ZnAl2O4/CaAl12O19∶Mn4+荧光粉制备与发光性能

林贵; 罗琦; 陈茜; 刘燕婷; 蒙丽丽

doi:10.37188/CJL.20210395

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ZnAl₂O₄/CaAl₁₂O₁₉∶Mn⁴⁺荧光粉制备与发光性能

材料合成及性能 | 更新时间：2022-04-20

- ZnAl₂O₄/CaAl₁₂O₁₉∶Mn⁴⁺荧光粉制备与发光性能
  增强出版
- Preparation and Luminescent Properties of ZnAl₂O₄/CaAl₁₂O₁₉∶Mn⁴⁺ Phosphors
- 发光学报 2022年43卷第4期页码：536-544
- 作者机构：
  
  南宁师范大学　化学与材料学院，广西天然高分子化学与物理重点实验室，广西　南宁　530001
- 作者简介：
  
  [ "林贵(1996- )，男，广西玉林人，硕士研究生，2019年于南宁师范大学获得学士学位，主要从事发光材料的研究。E-mail: lingui60@163.com" ]
  [ "蒙丽丽(1972- )，女，广西上林人，博士，教授，2015年于广西大学获得博士学位，主要从事发光材料的研究。E-mail: mll_0001@163.com" ]
- 基金信息：
  
  国家自然科学基金(51762008)
- DOI：10.37188/CJL.20210395
  中图分类号： O482.31
- 纸质出版日期：2022-04-01，
  
  收稿日期：2021-12-16，
  
  修回日期：2021-12-29，
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林贵, 罗琦, 陈茜, 等. ZnAl₂O₄/CaAl₁₂O₁₉∶Mn⁴⁺荧光粉制备与发光性能[J]. 发光学报, 2022,43(4):536-544.

Gui LIN, Qi LUO, Qian CHEN, et al. Preparation and Luminescent Properties of ZnAl₂O₄/CaAl₁₂O₁₉∶Mn⁴⁺ Phosphors[J]. Chinese Journal of Luminescence, 2022,43(4):536-544.
林贵, 罗琦, 陈茜, 等. ZnAl₂O₄/CaAl₁₂O₁₉∶Mn⁴⁺荧光粉制备与发光性能[J]. 发光学报, 2022,43(4):536-544. DOI： 10.37188/CJL.20210395.

Gui LIN, Qi LUO, Qian CHEN, et al. Preparation and Luminescent Properties of ZnAl₂O₄/CaAl₁₂O₁₉∶Mn⁴⁺ Phosphors[J]. Chinese Journal of Luminescence, 2022,43(4):536-544. DOI： 10.37188/CJL.20210395.

摘要

采用传统高温固相法制备了系列

ZnAl

/CaAl

∶Mn

(

ZAO/CAO∶Mn

)混合相红光荧光粉，研究了ZnAl

掺杂对CaAl

∶Mn

形貌和发光性能的影响。X射线衍射(XRD)表征结果表明，在1 723 K下煅烧6 h成功合成了

ZAO/CAO∶Mn

混合相荧光粉，随着ZnAl

掺杂量的增加依然保持两相共存。荧光光谱分析表明，当

=1时，ZAO/CAO∶Mn

具有最大的荧光强度，其值比CaAl

∶Mn

的荧光强度提高了203%。相对于CaAl

∶Mn

荧光粉，ZAO/CAO∶Mn

荧光粉具有更长的荧光寿命，其内量子效率提高了211%。在298~418 K温度范围内，ZAO/CAO∶Mn

荧光粉的绝对灵敏度(

)为4.32×10

-3

-1

；在418 K时，最大相对灵敏度(

)为3.65×10

-3

-1

。该荧光粉在光学测温方面具有潜在应用价值。

Abstract

A series of

ZnAl

/CaAl

∶Mn

(

ZAO/CAO∶Mn

) mixed-phase red-emit phosphors were prepared by traditional high-temperature solid-state method. The influence of ZnAl

doping on the morphology and luminescence properties of CaAl

∶Mn

was investigated. The X-ray diffraction(XRD) characterization results show that the mixed-phase phosphors were successfully synthesized after sintered at 1 723 K for 6 h

and the two-phase coexistence is maintained with the increase of ZnAl

doping amount. Fluorescence spectrum shows that ZAO/CAO∶Mn

has the largest fluorescence intensity when

which is 203% higher than that of CaAl

∶Mn

. Compared with CaAl

∶Mn

phosphor

the lifetime of ZAO/CAO∶Mn

is improved and internal quantum yield of ZAO/CAO∶Mn

is 211% higher than that of CaAl

∶Mn

. An absolute sensitivity(

) of 4.32×10

-3

-1

of the ZAO/CAO∶Mn

phosphor was obtained in the range of 298-418 K and the maximum relative sensitivity(

) was 3.65×10

-3

-1

at 418 K

implying that it has potential application value in optical thermometry.

