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1.成都大学 机械工程学院, 四川 成都 610106
2.四川新亚无损检测有限公司, 四川 成都 610213
Received:20 April 2020,
Accepted:11 May 2020,
Published:2020-08
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Xiao-dong ZHU, Juan WANG, Yu-hao LUO, et al. Preparation and Photocatalytic Activity of Rutile-TiO2/ZnTiO3 Composite[J]. Chinese journal of luminescence, 2020, 41(8): 964-970.
Xiao-dong ZHU, Juan WANG, Yu-hao LUO, et al. Preparation and Photocatalytic Activity of Rutile-TiO2/ZnTiO3 Composite[J]. Chinese journal of luminescence, 2020, 41(8): 964-970. DOI: 10.37188/fgxb20204108.0964.
采用溶胶-凝胶法制备了金红石型TiO
2
/ZnTiO
3
复合光催化剂,对其进行650℃保温1 h的热处理;通过X射线衍射(XRD)、扫描电子显微镜(SEM)、X射线光电子能谱(XPS)、荧光光谱(PL)对样品进行表征,并以亚甲基蓝(MB)溶液为目标污染物,研究了样品的光催化性能。结果表明,TiO
2
为金红石结构,随着Zn/Ti量比增加,TiO
2
晶粒尺寸减小;当Zn/Ti的量比达到2%时,有新相ZnTiO
3
生成。TiO
2
/ZnTiO
3
(Zn/Ti=8%)展现出最高的光催化活性,这归因于表面羟基含量增加以及形成的TiO
2
/ZnTiO
3
半导体复合结构加快了光生电子与空穴的转移。反应进行90 min后,对MB的降解率达到68.3%,反应速率常数
k
为0.012 min
-1
,分别为纯TiO
2
的1.85倍和3倍。
The rutile-TiO
2
/ZnTiO
3
composite photocatalysts were synthesized by a sol-gel method
and were heat treated at 650℃ for 1 h. The obtained samples were characterized by X-ray diffraction(XRD)
scanning electron microscopy(SEM)
X-ray photoelectron spectroscopy(XPS) and photoluminescence spectra(PL). The photocatalytic performance of samples was studied taking the degradation of methylene blue(MB) as the target reactant. The results show that the crystal structure of TiO
2
is rutile phase and the grain size of TiO
2
decreases with the increasing Zn/Ti molar ratio. ZnTiO
3
forms when the Zn/Ti molar ratio reaches 2%. TiO
2
/ZnTiO
3
(Zn/Ti=8%) exhibits the highest photocatalytic activity
which can be attributed to the increase of surface hydroxyl content and the formation of TiO
2
/ZnTiO
3
semiconductor composite structure
accelerating the transfer of photogenerated electrons and holes. After 90 minutes of reaction
the degradation rate of MB by TiO
2
/ZnTiO
3
(Zn/Ti=8%) reaches 68.3% and the reaction rate constant
k
is 0.012 min
-1
which are 1.85 times and 3 times higher than that of pure TiO
2
.
TRAN H T T, KOSSLICK H, IBAD M F, et al .. Photocatalytic performance of highly active brookite in the degradation of hazardous organic compounds compared to anatase and rutile[J] . Appl. Catal . B Environ ., 2017, 200:647-658.
陈越, 何大伟, 王永生, 等.水热法制备二氧化钛纳米管-石墨烯复合光催化剂及其光催化性能[J].发光学报, 2019, 40(2):177-182.
CHEN Y, HE D W, WANG Y S, et al .. Hydrothermal synthesis of graphene-TiO 2 nanotube composites and study of photocatalytic properties[J]. Chin. J. Lumin ., 2019, 40(2):177-182. (in Chinese)
ZHU X D, HAN S H, ZHU D Z, et al .. Preparation and characterisation of Ag modified rutile titanium dioxide and its photocatalytic activity under simulated solar light[J]. Micro Nano Lett ., 2019, 14(7):757-760.
ZHANG Y, WANG T, ZHOU M, et al .. Hydrothermal preparation of Ag-TiO 2 nanostructures with exposed {001}/{101} facets for enhancing visible light photocatalytic activity[J]. Ceram. Int ., 2017, 44(3):3118-3126.
LI X B, XIONG J, HUANG J T, et al .. Novel g-C 3 N 4 /h'ZnTiO 3 -a'TiO 2 direct Z-scheme heterojunction with significantly enhanced visible-light photocatalytic activity[J]. J. Alloys Compd ., 2019, 774:768-778.
NIU J F, LU P, KANG M, et al .. P-doped TiO 2 with superior visible-light activity prepared by rapid microwave hydrothermal method[J]. Appl. Surf. Sci ., 2014, 319:99-106.
贾哲, 方向明, 高世勇, 等. PbSe/TiO 2 同轴异质结纳米管的制备及光催化性能[J].发光学报, 2020, 41(2):181-187.
JIA Z, FANG X M, GAO S Y, et al .. Fabrication and photocatalytic properties of PbSe/TiO 2 coaxial heterojunction nanotubes[J]. Chin. J. Lumin ., 2020, 41(2):181-187. (in Chinese)
WANG Y Z, WU Y S, YANG H, et al .. Doping TiO 2 with boron or/and cerium elements:effects on photocatalytic antimicrobial activity[J]. Vacuum , 2016, 131:58-64.
