One- and Two-photon Excited Photoluminescence of Cuprous Iodide Coordination Polymer

Shao-yun YIN; Jun-ting MO; Mei PAN

doi:10.37188/fgxb20204107.0782

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One- and Two-photon Excited Photoluminescence of Cuprous Iodide Coordination Polymer

Synthesis and Properties of Materials | 更新时间：2020-09-10

- One- and Two-photon Excited Photoluminescence of Cuprous Iodide Coordination Polymer
- Chinese Journal of Luminescence Vol. 41, Issue 7, Pages: 782-790(2020)
- 作者机构：
  
  1.中山大学化学学院, 广东广州 510275
  2.广东工业大学分析测试中心, 广东广州 510006
- 作者简介：
- 基金信息：
  
  National Natural Science Foundation of China;National Natural Science Foundation of
- DOI：10.37188/fgxb20204107.0782
  CLC： O641
- Published：2020-7，
  
  Received：20 April 2020，
  
  Accepted：3 May 2020
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Shao-yun YIN, Jun-ting MO, Mei PAN. One- and Two-photon Excited Photoluminescence of Cuprous Iodide Coordination Polymer. [J]. Chinese Journal of Luminescence 41(7):782-790(2020)
DOI：

Shao-yun YIN, Jun-ting MO, Mei PAN. One- and Two-photon Excited Photoluminescence of Cuprous Iodide Coordination Polymer. [J]. Chinese Journal of Luminescence 41(7):782-790(2020) DOI： 10.37188/fgxb20204107.0782.

摘要

利用两种半柔性的π-不饱和双吡啶端基配体与CuI配位，分别通过结构转化法和原位组装法，得到两种具有{[CuIL]·solvents}

结构通式的二维和三维碘化亚铜配位聚合物，分别命名为Cu-3和Cu-4。利用X射线单晶衍射、X射线粉末衍射和元素分析等表征方法确定了Cu-3和Cu-4的结构信息。研究这两种配位聚合物的光物理性能发现，用紫外光激发时，Cu-3和Cu-4均表现出单一发射峰，最大波长分别为513 nm的蓝绿光和555 nm的黄色光，归属于卤素到配体的电荷转移（

XLCT）。同时，这两种配位聚合物均表现出双光子激发发光性质，有望应用于生物成像领域。

Abstract

Through structural transition method or

in-situ

assembly method

two semi-flexible π-conjugated unsaturated bipodal-ligands were coordinated with CuI to obtain 2-D or 3-D cuprous iodide coordination polymerizations with the general structure of {[CuIL]·solvents}

namely Cu-3 and Cu-4

respectively. The structural information of Cu-3 and Cu-4 was determined by X-ray single crystal diffraction

powder X-ray diffraction and elemental analysis. Studying the photophysical properties of these two coordination polymers revealed that when excited by ultraviolet light

Cu-3 and Cu-4 showed a single emission peak with blue-green light at 513 nm and yellow light at 555 nm

respectively

which were attributed to halogen to ligand charge transfer (

XLCT) state. At the same time

these two coordination polymers both exhibit two-photon excited luminescence properties

and are expected to be used in the field of biological imaging.

关键词

碘化亚铜配位聚合物卤素到配体电荷转移双光子发光

Keywords

cuprous iodidecoordination polymerXLCTtwo-photon luminescence

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