1. 长春师范大学 物理学院,吉林 长春,130032
2. 中国科学院长春光学精密机械与物理研究所 发光学及应用国家重点实验室, 吉林 长春 130033
3. 牡丹江师范学院 理学院, 黑龙江 牡丹江 157012
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孙晓园, 范小暄, 何俊杰等. CaLuBO<sub>4</sub>:Tb<sup>3+</sup>荧光粉的制备及发光性质[J]. 发光学报, 2020,41(3): 265-270
SUN Xiao-yuan, FAN Xiao-xuan, HE Jun-jie etc. Preparation and Photoluminescence Properties of CaLuBO<sub>4</sub>: Tb<sup>3+</sup> Phosphor[J]. Chinese Journal of Luminescence, 2020,41(3): 265-270
孙晓园, 范小暄, 何俊杰等. CaLuBO<sub>4</sub>:Tb<sup>3+</sup>荧光粉的制备及发光性质[J]. 发光学报, 2020,41(3): 265-270 DOI: 10.3788/fgxb20204103.0265.
SUN Xiao-yuan, FAN Xiao-xuan, HE Jun-jie etc. Preparation and Photoluminescence Properties of CaLuBO<sub>4</sub>: Tb<sup>3+</sup> Phosphor[J]. Chinese Journal of Luminescence, 2020,41(3): 265-270 DOI: 10.3788/fgxb20204103.0265.
采用高温固相反应法合成了不同Tb,3+,掺杂浓度的CaLuBO,4,:,x,Tb,3+,荧光粉,研究了样品的晶体结构和发光性质。在紫外光激发下,样品的发射光谱由Tb,3+,离子的,5,D,3,7,F,J,(,J,=6,5,4)和,5,D,4,7,F,J,',(,J,'=6,5,4,3)特征发射组成,其中位于545 nm和554 nm附近的,5,D,4,7,F,5,跃迁发射强度最大。荧光粉的激发光谱是由位于紫外区的Tb,3+,的4f-5d和f-f跃迁构成的。研究了Tb,3+,浓度对样品发光性质的影响。测量并分析了CaLuBO,4,:,x,Tb,3+,荧光粉的,5,D,3,能级和,5,D,4,能级荧光寿命。结果表明,CaLuBO,4,:,x,Tb,3+,是一种适于紫外激发的新型黄绿光荧光粉。
The phosphors CaLuBO,4,:,x,Tb,3+, were synthesized through the solid-state reaction technique. The structure, photoluminescence properties of these phosphors were described. Upon excitation with UV light excitation, the photoluminescence emission spectra could be assigned to the transitions of Tb,3+, from ,5,D,3,7,F,J, (,J,=6, 5, 4) and ,5,D,4,7,F,J', (,J,'=6, 5, 4, 3). The two strong emissions peaked at 545 nm and 554 nm, which arose from the ,5,D,4,-,7,F,5, of Tb,3+, respectively. The photoluminescence excitation spectra show a broad 4f-5d band and f,-,f transitions in UV region. The dependence of photoluminescence intensities on Tb,3+, concentration was studied. The luminescence lifetimes of ,5,D,3, and ,5,D,4, energy level were measured and analysed, respectively. The CaLuBO,4,:,x,Tb,3+, phosphor is a novel yellow-green emitting phosphor suitable for ultraviolet light excitation.
荧光粉光致发光荧光寿命
phosphorphotoluminescencefluorescence lifetime
张亮亮,张家骅,郝振东,等. Cr3+掺杂的宽带近红外荧光粉及其研究进展[J]. 发光学报, 2019,40(12):1449-1459. ZHANG L L,ZHANG J H,HAO Z D,et al.. Recent progress on Cr3+ doped broad band NIR phosphors[J]. Chin. J. Lumin., 2019,40(12):1449-1459. (in Chinese)
刘行仁. CRT、VFD及FED显示器用的荧光粉的进展[J]. 液晶与显示, 1996,11(1):61-68. LIU X R. Progress of the phosphors for CRT、VFD and FED displays[J]. Chin. J. Liq. Cryst. Disp., 1996,11(1):61-68. (in Chinese)
ZHANG C H,LIU Y F,ZHANG J H,et al.. A single-phase Ba9Lu2Si6O24:Eu2+,Ce3+,Mn2+ phosphor with tunable full-color emission for NUV-based white LED applications[J]. Mater. Res. Bull., 2016,80:288-294.
