二维光电材料与器件的研究。Email: jackie_mei@163.com" ]
- 基金信息：
  
  山西省基础研究基金(201701D221079;201801D121101);中国科学院可再生能源重点实验室开放基金(Y807k31001);国家自然科学基金(61475110)
- DOI：10.37188/CJL.20210040
  中图分类号： O482.31
- 纸质出版日期：2021-06-01，
  
  收稿日期：2021-01-27，
  
  修回日期：2021-02-28，
扫描看全文
高领伟, 翟光美, 任锦涛, 等. 碘化钾对两步法制备钙钛矿薄膜及其电池性能的影响[J]. 发光学报, 2021,42(6):838-848.

Ling-wei GAO, Guang-mei ZHAI, Jin-tao REN, et al. Effect of Potassium Iodide on Film Quality and Photovoltaic Performance of Perovskite Solar Cells Fabricated via Two-step Method[J]. Chinese Journal of Luminescence, 2021,42(6):838-848.
高领伟, 翟光美, 任锦涛, 等. 碘化钾对两步法制备钙钛矿薄膜及其电池性能的影响[J]. 发光学报, 2021,42(6):838-848. DOI： 10.37188/CJL.20210040.

Ling-wei GAO, Guang-mei ZHAI, Jin-tao REN, et al. Effect of Potassium Iodide on Film Quality and Photovoltaic Performance of Perovskite Solar Cells Fabricated via Two-step Method[J]. Chinese Journal of Luminescence, 2021,42(6):838-848. DOI： 10.37188/CJL.20210040.

摘要

有机-无机杂化钙钛矿太阳电池因具有光电转化效率高和制备成本低廉等优点而备受关注。钙钛矿薄膜中的缺陷是限制钙钛矿电池性能进一步提升的重要因素，而缺陷调控又依赖于薄膜制备方法的发展和进步。两步法是制备钙钛矿薄膜和电池的主要方法之一，但目前对在两步法前驱液中引入添加剂如何影响钙钛矿薄膜结晶过程和缺陷密度的认识不足。本工作致力于利用光谱、X射线衍射、扫描电镜和电学测试等技术手段研究在两步法的铅盐溶液中引入碘化钾(KI)对卤化铅溶液、钙钛矿转化、缺陷密度和电池性能的影响。实验结果表明，适量KI的引入有利于高碘配位数铅碘配合物的生成，促进卤化铅向钙钛矿相的室温转化，并有效降低钙钛矿薄膜中的缺陷密度，钙钛矿电池的光电转化效率从无KI时的17.49%提高到19.17%。本工作的研究结果不仅有助于加深对两步法制备钙钛矿过程中结晶规律的理解，而且有助于进一步推动钙钛矿薄膜质量和器件性能的提升。

Abstract

Organic-inorganic hybrid perovskite solar cells have attracted much attention due to their high photoelectric conversion efficiency and low preparation cost. An important factor limiting the further performance improvement of perovskite solar cells is defects existed in perovskite active layers. The passivation of these defects depends on the development of perovskite preparation techniques. The two-step method is one of the most popular methods to prepare perovskite films and photovoltaic devices. In order to fabricate high-quality perovskite films and high-efficiency solar cells

the modified two-step method

via

introducing additives has been developed. However

effects of additives introduced into the lead halide precursor on the crystallization process and defect density of perovskite films fabricated

via

the two-step method are not yet fully understood. In this work

the impacts of potassium iodide(KI) on colloidal properties of the lead halide precursor

perovskite transformation

film quality and cell performance were investigated by means of spectroscopy

X-ray diffraction

scanning electron microscopy and various electrical measurements. Our results show that the introduction of appropriate amount of KI facilitates the formation of iodide-rich iodoplumbates

which is beneficial to accelerating perovskite transformation from lead halide and improving perovskite film quality. The photoelectric conversion efficiency of the solar cell incorporating appropriate KI has been increased to 19.17% from 17.49% for the control device. The results of this work not only help to deepen the understanding of the crystallization of perovskite films in the two-step preparation process

but also help to further improve perovskite film quality and device performance.

关键词

钙钛矿太阳电池碘化钾两步法缺陷钝化碘铅酸盐

Keywords

perovskite solar cellspotassium iodide"two-step" depositiondefect passivationiodoplumbates

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