Effect of Defects on Performance of All Inorganic Perovskite Solar Cells

YAO Guangping; WEN Chao; LIU Jiapeng; SU Zisheng

doi:10.37188/CJL.20230196

您当前的位置：

首页 >

文章列表页 >

Effect of Defects on Performance of All Inorganic Perovskite Solar Cells

Device Fabrication and Physics | 更新时间：2023-11-27

- Effect of Defects on Performance of All Inorganic Perovskite Solar Cells
  增强出版
- Chinese Journal of Luminescence Vol. 44, Issue 11, Pages: 2033-2040(2023)
- 作者机构：
  
  1.泉州师范学院物理与信息工程学院福建省先进微纳光子技术与器件重点实验室，福建泉州　362000
  2.福州大学先进制造学院，福建泉州　362200
  3.福建师范大学光电与信息工程学院，福建福州　350117
- 作者简介：
- 基金信息：
  
  Youth Research Project of Fujian Provincial Department of Education(JAT200567);Natural Science Foundation of Fujian Province(2023J01890);Quanzhou City Science and Technology Program of China(2020C025R)
- DOI：10.37188/CJL.20230196
  CLC： O475.31;O482.7;TM914.4
- Published：05 November 2023，
  
  Received：30 August 2023，
  
  Revised：14 September 2023，
扫描看全文
姚广平,文超,刘佳澎等.缺陷对全无机钙钛矿太阳能电池性能的影响[J].发光学报,2023,44(11):2033-2040.

YAO Guangping,WEN Chao,LIU Jiapeng,et al.Effect of Defects on Performance of All Inorganic Perovskite Solar Cells[J].Chinese Journal of Luminescence,2023,44(11):2033-2040.
姚广平,文超,刘佳澎等.缺陷对全无机钙钛矿太阳能电池性能的影响[J].发光学报,2023,44(11):2033-2040. DOI： 10.37188/CJL.20230196.

YAO Guangping,WEN Chao,LIU Jiapeng,et al.Effect of Defects on Performance of All Inorganic Perovskite Solar Cells[J].Chinese Journal of Luminescence,2023,44(11):2033-2040. DOI： 10.37188/CJL.20230196.

摘要

利用一维太阳能电池仿真软件SCAPS对全无机钙钛矿太阳能电池中缺陷对器件性能的影响进行了研究。研究表明，在ITO/SnO

/CsPbI

/CuI/Au电池中，CuI/CsPbI

界面和CsPbI

光活性层缺陷密度对器件的性能具有较大影响。随着缺陷密度增大，器件的开路电压、短路电流、填充因子和光电转化效率均减小，尤其是当缺陷密度大于10

-3

后，器件性能显著下降。相反地，CsPbI

/SnO

界面缺陷对器件性能无显著影响。通过优化器件的缺陷密度、光活性层的厚度和受主掺杂浓度，全无机钙钛矿太阳能电池的光电转化效率可以达到20%以上。

Abstract

The effects of defects on the performance of all inorganic perovskite solar cells was studied using a one-dimensional solar cell simulation software SCAPS. It is found that in the device ITO/SnO

/CsPbI

/CuI/Au， the density of the defects at the CuI/CsPbI

interface and in the CsPbI

photoactive layer has dramatically influence on the performance of the device. With the increase of the defect density， the open-circuit voltage， short-circuit current， filling factor， and power conversion efficiency of the device all decrease， especially when the defect density exceeds 10

-3

. On the contrary， the defects at the CsPbI

/SnO

interface have almost no effect on device performance. By optimizing the defect density of the device， the thickness and doping concentration of the photoactive layer， a power conversion efficiency higher than 20% can be obtained in the all inorganic perovskite solar cells.

