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Lu2O3∶Er3+/Yb3+荧光材料的上转换发光及其温度传感特性
增强出版Upconversion Luminescence and Temperature Sensing Characteristics of Lu2O3∶Er3+/Yb3+ Phosphor
- 发光学报 2022年43卷第2期 页码：192-200
- 作者机构：
1.浙江大学 物理系，浙江 杭州 310027
2.中国航发四川燃气涡轮研究院，四川 成都 610500
- 作者简介：
[ "周慧丽(1996-)，女，浙江金华人，博士研究生，2017年于浙江外国语学院获得学士学位，主要从事稀土离子掺杂荧光材料温度传感特性的研究。E-mail: 12136077@zju.edu.cn" ]
[ "叶林华(1965-)，男，浙江宁海人，博士，副教授，2006年于浙江大学获得博士学位，主要从事高温氧化物单晶光纤材料制备及其应用的研究。E-mail: lhye@zju.edu.cn" ]
- 基金信息：国家自然科学基金(11674284);先进航空动力创新工作站（依托中国航空发动机研究院设立）(HKCX2019-01-017)
DOI：10.37188/CJL.20210363
中图分类号： O482.31纸质出版日期：2022-02，
收稿日期：2021-11-16，
修回日期：2021-11-30，
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周慧丽, 吴锋, 张志宏, 等. Lu2O3∶Er3+/Yb3+荧光材料的上转换发光及其温度传感特性[J]. 发光学报, 2022,43(2):192-200.
Hui-li ZHOU, Feng WU, Zhi-hong ZHANG, et al. Upconversion Luminescence and Temperature Sensing Characteristics of Lu2O3∶Er3+/Yb3+ Phosphor[J]. Chinese Journal of Luminescence, 2022,43(2):192-200.
周慧丽, 吴锋, 张志宏, 等. Lu2O3∶Er3+/Yb3+荧光材料的上转换发光及其温度传感特性[J]. 发光学报, 2022,43(2):192-200. DOI： 10.37188/CJL.20210363.
Hui-li ZHOU, Feng WU, Zhi-hong ZHANG, et al. Upconversion Luminescence and Temperature Sensing Characteristics of Lu2O3∶Er3+/Yb3+ Phosphor[J]. Chinese Journal of Luminescence, 2022,43(2):192-200. DOI： 10.37188/CJL.20210363.
摘要
采用CO
2
激光区熔法制备了Lu
2
O
3
∶0.5%Er
3+
/
x
%Yb
3+
(
x
=1
3
5)上转换荧光材料。X射线衍射结果表明，所制备的Lu
2
O
3
∶Er
3+
/Yb
3+
荧光材料具有纯Lu
2
O
3
晶相。在980 nm激光激发下，样品发出明亮的上转换荧光。光谱测试结果表明，样品上转换荧光强度和荧光中绿光与红光比例随Yb
3+
离子浓度改变，当Er
3+
和Yb
3+
离子浓度分别为0.5%和3%时，样品上转换荧光强度最强。通过荧光强度比(FIR)技术研究了样品Lu
2
O
3
∶0.5%Er
3+
/3%Yb
3+
在298~873 K温度范围内上转换荧光温度传感特性，在532.8 K时最大绝对灵敏度为0.006 0 K
-1
，在298 K时最大相对灵敏度为0.009 0 K
-1
。结果表明，Lu
2
O
3
∶Er
3+
/Yb
3+
荧光材料非常适合用于宽温度范围荧光温度传感。
Abstract
Lu
2
O
3
∶0.5%Er
3+
/
x
%Yb
3+
(
x
=1
3
5) phosphors were prepared by CO
2
laser zone melting method. X-ray diffraction results showed that all the prepared Lu
2
O
3
∶Er
3+
/Yb
3+
phosphors have a pure Lu
2
O
3
crystal phase. Under the excitation of a 980 nm laser diode
the samples emit bright up-conversion luminescence(UCL). The luminescence intensity and the ratio of green band to red band in luminescence spectra change with Yb
3+
concentration. Besides
the UCL intensity reaches its maximum value when the doping concentrations of Er
3+
and Yb
3+
ions are 0.5% and 3%
respectively. The temperature sensing characteristics of Lu
2
O
3
∶0.5%Er
3+
/3%Yb
3+
were investigated using fluorescence intensity ratio(FIR) technique from 298 K to 873 K. The maximum absolute sensitivity is 0.006 0 K
-1
at 532.8 K
and the maximum relative sensitivity is 0.009 0 K
-1
at 298 K. The above results indicate that the Lu
2
O
3
∶Er
3+
/Yb
3+
phosphor is very suitable for wide-range temperature sensing.
关键词
Lu2O3∶Er3+/Yb3+；上转换发光荧光强度比(FIR)荧光温度传感CO2激光区熔法
Keywords
Lu2O3∶Er3+/Yb3+upconversion luminescencefluorescence intensity ratio(FIR)fluorescence temperature sensingCO2 laser zone melting method
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