SnO<sub>2</sub>∶Zn纳米晶光阳极对染料敏化太阳能电池光电性能的影响

于翠玲; 朱瑞滨; 林珊; 武凤; 乌大坤; 赵海发; 常亮

doi:10.37188/CJL.20210285

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SnO₂∶Zn纳米晶光阳极对染料敏化太阳能电池光电性能的影响

器件制备及器件物理 | 更新时间：2021-12-17

- SnO₂∶Zn纳米晶光阳极对染料敏化太阳能电池光电性能的影响
  增强出版
- Influence of Zn Doped SnO₂ Nanocrystals as Photoanode Materials on Photoelectric Performance of Dye-sensitized Solar Cells
- 发光学报 2021年42卷第12期页码：1936-1943
- 作者机构：
  
  1.哈尔滨工业大学　物理学院，黑龙江　哈尔滨　150001
  2.长春希达电子科技有限公司，吉林　长春　130103
- 作者简介：
  
  [ "于翠玲(1979-)，女，吉林长春人，博士，讲师，2008年于吉林大学获得博士学位，主要从事光电材料与器件的研究。E-mail: cuiling.yu@hit.edu.cn" ]
- 基金信息：
  
  国家自然科学基金(51502056);中央高校基本科研业务费专项基金(HIT. NSRIF. 2020100)
- DOI：10.37188/CJL.20210285
  中图分类号： O482.31;TM914
- 纸质出版日期：2021-12，
  
  收稿日期：2021-08-27，
  
  修回日期：2021-09-10，
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于翠玲, 朱瑞滨, 林珊, 等. SnO₂∶Zn纳米晶光阳极对染料敏化太阳能电池光电性能的影响[J]. 发光学报, 2021,42(12):1936-1943.

Cui-ling YU, Rui-bin ZHU, Shan LIN, et al. Influence of Zn Doped SnO₂ Nanocrystals as Photoanode Materials on Photoelectric Performance of Dye-sensitized Solar Cells[J]. Chinese Journal of Luminescence, 2021,42(12):1936-1943.
于翠玲, 朱瑞滨, 林珊, 等. SnO₂∶Zn纳米晶光阳极对染料敏化太阳能电池光电性能的影响[J]. 发光学报, 2021,42(12):1936-1943. DOI： 10.37188/CJL.20210285.

Cui-ling YU, Rui-bin ZHU, Shan LIN, et al. Influence of Zn Doped SnO₂ Nanocrystals as Photoanode Materials on Photoelectric Performance of Dye-sensitized Solar Cells[J]. Chinese Journal of Luminescence, 2021,42(12):1936-1943. DOI： 10.37188/CJL.20210285.

摘要

利用水热法合成不同Zn掺杂含量的SnO

(SnO

∶Zn)纳米晶，并通过丝网印刷技术制备了SnO

∶Zn纳米晶光阳极，研究不同含量Zn掺杂SnO

纳米晶光阳极对染料敏化太阳能电池光电性能的影响。实验结果表明，Zn掺杂含量增加能够引起SnO

光阳极的平带电位负向偏移和等电点增加。与未掺杂SnO

染料敏化太阳能电池相比，当Zn掺杂量为2% 时，SnO

∶Zn基染料敏化太阳能电池的功率转换效率(PCE)最高，为4.2%，这归因于Zn掺杂能够增加染料在SnO

光阳极的担载量和提高染料敏化太阳能电池的光生电子寿命(

)。此外，2% Zn掺杂SnO

光阳极进一步经过TiCl

处理，其电池功率转换效率可提高到7.7%。

Abstract

Zn-doped SnO

nanocrystals under hydrothermal conditions were synthesized and subsequently the photoanodes were prepared

via

the screen printing technology for dye-sensitized solar cells. The effect of Zn-doped SnO

on the performance of dye-sensitized solar cells was investigated. It is found that Zn doping into SnO

can induce a negative shift in the flat-band potential and enhance the isoelectric point. As a result

the power conversion efficiency(PCE) of 4.2% was achieved for 2% Zn-doped SnO

based dye-sensitized solar cell compared with undoped SnO

based dye-sensitized solar cell. The enhancement in performance was ascribed to improve photogenerated electron lifetime(

) and dye-uptake capabilities. Moreover

after the TiCl

treatment of the photoanode

the 2% Zn-doped SnO

based dye-sensitized solar cell exhibited an impressive power conversion efficiency of 7.7%.