关键词

荧光粉光学测温发光性能Mn4+ZnAl2O4/CaAl12O19

Keywords

phosphoroptical thermometryluminescent propertiesMn4+ZnAl2O4/CaAl12O19

references

ZHENG Z G, ZHANG J F, LIU X Y, et al. Luminescence and self-referenced optical temperature sensing performance in Ca2YZr2Al3O12∶Bi3+,Eu3+ phosphors [J]. Ceram. Int., 2020, 46(5):6154-6159.

SONG Y Y, GUO N, LI J, et al. Photoluminescence and temperature sensing of lanthanide Eu3+ and transition metal Mn4+ dual-doped antimoniate phosphor through site-beneficial occupation [J]. Ceram. Int., 2020, 46(14):22164-22170.

王艺蒙, 舒浩文, 韩秀友. 高精度硅基集成光学温度传感器研究 [J]. 中国光学, 2021, 14(6):1355-1361.

WANG Y M, SHU H W, HAN X Y. High-precision silicon-based integrated optical temperature sensor [J]. Chin. Opt., 2021, 14(6):1355-1361. (in Chinese)

BRIK M G, SRIVASTAVA A M, AVRAM N M. Comparative analysis of crystal field effects and optical spectroscopy of six-coordinated Mn4+ ion in the Y2Ti2O7 and Y2Sn2O7 pyrochlores [J]. Opt. Mater., 2011, 33(11):1671-1676.

WEI Y, YANG H, GAO Z Y, et al. Strategies for designing antithermal-quenching red phosphors [J]. Adv. Sci., 2020, 7(8):1903060-1-9.

BAO G C, WONG K L, JIN D Y, et al. A stoichiometric terbium-europium dyad molecular thermometer:energy transfer properties [J]. Light:Sci. Appl., 2018, 7(1):96-1-10.

AMARASINGHE D K, RABUFFETTI F A. Bandshift luminescence thermometry using Mn4+∶Na4Mg(WO4)3 phosphors [J]. Chem. Mater., 2019, 31(24):10197-10204.

KATUMO N, GAO G J, LAUFER F, et al. Smartphone-based luminescent thermometry via temperature-sensitive delayed fluorescence from Gd2O2S∶Eu3+ [J]. Adv. Opt. Mater., 2020, 8(19):2000507-1-7.

LUO H Y, LI X Y, WANG X, et al. Highly thermal-sensitive robust LaTiSbO6∶Mn4+ with a single-band emission and its topological architecture for single/dual-mode optical thermometry [J]. Chem. Eng. J., 2020, 384:123272.

XU M, ZOU X M, SU Q Q, et al. Ratiometric nanothermometer in vivo based on triplet sensitized upconversion [J]. Nat. Commun., 2018, 9(1):2698-1-7.

MCLAURIN E J, BRADSHAW L R, GAMELIN D R. Dual-emitting nanoscale temperature sensors [J]. Chem. Mater., 2013, 25(8):1283-1292.

NIKOLI Ć M G, ANTI Ć Ž, ĆULUBRK S, et al. Temperature sensing with Eu3+ doped TiO2 nanoparticles [J]. Sens. Actuators B:Chem., 2014, 201:46-50.

SHI R, LIN L T, DORENBOS P, et al. Development of a potential optical thermometric material through photoluminescence of Pr3+ in La2MgTiO6 [J]. J. Mater. Chem. C, 2017, 5(41):10737-10745.

MARCINIAK L, PILCH A, ARABASZ S, et al. Heterogeneously Nd3+ doped single nanoparticles for NIR-induced heat conversion,luminescence,and thermometry [J]. Nanoscale, 2017, 9(24):8288-8297.

李晓晓, 李蕴乾, 汪欣, 等. 高灵敏度下转换光学测温材料∶NaGd(WO4)2∶Yb3+/Er3+ [J]. 中国光学, 2019, 12(3):596-605.

