One- and Two-photon Excited Photoluminescence of Cuprous Iodide Coordination Polymer

Shao-yun YIN; Jun-ting MO; Mei PAN

doi:10.37188/fgxb20204107.0782

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One- and Two-photon Excited Photoluminescence of Cuprous Iodide Coordination Polymer

Synthesis and Properties of Materials | 更新时间：2020-09-10

- One- and Two-photon Excited Photoluminescence of Cuprous Iodide Coordination Polymer
- Chinese Journal of Luminescence Vol. 41, Issue 7, Pages: 782-790(2020)
- 作者机构：
  
  1.中山大学化学学院, 广东广州 510275
  2.广东工业大学分析测试中心, 广东广州 510006
- 作者简介：
- 基金信息：
  
  National Natural Science Foundation of China;National Natural Science Foundation of
- DOI：10.37188/fgxb20204107.0782
  CLC：
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Shao-yun YIN, Jun-ting MO, Mei PAN. One- and Two-photon Excited Photoluminescence of Cuprous Iodide Coordination Polymer. [J]. Chinese Journal of Luminescence 41(7):782-790(2020)
DOI：

Shao-yun YIN, Jun-ting MO, Mei PAN. One- and Two-photon Excited Photoluminescence of Cuprous Iodide Coordination Polymer. [J]. Chinese Journal of Luminescence 41(7):782-790(2020) DOI： 10.37188/fgxb20204107.0782.

摘要

利用两种半柔性的π-不饱和双吡啶端基配体与CuI配位，分别通过结构转化法和原位组装法，得到两种具有{[CuIL]·solvents},n,结构通式的二维和三维碘化亚铜配位聚合物，分别命名为Cu-3和Cu-4。利用X射线单晶衍射、X射线粉末衍射和元素分析等表征方法确定了Cu-3和Cu-4的结构信息。研究这两种配位聚合物的光物理性能发现，用紫外光激发时，Cu-3和Cu-4均表现出单一发射峰，最大波长分别为513 nm的蓝绿光和555 nm的黄色光，归属于卤素到配体的电荷转移（,3,XLCT）。同时，这两种配位聚合物均表现出双光子激发发光性质，有望应用于生物成像领域。

Abstract

Through structural transition method or ,in-situ, assembly method, two semi-flexible π-conjugated unsaturated bipodal-ligands were coordinated with CuI to obtain 2-D or 3-D cuprous iodide coordination polymerizations with the general structure of {[CuIL]·solvents},n, namely Cu-3 and Cu-4, respectively. The structural information of Cu-3 and Cu-4 was determined by X-ray single crystal diffraction, powder X-ray diffraction and elemental analysis. Studying the photophysical properties of these two coordination polymers revealed that when excited by ultraviolet light, Cu-3 and Cu-4 showed a single emission peak with blue-green light at 513 nm and yellow light at 555 nm, respectively, which were attributed to halogen to ligand charge transfer (,3,XLCT) state. At the same time, these two coordination polymers both exhibit two-photon excited luminescence properties, and are expected to be used in the field of biological imaging.

关键词

碘化亚铜配位聚合物卤素到配体电荷转移双光子发光

Keywords

cuprous iodidecoordination polymerXLCTtwo-photon luminescence

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