Synthesis, Properties and Application of All-inorganic Perovskite Quantum Dots

LIU Wang-yu; CHEN Fei; KONG Shu-qi; TANG Ai-wei

doi:10.3788/fgxb20204102.0117

您当前的位置：

首页 >

文章列表页 >

Synthesis, Properties and Application of All-inorganic Perovskite Quantum Dots

Synthesis and Properties of Materials | 更新时间：2020-08-12

- Synthesis, Properties and Application of All-inorganic Perovskite Quantum Dots
- Chinese Journal of Luminescence Vol. 41, Issue 2, Pages: 117-133(2020)
- 作者机构：
  
  北京交通大学理学院北京,100044
- 作者简介：
- 基金信息：
  
  Supported by Fundamental Research Funds for The Central Universities(2019RC020);Na
- DOI：10.3788/fgxb20204102.0117
  CLC： TP394.1;TH691.9
- Published：5 February 2020，
  
  Published Online：30 October 2019，
  
  Received：29 September 2019，
  
  Revised：27 October 2019，
扫描看全文
刘王宇, 陈斐, 孔淑祺等. 全无机钙钛矿量子点的合成、性质及发光二极管应用进展[J]. 发光学报, 2020,41(2): 117-133

LIU Wang-yu, CHEN Fei, KONG Shu-qi etc. Synthesis, Properties and Application of All-inorganic Perovskite Quantum Dots[J]. Chinese Journal of Luminescence, 2020,41(2): 117-133
刘王宇, 陈斐, 孔淑祺等. 全无机钙钛矿量子点的合成、性质及发光二极管应用进展[J]. 发光学报, 2020,41(2): 117-133 DOI： 10.3788/fgxb20204102.0117.

LIU Wang-yu, CHEN Fei, KONG Shu-qi etc. Synthesis, Properties and Application of All-inorganic Perovskite Quantum Dots[J]. Chinese Journal of Luminescence, 2020,41(2): 117-133 DOI： 10.3788/fgxb20204102.0117.

摘要

近年来，全无机铯铅卤素钙钛矿（CsPb

，

=Cl，Br，I）量子点由于其色纯度高、具有可调谐的发射波长（410~760 nm）、窄的半峰宽（12~42 nm）和较高的荧光量子产率（最高可达95%以上）以及可全溶液处理等优势而受到人们的高度关注，在显示和照明领域有着较为广阔的应用前景。本文首先介绍了近年来发展起来的全无机钙钛矿量子点的液相合成方法，如高温热注射法、一步反应法、阴离子交换法和过饱和重结晶法等；其次介绍了全无机钙钛矿量子点的形貌、尺寸和晶型调控及材料组分、反应温度和杂质离子对其发光性能的影响，进而总结了无铅全无机钙钛矿量子点的研究进展；然后介绍了全无机钙钛矿量子点在发光二极管方面的应用进展；最后概述了全无机钙钛矿量子点在未来发展中存在的挑战和机遇。

Abstract

In recent years

all-inorganic cesium lead halide(CsPb

=Cl

I) perovskite quantum dots have attracted much attention due to their high color purity

tunable emission wavelength(410-760 nm)

narrow full width at half maximum (12-42 nm)

high photoluminescence quantum yield(up to 95% or more) and solution process ability. They have exhibited promising potential applications in displays and lightening. In this review

we firstly introduce the developing liquid-phase synthetic methods of all-inorganic cesium lead halide

such as high-temperature injection strategy

one-pot method

anion exchange approach

supersaturated re-crystallization method

and so on. Secondly

we present the influencing factors

such as size

morphology and crystal tailoring as well as the effects of composition

reaction temperature and dopants

on the photoluminescence properties

and the progress on all-inorganic lead-free perovskite quantum dots. We also summarize the advances in the light-emitting diodes based on all-inorganic quantum dots. Finally

the challenges and opportunities in the future are also highlighted.