关键词

钙钛矿太阳能电池全无机缺陷仿真

Keywords

perovskite solar cellall inorganicdefectsimulation

references

KOJIMA A， TESHIMA K， SHIRAI Y， et al. Organometal halide perovskites as visible-light sensitizers for photovoltaic cells ［J］. J. Am. Chem. Soc.， 2009， 131（17）： 6050-6051. doi: 10.1021/ja809598rhttp://dx.doi.org/10.1021/ja809598r

ZHAO Y， MA F， QU Z H， et al. Inactive （PbI2）2RbCl stabilizes perovskite films for efficient solar cells ［J］. Science， 2022， 377（6605）： 531-534. doi: 10.1126/science.abp8873http://dx.doi.org/10.1126/science.abp8873

YOO J J， SEO G， CHUA M R， et al. Efficient perovskite solar cells via improved carrier management ［J］. Nature， 2021， 590（7847）： 587-593. doi: 10.1038/s41586-021-03285-whttp://dx.doi.org/10.1038/s41586-021-03285-w

JEONG J， KIM M， SEO J， et al. Pseudo-halide anion engineering for α-FAPbI3 perovskite solar cells ［J］. Nature， 2021， 592（7854）： 381-385. doi: 10.1038/s41586-021-03406-5http://dx.doi.org/10.1038/s41586-021-03406-5

LI Z， LI B， WU X， et al. Organometallic-functionalized interfaces for highly efficient inverted perovskite solar cells ［J］. Science， 2022， 376（6591）： 416-420. doi: 10.1126/science.abm8566http://dx.doi.org/10.1126/science.abm8566

MIN H， LEE D Y， KIM J， et al. Perovskite solar cells with atomically coherent interlayers on SnO2 electrodes ［J］. Nature， 2021， 598（7881）： 444-450. doi: 10.1038/s41586-021-03964-8http://dx.doi.org/10.1038/s41586-021-03964-8

JIANG Q， TONG J H， XIAN Y M， et al. Surface reaction for efficient and stable inverted perovskite solar cells ［J］. Nature， 2022， 611（7935）： 278-283. doi: 10.1038/s41586-022-05268-xhttp://dx.doi.org/10.1038/s41586-022-05268-x

NREL. Interactive best research-cell efficiency chart ［EB/OL］. ［2023-08-15］. https：//www.nrel.gov/pv/interactive-cell-efficiency.htmlhttps://www.nrel.gov/pv/interactive-cell-efficiency.html. doi: 10.2172/6700http://dx.doi.org/10.2172/6700

WANG R， MUJAHID M， DUAN Y， et al. A review of perovskites solar cell stability ［J］. Adv. Funct. Mater.， 2019， 29（47）： 1808843. doi: 10.1002/adfm.201808843http://dx.doi.org/10.1002/adfm.201808843

NAZIR G， LEE S Y， LEE J H， et al. Stabilization of perovskite solar cells： recent developments and future perspectives ［J］. Adv. Mater.， 2022， 34（50）： 2204380. doi: 10.1002/adma.202204380http://dx.doi.org/10.1002/adma.202204380

刘鲲鹏，刘德烨，刘凤敏. 全无机钙钛矿太阳能电池湿度稳定性和光热稳定性研究进展［J］. 发光学报， 2021， 42（4）： 486-503. doi: 10.37188/CJL.20200343http://dx.doi.org/10.37188/CJL.20200343

LIU K P， LIU D Y， LIU F M. Research progress in humidity stability and light-thermal stability of all-inorganic perovskite solar cells ［J］. Chin. J. Lumin.， 2021， 42（4）： 486-503. （in Chinese）. doi: 10.37188/CJL.20200343http://dx.doi.org/10.37188/CJL.20200343

EPERON G E， PATERNÒ G M， SUTTON R J， et al. Inorganic caesium lead iodide perovskite solar cells ［J］. J. Mater. Chem. A， 2015， 3（39）： 19688-19695. doi: 10.1039/c5ta06398ahttp://dx.doi.org/10.1039/c5ta06398a

TAN S， TAN C Y， CUI Y Q， et al. Constructing an interfacial gradient heterostructure enables efficient CsPbI3 perovskite solar cells and printed minimodules ［J］. Adv. Mater.， 2023， 35（28）： 2301879. doi: 10.1002/adma.202301879http://dx.doi.org/10.1002/adma.202301879

