基于硅氧烷修饰的苝二酰亚胺氟离子荧光传感器

张丹; 刘婕; 石栋; 张新意; 高保祥; 冯亚凯; 任相魁

doi:10.37188/CJL.20210068

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基于硅氧烷修饰的苝二酰亚胺氟离子荧光传感器

器件制备及器件物理 | 更新时间：2021-06-18

- 基于硅氧烷修饰的苝二酰亚胺氟离子荧光传感器
  增强出版
- Fluorescent Sensor for Fluoride Ions Based on Perylene Diimide Tethered with Siloxane Moieties
- Chinese Journal of Luminescence 2021年42卷第6期页码：855-862
- 作者机构：
  
  1.天津大学化工学院化学工程联合国家重点实验室, 天津　 300350
  2.日本北海道大学全球软物质研究中心, 日本　札幌　 001-0021
  3.河北大学化学与环境科学学院, 河北保定　 071002
- 作者简介：
  
  [ "张丹(1995-)，女，山西兴县人，硕士研究生，2018年于天津科技大学获得学士学位，主要从事苝二酰亚胺有机小分子的合成与性质的研究。Email: zhangdannnn@tju.edu.cn" ]
  [ "任相魁(1980-)，男，河北邢台人，博士，副教授，2010年于南开大学获得博士学位，主要从事小分子及高分子材料的聚集态结构和性质的研究。Email: renxiangkui@tju.edu.cn" ]
- 基金信息：
  
  National Natural Science Foundation of China(21875157;21304069);Open Foundation of State Key Laboratory of Chemical Engineering(SKL-ChE-20B04);National Key R&D Program of China(2016YFC1100300)
- DOI：10.37188/CJL.20210068
  中图分类号： TP212.2
- 纸质出版日期：2021-06-01，
  
  收稿日期：2021-02-19，
  
  修回日期：2021-03-04，
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张丹, 刘婕, 石栋, 等. 基于硅氧烷修饰的苝二酰亚胺氟离子荧光传感器[J]. Chinese Journal of Luminescence, 2021,42(6):855-862.

Dan ZHANG, Jie LIU, Dong SHI, et al. Fluorescent Sensor for Fluoride Ions Based on Perylene Diimide Tethered with Siloxane Moieties[J]. 发光学报, 2021,42(6):855-862.
张丹, 刘婕, 石栋, 等. 基于硅氧烷修饰的苝二酰亚胺氟离子荧光传感器[J]. Chinese Journal of Luminescence, 2021,42(6):855-862. DOI： 10.37188/CJL.20210068.

Dan ZHANG, Jie LIU, Dong SHI, et al. Fluorescent Sensor for Fluoride Ions Based on Perylene Diimide Tethered with Siloxane Moieties[J]. 发光学报, 2021,42(6):855-862. DOI： 10.37188/CJL.20210068.

摘要

通过简单的一步反应合成了一种新型含硅氧烷基团的苝二酰亚胺(PDI-TES)荧光传感器. 结合小角X射线衍射、紫外-可见吸收光谱、荧光光谱和动态光散射等实验方法，阐明了PDI-TES的晶体结构、自组装行为和检测性能. 实验结果表明，PDI-TES具有良好的热稳定性和有序的晶体结构. 此外，由于Si—O键的断裂，PDI-TES对氟离子具有较高的选择性和灵敏度，检出限低至1.58×10

-6

mol/L. 这些优良的检测性能和简单、低成本的合成方法，有望使PDI-TES成为一种实用的氟离子检测荧光传感器.

Abstract

A novel perylene diimide(PDI) derivative bearing siloxane moieties(PDI-TES) was synthesized as fluorescent sensor by simple one-step reaction with high yield. The crystal structure

self-assembly behavior and detection property of the compound were then elucidated

via

a combination of different experimental techniques such as small-angle X-Ray scattering

UV-Vis absorption spectra

photoluminescence spectra and dynamic light scattering experiments. The experimental results reveal that PDI-TES has good thermal stability and ordered crystal structure. Moreover

due to the cleavage of Si—O bonds

PDI-TES exhibits high selectivity and sensitivity to F

with a detection limit as low as 1.58×10

-6

mol/L. These excellent detection performances

in combination with the simple and low-cost synthesis method

make PDI-TES a practical fluorescent sensor for detection of F

关键词

苝二酰亚胺荧光传感器硅氧烷氟离子

Keywords

perylene diimidefluorescent sensorsiloxanefluoride ions

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