关键词

全无机钙钛矿量子点合成方法光电性能发光二极管

Keywords

all-inorganic perovskitesquantum dotssynthetic methodsoptoelectronic propertieslight-emitting diodes

references

SWARNKAR A,CHULLIYIL R,RAVI V K,et al.. Colloidal CsPbBr3 perovskite nanocrystals:luminescence beyond traditional quantum dots[J]. Angew. Chem. Int. Ed. Engl., 2015,54(51):15424-15428.

MLLER C K. Crystal structure and photoconductivity of csium plumbohalides[J]. Nature, 1958,182(4647):1436.

NIKL M,NITSCH K,POLK K,et al.. Quantum size effect in the excitonic luminescence of CsPbX3-like quantum dots in CsX(X=Cl,Br) single crystal host[J]. J. Lumin., 1997,72-74:377-379.

PROTESESCU L,YAKUNIN S,BODNARCHUK M I,et al.. Nanocrystals of cesium lead halide perovskites (CsPbX3,X=Cl,Br,and I):novel optoelectronic materials showing bright emission with wide color gamut[J]. Nano Lett., 2015,15(6):3692-3696.

LIAO M L,SHAN B B,LI M. In situ Raman spectroscopic studies of thermal stability of all-inorganic cesium lead halide (CsPbX3,X=Cl,Br,I) perovskite nanocrystals[J]. J. Phys. Chem. Lett., 2019,10(6):1217-1225.

LIN K B,XING J,QUAN L N,et al.. Perovskite light-emitting diodes with external quantum efficiency exceeding 20 percent[J]. Nature, 2018,562(7726):245-248.

SONG J Z,LI J H,LI X M,et al.. Quantum dot light-emitting diodes based on inorganic perovskite cesium lead halides (CsPbX3)[J]. Adv. Mater., 2015,27(44):7162-7167.

XU H W,WANG J,XUAN T T,et al.. Convenient and large-scale synthesis of high-quality,all-inorganic lead halide perovskite nanocrystals for white light-emitting diodes[J]. Chem. Eng. J., 2019,364:20-27.

HUANG H,BODNARCHUK M I,KERSHAW S V,et al.. Lead halide perovskite nanocrystals in the research spotlight:stability and defect tolerance[J]. ACS Energy Lett., 2017,2(9):2071-2083.

SWARNKAR A,MIR W J,NAG A. Can B-site doping or alloying improve thermal-and phase-stability of all-inorganic CsPbX3(X=Cl,Br,I) perovskites?[J]. ACS Energy Lett., 2018,3(2):286-289.

WANG S,YU J H,ZHANG M Y,et al.. Stable,strongly emitting cesium lead bromide perovskite nanorods with high optical gain enabled by an intermediate monomer reservoir synthetic strategy[J]. Nano Lett., 2019,19(9):6315-6322.

ZHANG D D,EATON S W,YU Y,et al.. Solution-phase synthesis of cesium lead halide perovskite nanowires[J]. J. Am. Chem. Soc., 2015,137(29):9230-9233.

CHEN X,PENG L C,HUANG K K,et al.. Non-injection gram-scale synthesis of cesium lead halide perovskite quantum dots with controllable size and composition[J]. Nano Res., 2016,9(7):1994-2006.

NEDELCU G,PROTESESCU L,YAKUNIN S,et al.. Fast anion-exchange in highly luminescent nanocrystals of cesium lead halide perovskites (CsPbX3,X=Cl,Br,I)[J]. Nano Lett., 2015,15(8):5635-5640.

AKKERMAN Q A,D'INNOCENZO V,ACCORNERO S,et al.. Tuning the optical properties of cesium lead halide perovskite nanocrystals by anion exchange reactions[J]. J. Am. Chem. Soc., 2015,137(32):10276-10281.

LI X M,WU Y,ZHANG S L,et al.. CsPbX3 quantum dots for lighting and displays:room-temperature synthesis,photoluminescence superiorities,underlying origins and white light-emitting diodes[J]. Adv. Funct. Mater., 2016,26(15):2435-2445.

