用于液体激光介质的Nd3+离子掺杂氟化镧纳米颗粒的制备与性能表征

陈卓; 薄淑晖; 田昌勇; 甄珍; 刘新厚

doi:10.3788/fgxb20153602.0129

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用于液体激光介质的Nd³⁺离子掺杂氟化镧纳米颗粒的制备与性能表征

材料合成及性能 | 更新时间：2020-08-12

- 用于液体激光介质的Nd³⁺离子掺杂氟化镧纳米颗粒的制备与性能表征
- Synthesis and Characterization of Nd³⁺ Doped LaF₃ Nanocrystals for Liquid Laser Medium
- 发光学报 2015年36卷第2期页码：129-134
- 作者机构：
  
  1. 中国科学院理化技术研究所中国科学院光化学转换与功能材料重点实验室北京,100190
  2. 中国科学院理化技术研究所中国科学院功能晶体与激光技术重点实验室北京,100190
- 作者简介：
- 基金信息：
  
  国家自然科学基金(61101054)资助项目()
- DOI：10.3788/fgxb20153602.0129
  中图分类号： O614.33
- 纸质出版日期：2015-2-3，
  
  网络出版日期：2014-12-3，
  
  收稿日期：2014-9-3，
  
  修回日期：2014-11-19，
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陈卓, 薄淑晖, 田昌勇等. 用于液体激光介质的Nd3+离子掺杂氟化镧纳米颗粒的制备与性能表征[J]. 发光学报, 2015,36(2): 129-134

CHEN Zhuo, BO Shu-hui, TIAN Chang-yong etc. Synthesis and Characterization of Nd3+ Doped LaF3 Nanocrystals for Liquid Laser Medium[J]. Chinese Journal of Luminescence, 2015,36(2): 129-134
陈卓, 薄淑晖, 田昌勇等. 用于液体激光介质的Nd3+离子掺杂氟化镧纳米颗粒的制备与性能表征[J]. 发光学报, 2015,36(2): 129-134 DOI： 10.3788/fgxb20153602.0129.

CHEN Zhuo, BO Shu-hui, TIAN Chang-yong etc. Synthesis and Characterization of Nd3+ Doped LaF3 Nanocrystals for Liquid Laser Medium[J]. Chinese Journal of Luminescence, 2015,36(2): 129-134 DOI： 10.3788/fgxb20153602.0129.

摘要

设计并合成了掺杂不同Nd

离子浓度的氟化镧纳米颗粒

并用油酸进行了表面修饰

使得这类纳米颗粒可分散于常见的有机溶剂中形成透明、均一、稳定的溶液.对纳米颗粒的结构、晶相以及发光性能进行了表征.固体和溶液材料在1 060 nm都有强的发射峰

说明纳米晶格可有效地保护Nd

离子免受外界环境对发光的猝灭影响.纳米颗粒有机溶液的吸收损耗和散射损耗测试结果表明

其总损耗系数能够满足激光介质材料的损耗要求

为该材料的实用化打下了基础.

Abstract

LaF

nanocrytals with different Nd

concentration were designed

synthesized and modified by oleic acid. This kind of nanocrystals can be dissolved in many organic solvents and form a transparent

uniform and stable solution. The structure

crystal phase and luminescence properties of LaF

:Nd

nanocrytals were characterized and studied. The nanocrytals show strong emission at 1 060 nm not only in solid but also in solution. This illustrates that the nanocrystal lattice can efficiently protect Nd

ions from the influence of environment on the luminescence. Meanwhile

the absorption loss and scattering loss of LaF

nanocrystals in organic solution were tested by our own system. The total loss coefficient can meet the requirements for laser medium material. These results show that LaF

:Nd

nanocrystals may be used for liquid laser medium in the future.

关键词

稀土纳米发光材料共沉淀法液体激光介质

Keywords

rare-earthnanocrystal luminescent materialscoprecipitation methodliquid laser medium

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