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吉林大学 超硬材料国家重点实验室, 吉林 长春 130012
[ "邹勃(1974-), 男, 吉林长春人, 博士, 教授, 博士研究生导师。2002年于吉林大学高分子化学与物理专业获得理学博士学位。2001-2005年在德国明斯特大学和多特蒙德大学从事联合培养博士和博士后研究。2017年获得国家杰出青年科学基金。长期从事高压化学研究, 利用高压这个独特的热力学参量, 解决了部分常压下科学中有争议的问题; 通过调控化学反应动力学势垒和热力学相变势垒, 发现了系列高压相截获的方法, 并成功应用在高能密度材料和卤素钙钛矿材料上; 成功实现了压致变色材料光学特性的大范围精确调控, 提出了压力诱导发光(PIE)的概念; 发现了新型超大负压缩率材料, 提出分子层滑移和\"酒架状\"非共价键结构等负压缩新机制, 为制备具有特定功能的化学材料提供了新思路和新方法, 在压力传感、压力开关、防伪和信息存储等领域具有潜在应用前景。已在Nat.Commun., J.Am.Chem.Soc., Angew.Chem.Int.Ed., Adv.Mater.等刊物发表SCI论文300多篇。E-mail: zoubo@jlu.edu.cn" ]
纸质出版日期:2020-5,
收稿日期:2020-4-10,
录用日期:2020-4-20
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邹勃. 压力诱导发光未来可期[J]. 发光学报, 2020,41(5):507-509.
Bo ZOU. Pressure-induced Emission, Future Prospects[J]. Chinese Journal of Luminescence, 2020,41(5):507-509.
邹勃. 压力诱导发光未来可期[J]. 发光学报, 2020,41(5):507-509. DOI: 10.3788/fgxb20204105.0507.
Bo ZOU. Pressure-induced Emission, Future Prospects[J]. Chinese Journal of Luminescence, 2020,41(5):507-509. DOI: 10.3788/fgxb20204105.0507.
科技创新的根源是基于基础科学研究的提升,而"从0到1"的突破是需要长期的积累和灵感的。本文讲述了发现压力诱导发光这一新现象的思想和材料设计。
The root of technological innovation is based on the improvement of basic scientific research
and the /peakthrough from "0 to 1" requires long-term accumulation and inspiration. The paper describes the idea and material design for discovering the new phenomenon of pressure-induced emission.
压力诱导发光卤素钙钛矿材料自陷态激子
pressure-induced emissionhalide perovskite materialsself-trapped exciton
MA Z, LI F, ZHAO D, et al.. Whether or not emission of Cs4PbBr6 nanocrystals:high-pressure experimental evidence[J].CCS Chem., 2020, 2(2):71-80.
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DREGER Z A, LANG J M, DRICHAMER H G. High pressure effect on the twisted intramolecular charge transfer fluorescence and absorption of p-N, N-dimethylaminobenzylidenemalononitrile(DMABMN) in polymeric matrices[J].Chem. Phys., 1992, 166:193-206.
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LI Q, LI S, WANG K, et al.. Structural tuning and piezoluminescence phenomenon in trithiocyanuric acid[J].J. Phys. Chem. C, 2017, 121(3):1870-1875.
XIAO G, CAO Y, QI G, et al.. Pressure effects on structure and optical properties in cesium lead bromide perovskite nanocrystals[J].J. Am. Chem. Soc., 139(2017):10087-10094.
ZHANG L, LIU C, WANG L, et al.. Pressure-induced emission enhancement, band-gap narrowing, and metallization of halide perovskite Cs3Bi2I9[J].Angew. Chem. Int. Ed., 2018, 57(35):11213-11217.
MA Z, LIU Z, LU S, et al.. Pressure-induced emission of cesium lead halide perovskite nanocrystals[J].Nat. Commun., 2018, 9:4506.
SHI Y, MA Z, ZHAO D, et al.. Pressure-induced emission(PIE) of one-dimensional organic tin bromide perovskites[J].J. Am. Chem. Soc., 2019, 141(16):6504-6508.
FANG Y, ZHANG L, WU L, et al.. Pressure-induced emission(PIE) and phase transition of a two dimensional halide double perovskite (BA)4AgBiBr8 (BA=CH3(CH2)3NH3+)[J].Angew. Chem. Int. Ed., 2019, 58(43):15249-15253
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