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1.泉州师范学院物理与信息工程学院 福建省先进微纳光子技术与器件重点实验室, 福建 泉州 362000
2.福州大学 先进制造学院, 福建 泉州 362200
3.福建师范大学 光电与信息工程学院, 福建 福州 350117
Published:05 November 2023,
Received:30 August 2023,
Revised:14 September 2023,
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姚广平,文超,刘佳澎等.缺陷对全无机钙钛矿太阳能电池性能的影响[J].发光学报,2023,44(11):2033-2040.
YAO Guangping,WEN Chao,LIU Jiapeng,et al.Effect of Defects on Performance of All Inorganic Perovskite Solar Cells[J].Chinese Journal of Luminescence,2023,44(11):2033-2040.
姚广平,文超,刘佳澎等.缺陷对全无机钙钛矿太阳能电池性能的影响[J].发光学报,2023,44(11):2033-2040. DOI: 10.37188/CJL.20230196.
YAO Guangping,WEN Chao,LIU Jiapeng,et al.Effect of Defects on Performance of All Inorganic Perovskite Solar Cells[J].Chinese Journal of Luminescence,2023,44(11):2033-2040. DOI: 10.37188/CJL.20230196.
利用一维太阳能电池仿真软件SCAPS对全无机钙钛矿太阳能电池中缺陷对器件性能的影响进行了研究。研究表明,在ITO/SnO
2
/CsPbI
3
/CuI/Au电池中,CuI/CsPbI
3
界面和CsPbI
3
光活性层缺陷密度对器件的性能具有较大影响。随着缺陷密度增大,器件的开路电压、短路电流、填充因子和光电转化效率均减小,尤其是当缺陷密度大于10
15
cm
-3
后,器件性能显著下降。相反地,CsPbI
3
/SnO
2
界面缺陷对器件性能无显著影响。通过优化器件的缺陷密度、光活性层的厚度和受主掺杂浓度,全无机钙钛矿太阳能电池的光电转化效率可以达到20%以上。
The effects of defects on the performance of all inorganic perovskite solar cells was studied using a one-dimensional solar cell simulation software SCAPS. It is found that in the device ITO/SnO
2
/CsPbI
3
/CuI/Au, the density of the defects at the CuI/CsPbI
3
interface and in the CsPbI
3
photoactive layer has dramatically influence on the performance of the device. With the increase of the defect density, the open-circuit voltage, short-circuit current, filling factor, and power conversion efficiency of the device all decrease, especially when the defect density exceeds 10
15
cm
-3
. On the contrary, the defects at the CsPbI
3
/SnO
2
interface have almost no effect on device performance. By optimizing the defect density of the device, the thickness and doping concentration of the photoactive layer, a power conversion efficiency higher than 20% can be obtained in the all inorganic perovskite solar cells.
钙钛矿太阳能电池全无机缺陷仿真
perovskite solar cellall inorganicdefectsimulation
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