MALI S S， PATIL J V， SHAO J Y， et al. Phase-heterojunction all-inorganic perovskite solar cells surpassing 21.5% efficiency ［J］. Nat. Energy， 2023， 8（9）： 989-1001. doi: 10.1038/s41560-023-01310-yhttp://dx.doi.org/10.1038/s41560-023-01310-y

HAWASH Z， ONO L K， RAGA S R， et al. Air-exposure induced dopant redistribution and energy level shifts in spin-coated spiro-meOTAD films ［J］. Chem. Mater.， 2015， 27（2）： 562-569. doi: 10.1021/cm504022qhttp://dx.doi.org/10.1021/cm504022q

LIU X， ZHENG B L， SHI L， et al. Perovskite solar cells based on spiro-OMeTAD stabilized with an alkylthiol additive ［J］. Nat. Photonics， 2023， 17（1）： 96-105. doi: 10.1038/s41566-022-01111-xhttp://dx.doi.org/10.1038/s41566-022-01111-x

PENG Y， YAACOBI-GROSS N， PERUMAL A K， et al. Efficient organic solar cells using copper（I） iodide （CuI） hole transport layers ［J］. Appl. Phys. Lett.， 2015， 106（24）： 243302. doi: 10.1063/1.4922758http://dx.doi.org/10.1063/1.4922758

CHRISTIANS J A， FUNG R C M， KAMAT P V. An inorganic hole conductor for organo-lead halide perovskite solar cells. Improved hole conductivity with copper iodide ［J］. J. Am. Chem. Soc.， 2014， 136（2）： 758-764. doi: 10.1021/ja411014khttp://dx.doi.org/10.1021/ja411014k

ZHANG J X， ZHANG G Z， SU P Y， et al. 1D choline-PbI3-based heterostructure boosts efficiency and stability of CsPbI3 perovskite solar cells ［J］. Angew. Chem. Int. Ed.， 2023， 62（25）： e202303486. doi: 10.1002/anie.202303486http://dx.doi.org/10.1002/anie.202303486

CHEN W T， ZHANG S S， LIU Z H， et al. A tailored nickel oxide hole-transporting layer to improve the long-term thermal stability of inorganic perovskite solar cells ［J］. Sol. RRL， 2019， 3（11）： 1900346. doi: 10.1002/solr.201900346http://dx.doi.org/10.1002/solr.201900346

LIN L Y， JIANG L Q， LI P， et al. Simulated development and optimized performance of CsPbI3 based all-inorganic perovskite solar cells ［J］. Sol. Energy， 2020， 198： 454-460. doi: 10.1016/j.solener.2020.01.081http://dx.doi.org/10.1016/j.solener.2020.01.081

SHEN H， LI X K， ZHANG X， et al. Constructing gradient structure to increase efficiency for carbon-based hole transport layer free all-inorganic perovskite solar cells using SCAPS-1D ［J］. Sol. Energy， 2023， 253： 240-249. doi: 10.1016/j.solener.2023.02.037http://dx.doi.org/10.1016/j.solener.2023.02.037

BANSAL N K， PORWAL S， DIXIT H， et al. A theoretical study to investigate the impact of bilayer interfacial modification in perovskite solar cell ［J］. Energy Technol.， 2023， 11（4）： 2201395. doi: 10.1002/ente.202201395http://dx.doi.org/10.1002/ente.202201395

ISLAM M A， AKHTARUZZAMAN M， MOTTAKIN M， et al. Potential-induced performance degradation （PID） applied on a perovskite solar cell： exploring its effect on cell performance through numerical simulation ［J］. J. Electron. Mater.， 2023， 52（5）： 3205-3218. doi: 10.1007/s11664-023-10284-2http://dx.doi.org/10.1007/s11664-023-10284-2

QIN Z W， ZHOU H， LI S T， et al. CsPbI3 based all-inorganic perovskite solar cells： further performance enhancement of the electron transport layer-free structure from device simulation ［J］. Adv. Theory Simul.， 2023， 6（8）： 2200805. doi: 10.1002/adts.202200805http://dx.doi.org/10.1002/adts.202200805

