Preparation and Photoluminescence Properties of CaLuBO4: Tb3+ Phosphor

SUN Xiao-yuan; FAN Xiao-xuan; HE Jun-jie; LYU Qi-song; JIANG Guang-yuan; DENG Yun; LUO Yon

doi:10.3788/fgxb20204103.0265

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Preparation and Photoluminescence Properties of CaLuBO₄: Tb³⁺ Phosphor

Synthesis and Properties of Materials | 更新时间：2020-08-12

- Preparation and Photoluminescence Properties of CaLuBO₄: Tb³⁺ Phosphor
- Chinese Journal of Luminescence Vol. 41, Issue 3, Pages: 265-270(2020)
- 作者机构：
  
  1. 长春师范大学物理学院,吉林长春,130032
  2. 中国科学院长春光学精密机械与物理研究所发光学及应用国家重点实验室, 吉林长春 130033
  3. 牡丹江师范学院理学院, 黑龙江牡丹江 157012
- 作者简介：
- 基金信息：
  
  Supported by Natural Science Foundation of Changchun Normal University([2015]006)
- DOI：10.3788/fgxb20204103.0265
  CLC：
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孙晓园, 范小暄, 何俊杰等. CaLuBO4:Tb3+荧光粉的制备及发光性质[J]. 发光学报, 2020,41(3): 265-270

SUN Xiao-yuan, FAN Xiao-xuan, HE Jun-jie etc. Preparation and Photoluminescence Properties of CaLuBO4: Tb3+ Phosphor[J]. Chinese Journal of Luminescence, 2020,41(3): 265-270
孙晓园, 范小暄, 何俊杰等. CaLuBO4:Tb3+荧光粉的制备及发光性质[J]. 发光学报, 2020,41(3): 265-270 DOI： 10.3788/fgxb20204103.0265.

SUN Xiao-yuan, FAN Xiao-xuan, HE Jun-jie etc. Preparation and Photoluminescence Properties of CaLuBO4: Tb3+ Phosphor[J]. Chinese Journal of Luminescence, 2020,41(3): 265-270 DOI： 10.3788/fgxb20204103.0265.

摘要

采用高温固相反应法合成了不同Tb,3+,掺杂浓度的CaLuBO,4,:,x,Tb,3+,荧光粉，研究了样品的晶体结构和发光性质。在紫外光激发下，样品的发射光谱由Tb,3+,离子的,5,D,3,7,F,J,（,J,=6，5，4）和,5,D,4,7,F,J,',（,J,'=6，5，4，3）特征发射组成，其中位于545 nm和554 nm附近的,5,D,4,7,F,5,跃迁发射强度最大。荧光粉的激发光谱是由位于紫外区的Tb,3+,的4f-5d和f-f跃迁构成的。研究了Tb,3+,浓度对样品发光性质的影响。测量并分析了CaLuBO,4,:,x,Tb,3+,荧光粉的,5,D,3,能级和,5,D,4,能级荧光寿命。结果表明，CaLuBO,4,:,x,Tb,3+,是一种适于紫外激发的新型黄绿光荧光粉。

Abstract

The phosphors CaLuBO,4,:,x,Tb,3+, were synthesized through the solid-state reaction technique. The structure, photoluminescence properties of these phosphors were described. Upon excitation with UV light excitation, the photoluminescence emission spectra could be assigned to the transitions of Tb,3+, from ,5,D,3,7,F,J, (,J,=6, 5, 4) and ,5,D,4,7,F,J', (,J,'=6, 5, 4, 3). The two strong emissions peaked at 545 nm and 554 nm, which arose from the ,5,D,4,-,7,F,5, of Tb,3+, respectively. The photoluminescence excitation spectra show a broad 4f-5d band and f,-,f transitions in UV region. The dependence of photoluminescence intensities on Tb,3+, concentration was studied. The luminescence lifetimes of ,5,D,3, and ,5,D,4, energy level were measured and analysed, respectively. The CaLuBO,4,:,x,Tb,3+, phosphor is a novel yellow-green emitting phosphor suitable for ultraviolet light excitation.

关键词

荧光粉光致发光荧光寿命

Keywords

phosphorphotoluminescencefluorescence lifetime

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