Design, Synthesis and Properties of D-&pi;-A-&pi;-D Type Organic Red Light Luminogens

JIA Jun-sen; WANG Fei; ZHAO Bo; YANG Jing-jing; YU Chun-yan; SUN Jing; WANG Hua; XU Bing-she

doi:10.3788/fgxb20204101.0009

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Design, Synthesis and Properties of D-π-A-π-D Type Organic Red Light Luminogens

Synthesis and Properties of Materials | 更新时间：2020-08-12

- Design, Synthesis and Properties of D-π-A-π-D Type Organic Red Light Luminogens
- Chinese Journal of Luminescence Vol. 41, Issue 1, Pages: 9-15(2020)
- 作者机构：
  
  1. 太原理工大学新材料界面科学与工程教育部重点实验室,山西太原,030024
  2. 南京邮电大学有机电子与信息显示国家重点实验室培育基地信息材料与纳米技术研究院,江苏南京,210046
  3. 太原理工大学材料科学与工程学院, 山西太原 030024
- 作者简介：
- 基金信息：
  
  Supported by Science and Technology Innovation Project of Colleges and Universities
- DOI：10.3788/fgxb20204101.0009
  CLC： TP394.1;TH691.9
- Received：06 August 2019，
  
  Revised：10 September 2019，
  
  Published Online：16 September 2019，
  
  Published：05 January 2020
- 稿件说明：
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贾钧森, 王飞, 赵波等. D-π-A-π-D型小分子红光材料的制备及其性能[J]. 发光学报, 2020,41(1): 9-15

JIA Jun-sen, WANG Fei, ZHAO Bo etc. Design, Synthesis and Properties of D-π-A-π-D Type Organic Red Light Luminogens[J]. Chinese Journal of Luminescence, 2020,41(1): 9-15
贾钧森, 王飞, 赵波等. D-π-A-π-D型小分子红光材料的制备及其性能[J]. 发光学报, 2020,41(1): 9-15 DOI： 10.3788/fgxb20204101.0009.

JIA Jun-sen, WANG Fei, ZHAO Bo etc. Design, Synthesis and Properties of D-π-A-π-D Type Organic Red Light Luminogens[J]. Chinese Journal of Luminescence, 2020,41(1): 9-15 DOI： 10.3788/fgxb20204101.0009.

摘要

开发新型有机红光材料对于制备高性能红光有机电致发光器件具有重要的研究意义。本文采用SUZUKI偶联反应，以芴酮为受体（A）、3，4，5-三甲氧基苯为给体（D）合成了新型D--A--D结构的有机红光材料（3MeFO）。通过

H NMR谱、

C NMR谱和X单晶衍射确认了分子结构，该化合物展示了较强的电荷转移作用和良好的共轭结构，其晶体的发射峰达到620 nm。从单晶结构中看出甲氧基的引入有利于在分子间形成大量的氢键，有效地增强了分子间的相互作用。同时，该材料表现出良好的热稳定性能和电化学性能，使得其在OLED中展示了良好的电致发光性能。

Abstract

To develop a novel red light luminescent material was important to prepare the high-efficiency organic light emitting devices. In this paper

a new kind of D--A--D red light luminogen utilizing fluorenone as acceptor and 3

5-trimethoxybenzene as donor was designed and synthesized

named 3MeFO. Its structure was confirmed by the

H NMR spectra

C NMR spectra and X-ray single crystal diffraction. The compound had strong charge transfer and -conjugated structure that contributed to the red shift and the PL peak of crystal was located at 620 nm. From the single crystal analysis

the introduction of methoxy groups had increased the intermolecular interaction owing to the formation of the hydrogen bond. Meanwhile

the compound exhibited excellent thermal stability properties

electrochemical performance that were benefit to prepare the OLED with the considerable electroluminescent properties.

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references

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太原理工大学材料科学与工程学院

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Design, Synthesis and Properties of D-π-A-π-D Type Organic Red Light Luminogens

DOI：10.3788/fgxb20204101.0009

摘要

Abstract

关键词

Keywords

references