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1. 中国科学院理化技术研究所 中国科学院光化学转换与功能材料重点实验室 北京,100190
2. 中国科学院理化技术研究所 中国科学院功能晶体与激光技术重点实验室 北京,100190
纸质出版日期:2015-2-3,
网络出版日期:2014-12-3,
收稿日期:2014-9-3,
修回日期:2014-11-19,
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陈卓, 薄淑晖, 田昌勇等. 用于液体激光介质的Nd<sup>3+</sup>离子掺杂氟化镧纳米颗粒的制备与性能表征[J]. 发光学报, 2015,36(2): 129-134
CHEN Zhuo, BO Shu-hui, TIAN Chang-yong etc. Synthesis and Characterization of Nd<sup>3+</sup> Doped LaF<sub>3</sub> Nanocrystals for Liquid Laser Medium[J]. Chinese Journal of Luminescence, 2015,36(2): 129-134
陈卓, 薄淑晖, 田昌勇等. 用于液体激光介质的Nd<sup>3+</sup>离子掺杂氟化镧纳米颗粒的制备与性能表征[J]. 发光学报, 2015,36(2): 129-134 DOI: 10.3788/fgxb20153602.0129.
CHEN Zhuo, BO Shu-hui, TIAN Chang-yong etc. Synthesis and Characterization of Nd<sup>3+</sup> Doped LaF<sub>3</sub> Nanocrystals for Liquid Laser Medium[J]. Chinese Journal of Luminescence, 2015,36(2): 129-134 DOI: 10.3788/fgxb20153602.0129.
设计并合成了掺杂不同Nd
3+
离子浓度的氟化镧纳米颗粒
并用油酸进行了表面修饰
使得这类纳米颗粒可分散于常见的有机溶剂中形成透明、均一、稳定的溶液.对纳米颗粒的结构、晶相以及发光性能进行了表征.固体和溶液材料在1 060 nm都有强的发射峰
说明纳米晶格可有效地保护Nd
3+
离子免受外界环境对发光的猝灭影响.纳米颗粒有机溶液的吸收损耗和散射损耗测试结果表明
其总损耗系数能够满足激光介质材料的损耗要求
为该材料的实用化打下了基础.
LaF
3
nanocrytals with different Nd
3+
concentration were designed
synthesized and modified by oleic acid. This kind of nanocrystals can be dissolved in many organic solvents and form a transparent
uniform and stable solution. The structure
crystal phase and luminescence properties of LaF
3
:Nd
3+
nanocrytals were characterized and studied. The nanocrytals show strong emission at 1 060 nm not only in solid but also in solution. This illustrates that the nanocrystal lattice can efficiently protect Nd
3+
ions from the influence of environment on the luminescence. Meanwhile
the absorption loss and scattering loss of LaF
3
nanocrystals in organic solution were tested by our own system. The total loss coefficient can meet the requirements for laser medium material. These results show that LaF
3
:Nd
3+
nanocrystals may be used for liquid laser medium in the future.
稀土纳米发光材料共沉淀法液体激光介质
rare-earthnanocrystal luminescent materialscoprecipitation methodliquid laser medium
Lu W, Yan L, Menyuk C R. Kerr-lens mode-locking of Nd:glass laser [J]. Opt. Commun., 2001, 200(1-6): 159-163.
Cantatore J L, Kriegel D A. Laser surgery: An approach to the pediatric patient [J]. J. Am. Acad. Dermatol., 2004, 50(2):165-184.
Nava E, Stucchi E. Development of lasers for spaceborne Doppler wind lidar applications [J]. Opt. Laser Eng., 2003, 39:255-263.
Ren G G. Current situation and development trend of high energy laser weapon [J]. Laser Optoelectron. Prog.(激光与光电子学进展), 2008, 45(9):62-69 (in Chinese).
Zhou S H. The heat managements of the solid-state lasers [J]. Chin. J. Quant. Electron.(量子电子学报), 2005, 22(4):497-509 (in Chinese).
Zhou S H, Zhao H, Tang X J. High average power laser diode pumped solid-state laser [J]. Chin. J. Lasers (中国激光), 2009, 36(7):1605-1618 (in Chinese).
Mei S S. Solid-state lasers marching to 100 kWA pilot study on overseas development of high energy solid state lasers [J]. Laser Optoelectron. Prog.(激光与光电子学进展), 2005, 42(10):2-8 (in Chinese).