SUN S B,YUAN D,XU Y,et al.. Ligand-mediated synthesis of shape-controlled cesium lead halide perovskite nanocrystals via reprecipitation process at room temperature[J]. ACS Nano, 2016,10(3):3648-3657.

LONG Z,REN H,SUN J H,et al.. High-throughput and tunable synthesis of colloidal CsPbX3 perovskite nanocrystals in a heterogeneous system by microwave irradiation[J]. Chem. Commun., 2017,53(71):9914-9917.

IMRAN M,DI STASIO F,DANG Z Y,et al.. Colloidal synthesis of strongly fluorescent CsPbBr3 nanowires with width tunable down to the quantum confinement regime[J]. Chem. Mater., 2016,28(18):6450-6454.

DU Z T,FU D F,YANG T,et al.. Photo detectors with ultra-high detectivity based on stabilized all-inorganic perovskite CsPb0.922Sn0.078I3 nanobelts[J]. J. Mater. Chem. C, 2018,6(23):6287-6296.

SHAMSI J,DANG Z Y,BIANCHINI P,et al.. Colloidal synthesis of quantum confined single crystal CsPbBr3 nanosheets with lateral size control up to the micrometer range[J]. J. Am. Chem. Soc., 2016,138(23):7240-7243.

YUAN Y,LIU Z,LIU Z,et al.. Photoluminescence and self-assembly of cesium lead halide perovskite nanocrystals:effects of chain length of organic amines and reaction temperature[J]. Appl. Surf. Sci., 2017,405:280-288.

BEKENSTEIN Y,KOSCHER B A,EATHON S W,et al.. Highly luminescent colloidal nanoplates of perovskite cesium lead halide and their oriented assemblies[J]. J. Am. Chem. Soc., 2015,137(51):16008-16011.

LI Z J,HOFMAN E,DAVIS A H,et al.. General strategy for the growth of CsPbX3(X=Cl,Br,I) perovskite nanosheets from the assembly of nanorods[J]. Chem. Mater., 2018,30(11):3854-3860.

CHEN W W,XIN X,ZANG Z G,et al.. Tunable photoluminescence of CsPbBr3 perovskite quantum dots for light emitting diodes application[J]. J. Solid State Chem., 2017,255:115-120.

YUAN L,PATTERSON R,WEN X M,et al.. Investigation of anti-solvent induced optical properties change of cesium lead bromide iodide mixed perovskite (CsPbBr3-xIx) quantum dots[J]. J. Colloid Interface Sci., 2017,504:586-592.

SHARMA S,WEIDEN N,WEISS A. Phase diagrams of quasibinary systems of the type:ABX3-A'BX3;ABX3-AB'X3,and ABX3-ABX'3;X=halogen[J]. Z. Phys. Chem., 1992,175(1):63-80.

TROTS D M,MYAGKOTA S V. High-temperature structural evolution of caesium and rubidium triiodoplumbates[J]. J. Phys. Chem. Solids, 2008,69(10):2520-2526.

STOUMPOS C C,MALLIAKAS C D,KANATZIDIS M G. Semiconducting tin and lead iodide perovskites with organic cations:phase transitions,high mobilities,and near-infrared photoluminescent properties[J]. Inorg. Chem., 2013,52(15):9019-9038.

SHI Z F,LI Y,ZHANG Y T,et al.. High-efficiency and air-stable perovskite quantum dots light-emitting diodes with an all-inorganic heterostructure[J]. Nano Lett., 2017,17(1):313-321.

YUAN S,WANG Z K,ZHUO M P,et al.. Self-assembled high quality CsPbBr3 quantum dot films toward highly efficient light-emitting diodes[J]. ACS Nano, 2018,12(9):9541-9548.