王巍,李一,宁平凡,等. 广色域钙钛矿量子点/荧光粉转换白光LED[J]. 发光学报, 2018,39(5):627-632. WANG W,LI Y,NING P F,et al.. Perovskite quantum dot/powder phosphor converted white light LEDs with wide color gamut[J]. Chin. J. Lumin., 2018,39(5):627-632. (in Chinese)
王娟娟,袁曦明,李予晋,等. 共沉淀法制备PDP用红色荧光粉(Y,Gd)BO3:Eu3+的正交实验研究[J]. 液晶与显示, 2009,24(5):645-649. WANG J J,YUAN X M,LI Y J,et al.. Preparation of red phosphor (Y,Gd)BO3:Eu3+ by coprecipitation method with orthogonal test[J]. Chin. J. Liq. Cryst. Disp., 2009,24(5):645-649. (in Chinese)
付作岭,董晓睿,盛天琦,等. 纳米晶体中稀土离子的发光性质及其变化机理研究[J]. 中国光学, 2015,8(1):139-146. FU Z L,DONG X R,SHENG T Q,et al.. Luminescene properties and various mechanisms of rare earth ions in the nanocrystals[J]. Chin. Opt., 2015,8(1):139-146. (in Chinese)
NAIR G B,DHOBLE S J. Assessment of electron-vibrational interaction (EVI) parameters of YAG:Ce3+,TAG:Ce3+ and LuAG:Ce3+ garnet phosphors by spectrum fitting method[J]. Spectrochim. Acta Part A:Mol. Biomol. Spectrosc., 2017,173:822-826.
徐文,陈旭,宋宏伟. 稀土离子上转换发光中的局域电磁场调控[J]. 发光学报, 2018,39(1):1-26. XU W,CHEN X,SONG H W. Manipulation of local electromagnetic field in upconversion luminescence of rare earth ions[J]. Chin. J. Lumin., 2018,39(1):1-26. (in Chinese)
周青超,柏泽龙,鲁路,等. 白光LED远程荧光粉技术研究进展与展望[J]. 中国光学, 2015,8(3):313-328. ZHOU Q C,BAI Z L,LU L,et al.. Remote phosphor technology for white LED applications:advances and prospects[J]. Chin. Opt., 2015,8(3):313-328. (in Chinese)
洪广言. 稀土发光材料[M]. 北京:科学出版社, 2011:6-8. HONG G Y. Fundamental and Application of Rare Earth Luminescent Materials[M]. Beijing:Science Press, 2011:6-8. (in Chinese)
HAO Z D,ZHANG J H,ZHANG X,et al.. An intense blue-emitting phosphor for near-ultraviolet pumped white-light-emitting diodes:Ce3+-activated -Ca2SiO4[J]. J. Lumin., 2014,152:40-43.
唐靓,叶慧琪,肖东. 溶胶-凝胶法制备YAG:Ce,Yb纳米荧光粉及其发光性质研究[J]. 发光学报, 2018,39(8):1051-1058. TANG L,YE H Q,XIAO D. YAG:Ce,Yb nano-phosphor synthesized by sol-gel method and its luminescence properties[J]. Chin. J. Lumin., 2018,39(8):1051-1058. (in Chinese)
ZHANG L L,ZHANG J H,ZHANG X,et al.. Site distortion in Li2SrSiO4:influence on Pr3+ emission and application in wLED[J]. J. Lumin., 2016,180:158-162.
闫宏,宋婷,张猛,等. 高性能X射线影像存储12CaO7Al2O3:Pr3+荧光粉的微结构及光学特性[J]. 发光学报, 2018,39(7):895-902. YAN H,SONG T,ZHANG M,et al.. Microstructure and optical properties of 12CaO7Al2O3:Pr3+ phosphors for high quality X-ray imaging[J]. Chin. J. Lumin., 2018,39(7):895-902. (in Chinese)
WANG B H,WANG Z H,LIU Y G,et al.. Crystal structure tailoring and luminescence tuning of Sr1-xBaxAl2Si2O8:Eu2+ phosphors for white-light-emitting diodes[J]. J. Alloys Compd., 2019,776:554-559.
ZHANG Y J,ZHANG H,DONG P P,et al.. Synthesis,structure and photoluminescence properties of (Sr,Ca)AlSiN3:Eu2+ phosphor for white light emitting diodes with controllable optical performance[J]. J. Mater. Sci.:Mater. Electron., 2017,28(1):86-93.
