Sn2+-Mn2+共掺杂Gd2O3-Al2O3-SiO2玻璃光致发光性能与能量传递

华哲浩; 唐高; 魏钦华; 秦来顺; 蔡培庆; 林慧兴; 周真真; 钱森; 王志刚

doi:10.37188/CJL.20220042

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Sn²⁺-Mn²⁺共掺杂Gd₂O₃-Al₂O₃-SiO₂玻璃光致发光性能与能量传递

材料合成及性能 | 更新时间：2022-05-23

- Sn²⁺-Mn²⁺共掺杂Gd₂O₃-Al₂O₃-SiO₂玻璃光致发光性能与能量传递
  增强出版
- Photoluminescence Properties and Energy Transfer of Sn²⁺-Mn²⁺ Co-doped Gd₂O₃-Al₂O₃-SiO₂ Glass
- 发光学报 2022年43卷第5期页码：691-701
- 作者机构：
  
  1.中国计量大学　材料与化学学院，浙江　杭州　310018
  2.中国计量大学　光学与电子科技学院，浙江　杭州　310018
  3.中国科学院上海硅酸盐研究所　无机功能材料与器件重点实验室，上海　201899
  4.中国科学院高能物理研究所　核探测与核电子学国家重点实验室，北京　100049
- 作者简介：
  
  [ "华哲浩(1996-)，男，浙江舟山人，硕士研究生，2019年于中国计量大学获得学士学位，主要从事闪烁玻璃应用的研究。E-mail: huazh@ihep.ac.cn" ]
  [ "唐高(1981-)，男，湖南株洲人，博士，副研究员，2009年于中国科学院上海硅酸盐研究所获得博士学位，主要从事闪烁材料的研究。E-mail: gtang@cjlu.edu.cn" ]
- 基金信息：
  
  国家自然科学基金(61505193;11904345;11975220;51972291);浙江省科技厅2022年度“尖兵”研发攻关计划(2022C01046);浙江省自然科学基金(LGG22E020001);中国科学院无机功能材料与器件重点实验室开放项目(KLIFMD201808)
- DOI：10.37188/CJL.20220042
  中图分类号： TQ171
- 纸质出版日期：2022-05，
  
  收稿日期：2022-02-06，
  
  修回日期：2022-02-17，
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华哲浩, 唐高, 魏钦华, 等. Sn²⁺-Mn²⁺共掺杂Gd₂O₃-Al₂O₃-SiO₂玻璃光致发光性能与能量传递[J]. 发光学报, 2022,43(5):691-701.

Zhe-hao HUA, Gao TANG, Qin-hua WEI, et al. Photoluminescence Properties and Energy Transfer of Sn²⁺-Mn²⁺ Co-doped Gd₂O₃-Al₂O₃-SiO₂ Glass[J]. Chinese Journal of Luminescence, 2022,43(5):691-701.
华哲浩, 唐高, 魏钦华, 等. Sn²⁺-Mn²⁺共掺杂Gd₂O₃-Al₂O₃-SiO₂玻璃光致发光性能与能量传递[J]. 发光学报, 2022,43(5):691-701. DOI： 10.37188/CJL.20220042.

Zhe-hao HUA, Gao TANG, Qin-hua WEI, et al. Photoluminescence Properties and Energy Transfer of Sn²⁺-Mn²⁺ Co-doped Gd₂O₃-Al₂O₃-SiO₂ Glass[J]. Chinese Journal of Luminescence, 2022,43(5):691-701. DOI： 10.37188/CJL.20220042.

摘要

通过传统的高温熔融淬火技术制备了Sn

-Mn

共掺杂的Gd

-Al

-SiO

（GAS∶0.5Sn

，

）玻璃。研究了玻璃的光致发光特性和Sn

-Mn

能量传递过程。在365 nm激发下，随着Mn

浓度的增加（1.0%，1.5%，2.0%，2.5%，3.0%，3.5%，4.0%），玻璃中Sn

的发光强度逐渐降低，而Mn

的发光强度逐渐增大。Sn

的衰减时间随着Mn

含量的增加而减小，玻璃中产生了Sn

到Mn

离子的能量传递。GAS∶0.5Sn

，

玻璃的光致发光量子产率（PLQY）随着Mn

含量的增加而减小，其最大值为25.48%。玻璃中Mn

离子浓度达到4.0%时，其发光属于准白光发射，色坐标为（0.323，0.273）。另外，本文还研究了Sn

-Mn

共掺杂玻璃的发光热猝灭现象，Sn

发光中心电子跃迁所需克服的热激活能约为0.23 eV。

Abstract

The Sn

-Mn

co-doped Gd

-Al

-SiO

(GAS∶0.5Sn

) glass was prepared by traditional high temperature melt-quenching technology. The photoluminescence properties of the glass and the energy transfer process of Sn

-Mn

were studied. Under 365 nm excitation wavelength

with the increase of Mn

content(1.0%

1.5%

2.0%

2.5%

3.0%

3.5%

4.0%)

the emission intensity of the Sn

center gradually decreases

and the emission intensity of the Mn

center gradually increases. Moreover

the decay time of the Sn

center decreases with the increase of Mn

content

indicating that energy transfer from Sn

to Mn

ions occurs in the glass. The photoluminescence quantum yield(PLQY) decreases with the increase of Mn

content

the maximum of PLQY of GAS∶0.5Sn

glass is 25.48%. When the Mn

ions concentration reaches 4.0%

the chromatic coordinate of the glass is (0.323

0.273)

which is close to the standard white light emission. In addition

the thermal quenching behavior of Sn

-Mn

co-doped glass was also studied. The thermal activation energy required to overcome the electronic transition of the Sn

emission center is approximately 0.23 eV.

关键词

铝硅酸盐玻璃Sn2+-Mn2+共掺能量传递白光发射

Keywords

aluminum-silicate glassSn2+-Mn2+ co-dopedenergy transferwhite light emission

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