分子堆积——影响固态有机小分子力响应发光行为的关键因素

李爱森; 王金凤; 李振

doi:10.37188/CJL.20200354

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分子堆积——影响固态有机小分子力响应发光行为的关键因素

特邀报告 | 更新时间：2021-03-19

- 分子堆积——影响固态有机小分子力响应发光行为的关键因素
- Molecular Stacking—Key Factor in Mechanical-responsive Luminescent Behaviors of Solid Organic Small Molecules
- 发光学报 2021年42卷第3期页码：283-295
- 作者机构：
  
  1.天津大学-新加坡国立大学福州联合学院天津大学福州国际校区，福建福州　 350207;
  2.天津大学分子聚集态科学研究院，天津　 300072；
  3.武汉大学化学与分子科学学院，湖北武汉　 430072
- 作者简介：
  
  [ "李爱森(1993－)，女，河北辛集人，博士，天津大学在站博士后，2020年于吉林大学获得博士学位，主要从事力刺激响应材料的相关研究。E-mail: liaisen@tju.edu.cn" ]
  [ "李振(1976－)，男，湖北孝感人，博士，教授，2002年于武汉大学获得博士学位，主要从事二阶非线性光学、有机室温磷光、力致发光、聚集诱导发光、传感器、太阳能电池、磁性纳米材料等的研究。E-mail: lizhentju@tju.edu.cn" ]
- 基金信息：
  
  Start-up Funds for Tianjin University
- DOI：10.37188/CJL.20200354
  中图分类号： O482.31
- 纸质出版日期：2021-03-01，
  
  收稿日期：2020-11-22，
  
  修回日期：2021-01-24，
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李爱森, 王金凤, 李振. 分子堆积——影响固态有机小分子力响应发光行为的关键因素[J]. 发光学报, 2021,42(3):283-295.

Ai-sen LI, Jin-feng WANG, Zhen LI. Molecular Stacking—Key Factor in Mechanical-responsive Luminescent Behaviors of Solid Organic Small Molecules[J]. Chinese Journal of Luminescence, 2021,42(3):283-295.
李爱森, 王金凤, 李振. 分子堆积——影响固态有机小分子力响应发光行为的关键因素[J]. 发光学报, 2021,42(3):283-295. DOI： 10.37188/CJL.20200354.

Ai-sen LI, Jin-feng WANG, Zhen LI. Molecular Stacking—Key Factor in Mechanical-responsive Luminescent Behaviors of Solid Organic Small Molecules[J]. Chinese Journal of Luminescence, 2021,42(3):283-295. DOI： 10.37188/CJL.20200354.

摘要

力刺激响应型有机发光小分子因其独特的发光性质在信息加密、光学存储、压力传感器等领域具有潜在应用，引起了广泛关注。其相关发光特性并不只来源于单分子结构，更与分子聚集态不同的堆积模式密切相关，因此，如何调控分子堆积模式是获得功能化发光材料的关键。本文主要从力致变色和力致发光材料体系出发，概述了几种调控分子间相互作用的策略，突出强调了分子堆积与发光性能之间的关系，为研究具有新颖发光特性的发光材料提供了研究思路，希望促进有机发光材料的进一步发展。

Abstract

Mechanical-responsive organic luminogens have potential applications in the fields of information encryption

optical storage

pressure sensors

etc

. due to their unique luminescent properties

and have attracted widespread attention. Their luminescent properties are not only derived from the single-molecule structure

but also closely related to the different stacking modes of molecular aggregates. Therefore

how to control the molecular stacking mode becomes a key issue for obtaining functional luminescent materials. This review mainly focuses on the material system of mechanochromism and mechanoluminescence

outlines several strategies to regulate the intermolecular interactions

and highlights the relationship between molecular stacking and luminescent performance

which paves a new way to design novel luminescence materials and further promotes the development of organic luminescent materials.

关键词

外力力致变色力致发光分子堆积分子间相互作用

Keywords

external forcemechanochromismmechanoluminescencemolecular stackingintermolecular interactions

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