关键词

染料敏化太阳能电池SnO2Zn掺杂光阳极

Keywords

dye-sensitized solar cellSnO2Zn dopedphotoanode

references

O'REGAN B, GRÄTZEL M. A low-cost,high-efficiency solar cell based on dye-sensitized colloidal TiO2 films[J]. Nature, 1991, 353(6346):737-740.

CHUNG I, LEE B, HE J Q, et al. All-solid-state dye-sensitized solar cells with high efficiency[J]. Nature, 2012, 485(7399):486-489.

DEVADIGA D, SELVAKUMAR M, SHETTY P, et al. Recent progress in dye sensitized solar cell materials and photo-supercapacitors:a review[J]. J. Power Sources, 2021, 493:229698.

KOKKONEN M, TALEBI P, ZHOU J, et al. Advanced research trends in dye-sensitized solar cells[J]. J. Mater. Chem. A, 2021, 9(17):10527-10545.

YEOH M E, CHAN K Y. A review on semitransparent solar cells for real-life applications based on dye-sensitized technology[J]. IEEE J. Photovolt., 2021, 11(2):354-361.

YU Q J, WANG Y H, YI Z H, et al. High-efficiency dye-sensitized solar cells:the influence of lithium ions on exciton dissociation,charge recombination,and surface states[J]. ACS Nano, 2010, 4(10):6032-6038.

REN Y M, SUN D Y, CAO Y M, et al. A stable blue photosensitizer for color palette of dye-sensitized solar cells reaching 12.6% efficiency[J]. J. Am. Chem. Soc., 2018, 140(7):2405-2408.

ZENG K W, CHEN Y Y, ZHU W H, et al. Efficient solar cells based on concerted companion dyes containing two complementary components:an alternative approach for cosensitization[J]. J. Am. Chem. Soc., 2020, 142(11):5154-5161.

JI J M, ZHOU H R, EOM Y K, et al. 14.2% Efficiency dye-sensitized solar cells by co-sensitizing novel thieno[3,2-b]indole-based organic dyes with a promising porphyrin sensitizer[J]. Adv. Energy Mater., 2020, 10(15):2000124-1-12.

KUMAR V, GUPTA R, BANSAL A. Hydrothermal growth of ZnO nanorods for use in dye-sensitized solar cells[J]. ACS Appl. Nano Mater., 2021, 4(6):6212-6222.

RINGLEB A, RUESS R, HOFEDITZ N, et al. Influence of Mg-doping on the characteristics of ZnO photoanodes in dye-sensitized solar cells[J]. Phys. Chem. Chem. Phys., 2021, 23(14):8393-8402.

SOUZA A P S, OLIVEIRA F G S, NUNES V F, et al. High performance SnO2 pure photoelectrode in dye-sensitized solar cells achieved via electrophoretic technique[J]. Solar Energy, 2020, 221:312-323.

PHAM B, WILLINGER D, MCMILLAN N K, et al. Tin(Ⅳ) oxide nanoparticulate films for aqueous dye-sensitized solar cells[J]. Solar Energy, 2021, 224:984-991.

MOHITE N, SHINDE M, GUPTA A K, et al. Facile synthesis of hollow urchin-like Nb2O5 nanostructures and their performance in dye-sensitized solar cells[J]. J. Solid State Electrochem., 2020, 24(2):273-281.

ARNOLD M S, AVOURIS P, PAN Z W, et al. Field-effect transistors based on single semiconducting oxide nanobelts[J]. J. Phys. Chem. B, 2003, 107(3):659-663.

SENEVIRATHNA M K I, PITIGALA P K D D P, PREMALAL E V A, et al. Stability of the SnO2/MgO dye-sensitized photoelectrochemical solar cell[J]. Solar Energy Mater. Solar Cells, 2007, 91(6):544-547.

GREEN A N M, PALOMARES E, HAQUE S A, et al. Charge transport versus recombination in dye-sensitized solar cells employing nanocrystalline TiO2 and SnO2 films[J]. J. Phys. Chem. B, 2005, 109(25):12525-12533.

KAY A, GRÄTZEL M. Dye-sensitized core-shell nanocrystals:improved efficiency of mesoporous tin oxide electrodes coated with a thin layer of an insulating oxide[J]. Chem. Mater., 2002, 14(7):2930-2935.

