Luminescence Properties of Ce3+-Cr3+ co-Doped Ba3Sc4O9 Phosphors

Wen Haiyang; Zhang Chenjie; Zhou Tianliang; Xie Rong-Jun

doi:10.37188/CJL.20230225

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Luminescence Properties of Ce³⁺-Cr³⁺ co-Doped Ba₃Sc₄O₉ Phosphors

更新时间：2023-11-07

- Luminescence Properties of Ce³⁺-Cr³⁺ co-Doped Ba₃Sc₄O₉ Phosphors
  增强出版
- Chinese Journal of Luminescence Pages: 1-9(2023)
- 作者机构：
  
  1.厦门大学材料学院，福建厦门　361005
  2.厦门大学固体表面物理化学国家重点实验室，福建厦门　361005
- 作者简介：
- 基金信息：
  
  Fujian Provincial Natural Science Foundation(2021J01042);National Natural Science Foundation of China(52172157)
- DOI：10.37188/CJL.20230225
  CLC：
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温海洋,张晨杰,周天亮等.Ce³⁺-Cr³⁺共掺杂Ba₃Sc₄O₉荧光材料的发光性能[J].发光学报,

Wen Haiyang,Zhang Chenjie,Zhou Tianliang,et al.Luminescence Properties of Ce³⁺-Cr³⁺ co-Doped Ba₃Sc₄O₉ Phosphors[J].Chinese Journal of Luminescence,
温海洋,张晨杰,周天亮等.Ce³⁺-Cr³⁺共掺杂Ba₃Sc₄O₉荧光材料的发光性能[J].发光学报, DOI：10.37188/CJL.20230225

Wen Haiyang,Zhang Chenjie,Zhou Tianliang,et al.Luminescence Properties of Ce³⁺-Cr³⁺ co-Doped Ba₃Sc₄O₉ Phosphors[J].Chinese Journal of Luminescence, DOI：10.37188/CJL.20230225

摘要

红光-近红外光谱技术在医疗领域具有广泛的应用。但对于当下采用蓝光LED激发荧光材料实现红光-近红外光谱输出的器件结构而言，则普遍存在蓝光过剩的问题。本文提出了通过构筑Ce,3+,→Cr,3+,能量传递，从而实现抑制器件蓝光输出的策略。以Ba,3,Sc,4,O,9,为研究对象，采用Ce,3+,/Cr,3+,共掺杂，研究了其发光性能。结果表明，共掺杂的Ba,3,Sc,4,O,9,：Ce,3+,/Cr,3+,同时具备了红光和近红外光发射能力，发射主峰分别位于585 nm和835 nm；Ce,3+,→Cr,3+,能量传递效率达50.92%。所封装的近红外LED器件的蓝光强度下降了78%，而Cr,3+,的发射强度增至181%。

Abstract

The red-near-infrared spectrum is widely used in many fields such as medical treatments. However， there is an excess of blue luminescence caused by red-near-infrared device excited by 450 nm LEDs. In this work， we proposed to construct the Ce,3+,→Cr,3+, energy transfer to suppress the blue emission from the lighting devices. The Ce,3+,/Cr,3+, co-doped Ba,3,Sc,4,O,9 ,phosphors,were prepared and their photoluminescence were investigated. The Ba,3,Sc,4,O,9,：Ce,3+,/Cr,3+, phosphors exhibit double emission bands centered at 585 nm and 835 nm， respectively. The blue emission remained in the prepared LED device is reduced by 78%， and the emission intensity of Cr,3+, is increased up to 181% due to the energy transfer efficiency as high as 50.92% between Ce,3+, and Cr,3+,.

关键词

近红外Ce3+/Cr3+共掺杂Ba3Sc4O9能量传递

Keywords

near-infraredCe3+/Cr3+ co-dopedBa3Sc4O9energy transfer

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College of Physics Science & Technology, Hebei University

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College of Physics Science & Technology， Hebei University

Key Laboratory for Liquid-solid Structural Evolution and Processing of Materials （Ministry of Education）， School of Material Science and Engineering， Shandong University

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