HUANG Y， YIN W J， HE Y. Intrinsic point defects in inorganic cesium lead iodide perovskite CsPbI3 ［J］. J. Phys. Chem. C， 2018， 122（2）： 1345-1350. doi: 10.1021/acs.jpcc.7b10045http://dx.doi.org/10.1021/acs.jpcc.7b10045

BURGELMAN M， NOLLET P， DEGRAVE S. Modelling polycrystalline semiconductor solar cells ［J］. Thin Solid Films， 2000， 361-362： 527-532. doi: 10.1016/s0040-6090(99)00825-1http://dx.doi.org/10.1016/s0040-6090(99)00825-1

DENG Q R， LI Y Q， CHEN L A， et al. The effects of electron and hole transport layer with the electrode work function on perovskite solar cells ［J］. Mod. Phys. Lett. B， 2016， 30（27）： 1650341. doi: 10.1142/s0217984916503413http://dx.doi.org/10.1142/s0217984916503413

AZRI F， MEFTAH A， SENGOUGA N， et al. Electron and hole transport layers optimization by numerical simulation of a perovskite solar cell ［J］. Sol. Energy， 2019， 181： 372-378. doi: 10.1016/j.solener.2019.02.017http://dx.doi.org/10.1016/j.solener.2019.02.017

DASTIDAR S， LI S M， SMOLIN S Y， et al. Slow electron-hole recombination in lead iodide perovskites does not require a molecular dipole ［J］. ACS Energy Lett.， 2017， 2（10）： 2239-2244. doi: 10.1021/acsenergylett.7b00606http://dx.doi.org/10.1021/acsenergylett.7b00606

WANG P Y， ZHANG X W， ZHOU Y Q， et al. Solvent-controlled growth of inorganic perovskite films in dry environment for efficient and stable solar cells ［J］. Nat. Commun.， 2018， 9（1）： 2225. doi: 10.1038/s41467-018-04636-4http://dx.doi.org/10.1038/s41467-018-04636-4

HUTTER E M， SAVENIJE T J. Thermally activated second-order recombination hints toward indirect recombination in fully inorganic CsPbI3 perovskites ［J］. ACS Energy Lett.， 2018， 3（9）： 2068-2069. doi: 10.1021/acsenergylett.8b01106http://dx.doi.org/10.1021/acsenergylett.8b01106

HOSSAIN M I， ALHARBI F H， TABET N. Copper oxide as inorganic hole transport material for lead halide perovskite based solar cells ［J］. Sol. Energy， 2015， 120： 370-380. doi: 10.1016/j.solener.2015.07.040http://dx.doi.org/10.1016/j.solener.2015.07.040

KANOUN A A， KANOUN M B， MERAD A E， et al. Toward development of high-performance perovskite solar cells based on CH3NH3GeI3 using computational approach ［J］. Sol. Energy， 2019， 182： 237-244. doi: 10.1016/j.solener.2019.02.041http://dx.doi.org/10.1016/j.solener.2019.02.041

HU Y Q， BAI F， LIU X B， et al. Bismuth incorporation stabilized α-CsPbI3 for fully inorganic perovskite solar cells ［J］. ACS Energy Lett.， 2017， 2（10）： 2219-2227. doi: 10.1021/acsenergylett.7b00508http://dx.doi.org/10.1021/acsenergylett.7b00508

TAN K， LIN P， WANG G， et al. Controllable design of solid-state perovskite solar cells by SCAPS device simulation ［J］. Solid⁃State Electron.， 2016， 126： 75-80. doi: 10.1016/j.sse.2016.09.012http://dx.doi.org/10.1016/j.sse.2016.09.012

HUANG L K， SUN X X， LI C， et al. Electron transport layer-free planar perovskite solar cells： further performance enhancement perspective from device simulation ［J］. Sol. Energy Mater. Sol. Cells， 2016， 157： 1038-1047. doi: 10.1016/j.solmat.2016.08.025http://dx.doi.org/10.1016/j.solmat.2016.08.025

张康杰，闫伟博，辛颢. 苯乙胺钝化钙钛矿埋底界面提高太阳能电池性能［J］. 发光学报， 2023， 44（9）： 1636-1643.