LI X X, LI Y Q, WANG X, et al. Highly sensitive down-conversion optical temperature-measurement material∶NaGd(WO4)2∶Yb3+/Er3+ [J]. Chin. Opt., 2019, 12(3):596-605. (in Chinese)

CAI P Q, QIN L, CHEN C L, et al. Optical thermometry based on vibration sidebands in Y2MgTiO6∶Mn4+ double perovskite [J]. Inorg. Chem., 2018, 57(6):3073-3081.

SEKULI ĆM, -DOR-DEVI Ć V, RISTI Ć Z, et al. Highly sensitive dual self-referencing temperature readout from the Mn4+/ Ho3+ binary luminescence thermometry probe [J]. Adv. Opt. Mater., 2018, 6(17):1800552-1-7.

TAKEDA Y, KATO H, KOBAYASHI M, et al. Photoluminescence properties of double perovskite tantalates activated with Mn4+,AE2LaTaO6∶Mn4+ (AE=Ca,Sr,and Ba) [J]. J. Phys. Chem. C, 2017, 121(34):18837-18844.

YANG S H, LEE Y C, HUNG Y C. Thermometry of red nanoflaked SrAl12O19∶Mn4+ synthesized with boric acid flux [J]. Ceram. Int., 2018, 44(10):11665-11673.

CAI P Q, QIN L, CHEN C L, et al. Luminescence,energy transfer and optical thermometry of a novel narrow red emitting phosphor:Cs2WO2F4∶Mn4+ [J]. Dalton Trans., 2017, 46(41):14331-14340.

WU Y B, ZHUANG Y X, XIE R J, et al. Novel Mn4+ doped red phosphors composed of MgAl2O4 and CaAl12O19 phases for light-emitting diodes [J]. Dalton Trans., 2020, 49(11):3606-3614.

COSTA G, RIBEIRO M J, HAJJAJI W, et al. Ni-doped hibonite (CaAl12O19):a new turquoise blue ceramic pigment [J]. J. Eur. Ceram. Soc., 2009, 29(13):2671-2678.

王细凤, 夏威, 肖志国. 一种新型红色荧光粉CaAl12O19∶Eu,Mn的制备及发光性能 [J]. 发光学报, 2009, 30(3):405-408.

WANG X F, XIA W, XIAO Z G. Synthesis and luminescent properties of a novel red phosphor CaAl12O19∶Eu,Mn [J]. Chin. J. Lumin., 2009, 30(3):405-408. (in Chinese)

SINGH V, CHAKRADHAR R P S, RAO J L, et al. Characterization,EPR and luminescence studies of ZnAl2O4∶Mn phosphors [J]. J. Lumin., 2008, 128(3):394-402.

黄尚攀, 魏智强, 武晓娟, 等. Cu2+掺杂ZnAl2O4纳米颗粒的光学性能 [J]. 发光学报, 2019, 40(11):1386-1393.

HUANG S P, WEI Z Q, WU X J, et al. Optical properties of Cu2+ doped ZnAl2O4 nanoparticles [J]. Chin. J. Lumin., 2019, 40(11):1386-1393. (in Chinese)

ZHU Y J, QIU Z X, AI B Y, et al. Significant improved quantum yields of CaAl12O19∶Mn4+ red phosphor by co-doping Bi3+ and B3+ ions and dual applications for plant cultivations [J]. J. Lumin., 2018, 201:314-320.

MURATA T, TANOUE T, IWASAKI M, et al. Fluorescence properties of Mn4+ in CaAl12O19 compounds as red-emitting phosphor for white LED [J]. J. Lumin., 2005, 114(3-4):207-212.

CHEN Y B, CHEN J Q, LIANG J H, et al. Localized charge accumulation driven by Li+ incorporation for efficient LED phosphors with tunable photoluminescence [J]. Chem. Mater., 2020, 32(22):9551-9559.

LU J, PAN Y X, WANG J G, et al. Reduction of Mn4+ to Mn2+ in CaAl12O19 by co-doping charge compensators to obtain tunable photoluminescence [J]. RSC Adv., 2013, 3(14):4510-4513.

SINGH V, NATARAJAN V, ZHU J J. Luminescence and EPR investigations of Mn activated calcium aluminate prepared via combustion method [J]. Opt. Mater., 2007, 30(3):468-472.

ZHAO Y, SHI L, HAN Y J, et al. Luminescent properties of Zn2+-doped CaAl12O19∶Mn4+ deep-red phosphor for indoor plant cultivation [J]. Ceram. Int., 2019, 45(7):8265-8270.

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