LIU W Y,LIN Q L,LI H B,et al.. Mn2+-doped lead halide perovskite nanocrystals with dual-color emission controlled by halide content[J]. J. Am. Chem. Soc., 2016,138(45):14954-14961.

PAROBEK D,ROMAN B J,DONG Y T,et al.. Exciton-to-dopant energy transfer in Mn-doped cesium lead halide perovskite nanocrystals[J]. Nano Lett., 2016,16(12):7376-7380.

LIU H W,WU Z N,SHAO J R,et al.. CsPbxMn1-xCl3 perovskite quantum dots with high Mn substitution ratio[J]. ACS Nano, 2017,11(2):2239-2247.

ZOU S H,LIU Y S,LI J H,et al.. Stabilizing cesium lead halide perovskite lattice through Mn(Ⅱ) substitution for air-stable light-emitting diodes[J]. J. Am. Chem. Soc., 2017,139(33):11443-11450.

陈肖慧,季思航,袁曦,等. Mn掺杂CsPbCl3钙钛矿量子点的发光性质[J]. 发光学报, 2018,39(5):609-614. CHEN X H,JI S H,YUAN X,et al.. Photoluminescence properties of Mn doped CsPbCl3 perovskite quantum dots[J]. Chin. J. Lumin., 2018,39(5):609-614. (in Chinese)

WANG H C,WANG W G,TANG A C,et al.. High-performance CsPb1-xSnxBr3 perovskite quantum dots for light-emitting diodes[J]. Angew. Chem. Int. Ed. Engl., 2017,56(44):13650-13654.

LIU M,ZHONG G H,YIN Y M,et al.. Aluminum-doped cesium lead bromide perovskite nanocrystals with stable blue photoluminescence used for display backlight[J]. Adv. Sci., 2017,4(11):1700335-1-8.

WANG X T,ZHANG T Y,LOU Y B,et al.. All-inorganic lead-free perovskites for optoelectronic applications[J]. Mater. Chem. Front., 2019,3(3):365-375.

KRISHNAMOORTHY T,DING H,YAN C,et al.. Lead-free germanium iodide perovskite materials for photovoltaic applications[J]. J. Mater. Chem. A, 2015,3(47):23829-23832.

NELSON R D,SANTRA K,WANG Y,et al.. Synthesis and optical properties of ordered-vacancy perovskite cesium bismuth halide nanocrystals[J]. Chem. Commun., 2018,54(29):3640-3643.

PARK B W,PHILIPPE B,ZHANG X L,et al.. Bismuth based hybrid perovskites A3Bi2I9(A:methylammonium or cesium) for solar cell application[J]. Adv. Mater., 2015,27(43):6806-6813.

LOU Y B,FANG M Y,CHEN J X,et al.. Formation of highly luminescent cesium bismuth halide perovskite quantum dots tuned by anion exchange[J]. Chem. Commun., 2018,54(30):3779-3782.

CHUNG I,LEE B,HE J Q,et al.. All-solid-state dye-sensitized solar cells with high efficiency[J]. Nature, 2012,485(7399):486-489.

WANG B,ZHANG C Y,HUANG S Q,et al.. Postsynthesis phase transformation for CsPbBr3/Rb4PbBr6 core/shell nanocrystals with exceptional photostability[J]. ACS Appl. Mater. Interface, 2018,10(27):23303-23310.

余彬海,卢汉光,饶龙石,等. 微通道反应器合成高质量的无机钙钛矿量子点及其LED应用[J]. 发光学报, 2018,39(4):440-448. YU B H,LU H G,RAO L S,et al.. Synthesis of high quality inorganic perovskite quantum dots via microchannel reactor and their application in LED[J]. Chin. J. Lumin., 2018,39(4):440-448. (in Chinese)

LI G P,HUANG J S,ZHU H W,et al.. Surface ligand engineering for near-unity quantum yield inorganic halide perovskite QDs and high-performance QLEDs[J]. Chem. Mater., 2018,30(17):6099-6107.