Li J D, Guo M X, Fu W Q, et al. Thermal distortion influence on single-slab heat capacity laser output [J]. Chin. J. Lasers (中国激光), 2007, 34(1):45-49 (in Chinese).
Heller A. A high-gain room-temperature liquid laser: Trivalent neodymium in selenium oxychloride [J]. Appl. Phys. Lett., 1966, 9(3):106-107.
Heller A. Formation of hot OH bonds in the radiationless relaxations of excited rare earth ions in aqueous solutions [J]. J. Am. Chem. Soc., 1966, 88:2058-2059.
Winston H, Marsh O J, Suzuki C K. Fluorescence of europium thenoyltrifluoroacetonate I: Evaluation of laser threshold parameters [J]. J. Chem. Phys., 1963, 39(2):267-271.
Miao T Z, Zhang Z, Feng W X, et al. Temperature-dependent self-assembly of near-infrared (NIR) luminescent Zn2Ln and Zn2Ln3 (Ln=Nd, Yb or Er) complexes from the flexible Salen-type Schiff-base ligand [J]. Spectrochim. Acta Part A: Mol. Biomol. Spectrosc., 2014, 132:205-214.
Xu X D, Wang X D, Meng J Q, et al. Crystal growth, spectral and laser properties of Nd:LuAG single crystal [J]. Laser Phys. Lett., 2009, 6(9):678-681.
Lin J, Li C X. Hydrothermal synthesis, formation mechanisms and luminescence properties of the rare earth fluorides nano- and micro-materials [J]. Chin. J. Lumin.(发光学报), 2011, 32(6):519-534 (in Chinese).
Zhuo Z, Li T, Li S G, et al. A new composite YVO4/Nd:Y0.9La0.1VO4 crystal laser end-pumped with a fiber coupled diode array [J]. Laser Phys. Lett., 2009, 6(6):445-449.
Yu K H, Qiu X M, Xu X X, et al. Enhanced photoluminescence of Nd2O3 nanoparticles modified with silane-coupling agent: Fluorescent resonance energy transfer analysis [J]. Appl. Phys. Lett., 2007, 90(9):091916-1-3.
Yu R B, Yu K H, Wei W, et al. Nd2O3 nanoparticles modified with a silane-coupling agent as a liquid laser medium [J]. Adv. Mater., 2007, 19:838-842.
Wang G, Peng Q. Tunable photoluminescence of NaYF4:Eu nanocrystals by Sr2+ codoping [J]. Solid State Chem., 2011, 184:59-63.
Achary S N, Tyagi A K, Seshagiri T K, et al. Synthesis, powder XRD studies on LiF-BaF2/EuF3 systems and thermo-stimulated luminescence (TSL) of Eu3+ doped LiBaF3 [J]. Mater. Sci. Eng. B, 2006, 129:256-260.
Shen L F, Laibinis P E, Hatton T A. Bilayer surfactant stabilized magnetic fluids: Synthesis and interactions at interfaces [J]. Langmuir, 1999, 15(2):447-453.
Kim J, Lee J H, An H J, et al. Luminescence properties of LaF3:Ce nanoparticles encapsulated by oleic acid [J]. Mater. Res. Bull., 2014, 57:110-115.
Thistlethwaite P J, Hook M S. Diffuse reflectance Fourier transform infrared study of the absorption of oleate/oleic acid onto titania [J]. Langmuir, 2000, 16(11):4993-4998.
Thistlethwaite P J, Gee M L, Wilson D. Diffuse reflectance infrared Fourier transform spectroscopic studies of the adsorption of oleate/oleic acid onto zirconia [J]. Langmuir, 1996, 12(26):6487-6491.
Nara M, Torii H, Tasumi M. Correlation between the vibrational frequencies of the carboxylate group and the types of its coordination to a metal ion: An ab initio molecular orbital study [J]. J. Phys. Chem., 1996, 100(51):19812-19817.
Delphine P, Yan S, Mohamed B T, et al. Optical properties of Nd3+ and Yb3+-doped AgM(IO3)4 metal iodates: Transparent host matrices for mid-IR lasers and nonlinear materials [J]. J. Mater. Chem. C, 2014, 2:2715-2723.
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