SALAZAR-VILLANUEVA M, CRUZ-LÓPEZ A, ZALDÍVAR-CADENA A A, et al .. Effect of the electronic state of Ti on M -doped TiO 2 nanoparticles ( M =Zn, Ga or Ge) with high photocatalytic activities:a experimental and DFT molecular study[J]. Mater. Sci. Semicon. Proc ., 2017, 58:8-14.
ANJU K R, THANKAPAN R, RAJABATHAR J R, et al .. Hydrothermal synthesis of nanosized (Fe, Co, Ni)-TiO 2 for enhanced visible light photosensitive applications[J]. Optik , 2018, 165:408-415.
KALANTARI K, KALBASI M, SOHRABI M, et al .. Enhancing the photocatalytic oxidation of dibenzothiophene using visible light responsive Fe and N co-doped TiO 2 nanoparticles[J]. Ceram. Int ., 2017, 43(1):973-981.
张进, 刘一鸣, 张王刚, 等. TiO 2 -ZnTiO 3 纳米复合薄膜的制备及光催化性能[J].人工晶体学报, 2015, 44(4):1003-1008.
ZHANG J, LIU Y M, ZHANG W G, et al .. Preparation and photocatalytic properties of TiO 2 -ZnTiO 3 nanocomposite thin films[J]. J. Synth. Cryst ., 2015, 44(4):1003-1008. (in Chinese)
HAN Z Y, ZHANG J C, YANG X Y, et al .. Synthesis and photoelectric property of poly(3-octylthiophene)/zinc oxide complexes[J]. Solar Energy Mater. Solar Cells , 2010, 94(2):194-200.
ADYANI S M, GHORBANI M. A comparative study of physicochemical and photocatalytic properties of visible light responsive Fe, Gd and P single and tri-doped TiO 2 nanomaterials[J]. J. Rare Earth , 2018, 36(1):72-85.
BENJWAL P, DE B, KAR K K. 1-D and 2-D morphology of metal cation co-doped (Zn, Mn) TiO 2 and investigation of their photocatalytic activity[J]. Appl. Surf. Sci ., 2018, 427:262-272.
冯黛丽, 冯妍卉, 袁思伟, 等.颗粒团聚对纳米尺度熔化行为的影响[J].工程热物理学报, 2015, 36(2):397-401.
FENG D L, FENG Y H, YUAN S W, et al .. Effect of nano particles clustering on the melting behavior[J]. J. Eng. Thermophys. , 2015, 36(2):397-401. (in Chinese)
WANG Y Z, XUE X X, YANG H. Modification of the antibacterial activity of Zn/TiO 2 nano-materials through different anions doped[J]. Vacuum , 2014, 101:193-199.
ZHANG Y, WANG L L, LIU B K, et al .. Synthesis of Zn-doped TiO 2 microspheres with enhanced photovoltaic performance and application for dye-sensitized solar cells[J]. Electrochim. Acta , 2011, 56(18):6517-6523.
DEMIRCI S, DIKICI T, YURDDASKAL M, et al .. Synthesis and characterization of Ag doped TiO 2 heterojunction films and their photocatalytic performances[J]. Appl. Surf. Sci ., 2016, 390:591-601.
LIU J M, HAN L, AN N, et al .. Enhanced visible-light photocatalytic activity of carbonate-doped anatase TiO 2 based on the electron-withdrawing bidentate carboxylate linkage[J]. Appl. Catal . B Environ ., 2017, 202:642-652.
JIANG H B, XING J, CHEN Z P, et al .. Enhancing photocatalytic activity of Sn doped TiO 2 dominated with {105} facets[J]. Catal. Today , 2014, 225:18-23.
CHEN Y, LIU K R. Fabrication of Ce/N co-doped TiO 2 /diatomite granule catalyst and its improved visible-light-driven photoactivity[J]. J. Hazard. Mater ., 2017, 324:139-150.
LI X Z, LI F B, YANG C L, et al .. Photocatalytic activity of WO x -TiO 2 under visible light irradiation[J]. J. Photoch. Photobiol . A Chem. , 2001, 141(2-3):209-217.
KE S J, CHENG X S, WANG Q H, et al .. Preparation of a photocatalytic TiO 2 /ZnTiO 3 coating on glazed ceramic tiles[J]. Ceram. Int ., 2014, 40(6):8891-8895.
田泽, 郑焘, 朱平武, 等.太阳光活性的ZnTiO 3 /TiO 2 纳米复合催化材料的制备及其表征[J].无机化学学报, 2012, 28(2):269-274.
TIAN Z, ZHENG T, ZHU P W, et al .. Preparation and characterization of sunlight-active ZnTiO 3 /TiO 2 nano-composite catalytic materials[J]. Chin. J. Inorg. Chem ., 2012, 28(2):269-274. (in Chinese)
徐艳, 张翁晶, 胡木林.用于钙钛矿太阳能电池光阳极的TiO 2 /ZnTiO 3 复合物的制备与性能[J].材料导报, 2016, 30(20):21-25.
XU Y, ZHANG W J, HU M L. Preparation and properties of TiO 2 /ZnTiO 3 Composites via a sol-gel route served as photoanode of perovskite solar cells[J]. Mater. Rev. , 2016, 30(20):21-25. (in Chinese)
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