ZHONG J S,CHEN D Q,YUAN Y J,et al.. Synthesis and spectroscopic investigation of Ba3La6(SiO4)6:Eu2+ green phosphors for white light-emitting diodes[J]. Chem. Eng. J., 2017,309:795-801.
LI J,CHEN L,ZHANG J H,et al.. Photoluminescence properties of a novel red-emitting phosphor Eu3+ activated scandium molybdate for white light emitting diodes[J]. Mater. Res. Bull., 2016,83:290-293.
HUANG C H,CHEN C T,GUO S Q,et al.. Luminescence and theoretical calculations of novel red-emitting NaYPO4F:Eu3+ phosphor for LED applications[J]. J. Alloys Compd., 2017,712:225-232.
ZHOU L Y,HUANG J L,YI L H,et al.. Luminescent properties of Ba3Gd(BO3)3:Eu3+ phosphor for white LED applications[J]. J. Rare Earths, 2009,27(1):54-57.
孙雷,张毅,胡兴凯,等. LED用KZn4(BO3)3:Eu3+荧光粉的合成与发光性能研究[J]. 液晶与显示, 2014,29(6):893-900. SUN L,ZHANG Y,HU X K,et al.. Synthesis and photoluminescence properties of KZn4(BO3)3:Eu3+ red-emitting phosphor[J]. Chin. J. Liq. Cryst. Disp., 2014,29(6):893-900. (in Chinese)
张家骅,吕伟,郝振东,等. 利用能量传递实现可调全色单一白光BaMg2Al6Si9O30:Eu2+,Tb3+,Mn2+荧光粉(特邀)[J]. 中国光学, 2012,5(3):203-208. ZHANG J H,L W,HAO Z D,et al.. Color-tunable white-light emitting BaMg2Al6Si9O30:Eu2+,Tb3+,Mn2+ phosphors via energy transfer (Invited)[J]. Chin. Opt., 2012,5(3):203-208. (in Chinese)
RAO B V,RAMBABU U,BUDDHUDU S. Analysis of green luminescent Tb3+:Ca4GdO(BO3)3 powder phosphor[J]. Phys. B:Condens. Matter, 2007,391(2):339-343.
ZHANG R,WANG X. Preparation and luminescent characteristics of Sr3RE2(BO3)4:Dy3+ (RE=Y,La,Gd) phosphors for white LED[J]. J. Alloys Compd., 2011,509(4):1197-1200.
LENG J,TANG J,XIE W Y,et al.. Impact of pH and urea content on size and luminescence of upconverting Y2O3:Yb,Er nanophosphors[J]. Mater. Res. Bull., 2018,100:171-177.
王林香,庹娟,叶颖,等. Li+,Zn2+,Mg2+掺杂Lu2O3:Er3+荧光粉的制备及发光特性[J]. 中国光学, 2019,12(1):112-121. WANG L X,TUO J,YE Y,et al.. Preparation and luminescence properties of Li+,Zn2+,Mg2+ doped Lu2O3:Er3+ phosphors[J]. Chin. Opt., 2019,12(1):112-121. (in Chinese)
YAN X,FERN G R,WITHNALL R,et al.. Contrasting behaviour of the co-activators in the luminescence spectra of Y2O2S:Tb3+,Er3+ nanometre sized particles under UV and red light excitation[J]. Nanoscale, 2013,5(3):1091-1096.
ZHAO W Y,AN S L,FAN B,et al.. Cathodoluminescent properties of the green phosphor Sr3Gd(BO3)3:Tb3+[J]. Opt. Mater., 2012,34(7):1124-1127.
林惠红,梁宏斌,苏锵,等. Sr2Mg(BO3)2:Tb3+的真空紫外发光性质[J]. 光谱学与光谱分析, 2011,31(7):1743-1746. LIN H H,LIANG H B,SU Q,et al.. Luminescence of Sr2Mg(BO3)2:Tb3+ under vacuum ultraviolet excitation[J]. Spectrosc. Spect. Anal., 2011,31(7):1743-1746. (in Chinese)
洪广言. 稀土发光材料[M]. 北京:科学出版社, 2011:160. HONG G Y. Fundamental and Application of Rare Earth Luminescent Materials[M]. Beijing:Science Press, 2011:160. (in Chinese)
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