CHIBA T,HOSHI K,PU Y J,et al.. High-efficiency perovskite quantum-dot light-emitting devices by effective washing process and interfacial energy level alignment[J]. ACS Appl. Mater. Interfaces, 2017,9(21):18054-18060.

WANG H R,ZHANG X Y,WU Q Q,et al.. Trifluoroacetate induced small-grained CsPbBr3 perovskite films result in efficient and stable light-emitting devices[J]. Nat. Commun., 2019,10:665-1-10.

PALAZON F,AKKERMAN Q A,PRATO M,et al.. X-Ray lithography on perovskite nanocrystals films:from patterning with anion-exchange reactions to enhanced stability in air and water[J]. ACS Nano, 2016,10(1):1224-1230.

SUN C,ZHANG Y,RUAN C,et al.. Efficient and stable white LEDs with silica-coated inorganic perovskite quantum dots[J]. Adv. Mater., 2016,28(45):10088-10094.

WU H,WANG S,CAO F,et al.. Ultrastable inorganic perovskite nanocrystals coated with thick long-chain polymer for efficient white light-emitting diodes[J]. Chem. Mater., 2019,31(6):1936-1940.

QIU L,HAO J R,FENG Y X,et al.. One-pot in situ synthesis of CsPbX3@h-BN(X=Cl,Br,I) nanosheet composites with superior thermal stability for white LEDs[J]. J. Mater. Chem. C, 2019,7(14):4038-4042.

XIANG W C,TRESS W. Review on recent progress of all-inorganic metal halide perovskites and solar cells[J]. Adv. Mater., 2019,31(44):1902851.

GIUSTINO F,SNAITH H J. Toward lead-free perovskite solar cells[J]. ACS Energy Lett., 2016,1(6):1233-1240.

ZHAO X G,YANG J H,FU Y H,et al.. Design of lead-free inorganic halide perovskites for solar cells via cation-transmutation[J]. J. Am. Chem. Soc., 2017,139(7):2630-2638.

Views

298

下载量

CSCD

Alert me when the article has been cited

提交

Tools

Publicity Resources

Synthesis and Luminescence Properties of CuInS₂ Nanocrystals

Rapid Detection of Neonicotinoids by Metal Halide CH₃NH₃PbBr₃ Perovskite Quantum Dots

Current Status and Challenges in Indium Phosphide Quantum Dots and Their Electroluminescence

Controlled Doping of Mn（Ⅱ） Ions in CsPbX₃ Perovskite Nanocrystals and Luminescence Properties

Color Conversion Characteristics of Micro-LED Based on Quantum Dot@Ordered Mesoporous Composite Materials

Related Author

WANG Xiu-ying

LIU Xue-yan

ZHAO Jia-long

ZHOU Ranfeng

PENG Maomin

LIU Li

YIN Xiaoli

PENG Xitian

Related Institution

State Key Laboratory of Luminescence and Applications, Changchun Institute of Optics, Fine Mechanics and Physics, Chinese Academy of Sciences, Changchun 130033, China

Hubei Key Laboratory of Nutritional Quality and Safety of Agro Products， Institute of Agricultural Quality Standards and Testing Technology Research， Hubei Academy of Agricultural Science

College of Life Science， Yangtze University

Key Laboratory of New Display Materials and Devices， Ministry of Industry and Information Technology， School of Materials Science and Engineering， Nanjing University of Science and Technology

College of Physical Science and Engineering Technology， Guangxi University

Address：No.3888 Dong Nanhu Road, Changchun, Jilin, China Postal code：130033
Tel：0431-86176862 Email：fgxbt@126.com
Technical support is provided by Beijing Founder electronics co., LTD 吉ICP备11002662号-17 京公网安备11010802024621
It is recommended to read the content of this site in Chrome&IE9+. Please switch to extreme mode in browser 360.
Cookies We use cookies to help provide and enhance our service and tailor content. By continuing, you agree to the use of cookies.

⁰