WANG Y F, LI K N, LIANG C L, et al. Synthesis of hierarchical SnO2 octahedra with tailorable size and application in dye-sensitized solar cells with enhanced power conversion efficiency[J]. J. Mater. Chem., 2012, 22(40):21495-21501.

RAMASAMY E, LEE J. Ordered mesoporous Zn-doped SnO2 synthesized by exotemplating for efficient dye-sensitized solar cells[J]. Energy Environ. Sci., 2011, 4(7):2529-2536.

DOU X C, SABBA D, MATHEWS N, et al. Hydrothermal synthesis of high electron mobility Zn-doped SnO2 nanoflowers as photoanode material for efficient dye-sensitized solar cells[J]. Chem. Mater., 2011, 23(17):3938-3945.

MAO W T, LI Z D, BAO K Y, et al. Nanowire-based zinc-doped tin oxide microtubes for enhanced solar energy utilization efficiency[J]. Ceram. Int., 2017, 43(9):6822-6830.

DUAN J H, ZOU S B, YANG C M, et al. Full SnO2 double-layer dye-sensitized solar cells:slowly increasing phenomenon of power conversion efficiency[J]. Solar Energy, 2020, 196:99-106.

WANG P, ZAKEERUDDIN S M, COMTE P, et al. Enhance the performance of dye-sensitized solar cells by Co-grafting amphiphilic sensitizer and hexadecylmalonic acid on TiO2 nanocrystals[J]. J. Phys. Chem. B, 2003, 107(51):14336-14341.

ITO S, MURAKAMI T N, COMTE P, et al. Fabrication of thin film dye sensitized solar cells with solar to electric power conversion efficiency over 10%[J]. Thin Solid Films, 2008, 516(14):4613-4619.

BILGIN V, KOSE S, ATAY F, et al. The effect of Zn concentration on some physical properties of tin oxide films obtained by ultrasonic spray pyrolysis[J]. Mater. Lett., 2004, 58(29):3686-3693.

LIU X F, IQBAL J, WU Z B, et al. Structure and room-temperature ferromagnetism of Zn-Doped SnO2 nanorods prepared by solvothermal method[J]. J. Phys. Chem. C, 2010, 114(11):4790-4796.

LI Z, ZHOU Y, YU T, et al. Unique Zn-doped SnO2 nano-echinus with excellent electron transport and light harvesting properties as photoanode materials for high performance dye-sensitized solar cell[J]. CrystEngComm, 2012, 14(20):6462-6468.

XIANG P, LI X, WANG H, et al. Mesoporous nitrogen-doped TiO2 sphere applied for quasi-solid-state dye-sensitized solar cell[J]. Nanoscale Res. Lett., 2011, 6(1):606-1-5.

VAN DE KROL R, GOOSSENS A, SCHOONMAN J. Mott-Schottky analysis of nanometer-scale thin-film anatase TiO2[J]. J. Electrochem. Soc., 1997, 144(5):1723-1727.

FENG X J, SHANKAR K, PAULOSE M, et al. Tantalum-doped titanium dioxide nanowire arrays for dye-sensitized solar cells with high open-circuit voltage[J]. Angew. Chem. Int. Ed., 2009, 48(43):8095-8098.

SNAITH H J, DUCATI C. SnO2-based dye-sensitized hybrid solar cells exhibiting near unity absorbed photon-to-electron conversion efficiency[J]. Nano Lett., 2010, 10(4):1259-1265.

GRINIS L, KOTLYAR S, RÜHLE S, et al. Conformal nano-sized inorganic coatings on mesoporous TiO2 films for low-temperature dye-sensitized solar cell fabrication[J]. Adv. Funct. Mater., 2010, 20(2):282-228.

BASU K, BENETTI D, ZHAO H G, et al. Enhanced photovoltaic properties in dye sensitized solar cells by surface treatment of SnO2 photoanodes[J]. Sci. Rep., 2016, 6:23312-1-10.

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SnO2∶Zn纳米晶光阳极对染料敏化太阳能电池光电性能的影响

Influence of Zn Doped SnO2 Nanocrystals as Photoanode Materials on Photoelectric Performance of Dye-sensitized Solar Cells

DOI：10.37188/CJL.20210285

摘要

Abstract

关键词

Keywords

references

SnO₂∶Zn纳米晶光阳极对染料敏化太阳能电池光电性能的影响

Influence of Zn Doped SnO₂ Nanocrystals as Photoanode Materials on Photoelectric Performance of Dye-sensitized Solar Cells