ZHANG K J， YAN W B， XIN H. Passivation of perovskite buried-interface using phenethylamine for enhanced solar cell performance ［J］. Chin. J. Lumin.， 2023， 44（9）： 1636-1643. （in Chinese）

邹宇，李昭，陈衡慧，等. NaTFSI界面修饰对平面TiO2基钙钛矿太阳能电池的影响［J］. 发光学报， 2021， 42（5）： 682-690. doi: 10.37188/cjl.20210045http://dx.doi.org/10.37188/cjl.20210045

ZOU Y， LI Z， CHEN H H， et al. Effect of interfacial modification for TiO2-based planar perovskite solar cells using NaTFSI ［J］. Chin. J. Lumin.， 2021， 42（5）： 682-690. （in Chinese）. doi: 10.37188/cjl.20210045http://dx.doi.org/10.37188/cjl.20210045

GAO Z W， WANG Y， CHOY W C H. Buried interface modification in perovskite solar cells： a materials perspective ［J］. Adv. Energy Mater.， 2022， 12（20）： 2104030. doi: 10.1002/aenm.202104030http://dx.doi.org/10.1002/aenm.202104030

ZHANG C C， YUAN S， LOU Y H， et al. Perovskite films with reduced interfacial strains via a molecular-level flexible interlayer for photovoltaic application ［J］. Adv. Mater.， 2020， 32（38）： 2001479. doi: 10.1002/adma.202001479http://dx.doi.org/10.1002/adma.202001479

CHEN B， CHEN H， HOU Y， et al. Passivation of the buried interface via preferential crystallization of 2D perovskite on metal oxide transport layers ［J］. Adv. Mater.， 2021， 33（41）： 2103394. doi: 10.1002/adma.202103394http://dx.doi.org/10.1002/adma.202103394

ZHENG Z H， LI F M， GONG J， et al. Pre-buried additive for cross-layer modification in flexible perovskite solar cells with efficiency exceeding 22% ［J］. Adv. Mater.， 2022， 34（21）： 2109879. doi: 10.1002/adma.202109879http://dx.doi.org/10.1002/adma.202109879

Views

203

下载量

CSCD

Alert me when the article has been cited

提交

Tools

Publicity Resources

Flexible Perovskite Photovoltaics: Progress, Commercialization and Prospects

Research Progress on Electrode Materials and Charge Transport Materials in Flexible Perovskite Solar Cells

Effect of Viscosity on Droplet Volume During Inkjet Printing

Crosstalk Simulation of LED Autostereoscopic Display Based on TracePro Software

Related Author

YAO Guang-ping

WEN Chao

LIU Jia-peng

SU Zi-Sheng

LI Manya

LI Ludong

LIU Zhou

TAN Hairen

Related Institution

College of Physics and Information Engineering， Fujian Key Laboratory for Advanced Micro-nano Photonics Technology and Devices， Quanzhou Normal University

School of Engineering and Applied Sciences， Nanjing University

State Key Laboratory on Integrated Optoelectronics, College of Electronic Science and Engineering, Jilin University

Department of Chemistry, Physics and Atmospheric Sciences, Jackson State University

School of Material Science and Engineering, Hebei University of Technology

Address：No.3888 Dong Nanhu Road, Changchun, Jilin, China Postal code：130033
Tel：0431-86176862 Email：fgxbt@126.com
Technical support is provided by Beijing Founder electronics co., LTD 吉ICP备11002662号-17 京公网安备11010802024621
It is recommended to read the content of this site in Chrome&IE9+. Please switch to extreme mode in browser 360.
Cookies We use cookies to help provide and enhance our service and tailor content. By continuing, you agree to the use of cookies.

⁰