Preparation and Sensing Detection Application of Lanthanide Eu<sup>3+</sup>/PMMA Polymer Hybrid Probe

MIN Hua; LIU Li; XIA Jiji; XU Chen; TANG Siyi; LI Ying

doi:10.37188/CJL.20230179

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Preparation and Sensing Detection Application of Lanthanide Eu³⁺/PMMA Polymer Hybrid Probe

Luminescence Applications and Interdisciplinary Fields | 更新时间：2023-11-27

- Preparation and Sensing Detection Application of Lanthanide Eu³⁺/PMMA Polymer Hybrid Probe
  增强出版
- Chinese Journal of Luminescence Vol. 44, Issue 11, Pages: 2076-2080(2023)
- 作者机构：
  
  1.上海理工大学科技发展研究院技术转移中心，上海　200093
  2.上海理工大学材料与化学学院，上海　200093
- 作者简介：
- 基金信息：
  
  National Natural Science Foundation of China(21101107;51173107);State Key Laboratory of Pollution Control and Resource Reuse Foundation(PCRRF19017)
- DOI：10.37188/CJL.20230179
  CLC： O482.31
- Published：05 November 2023，
  
  Received：30 July 2023，
  
  Revised：17 August 2023，
- 稿件说明：
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闵华,刘丽,夏继绩等.镧系Eu³⁺/PMMA聚合物杂化探针的制备及其对唾液酸的传感检测应用[J].发光学报,2023,44(11):2076-2080.

MIN Hua,LIU Li,XIA Jiji,et al.Preparation and Sensing Detection Application of Lanthanide Eu³⁺/PMMA Polymer Hybrid Probe[J].Chinese Journal of Luminescence,2023,44(11):2076-2080.
闵华,刘丽,夏继绩等.镧系Eu³⁺/PMMA聚合物杂化探针的制备及其对唾液酸的传感检测应用[J].发光学报,2023,44(11):2076-2080. DOI： 10.37188/CJL.20230179.

MIN Hua,LIU Li,XIA Jiji,et al.Preparation and Sensing Detection Application of Lanthanide Eu³⁺/PMMA Polymer Hybrid Probe[J].Chinese Journal of Luminescence,2023,44(11):2076-2080. DOI： 10.37188/CJL.20230179.

摘要

设计合成了一种Eu

离子功能化的聚合物基稀土杂化探针。利用苯甲酰三氟丙酮（BFA）与镧系Eu

进行配位反应得到配合物Eu（BFA）

后再进一步与MMA单体进行聚合制备得到聚合物杂化探针分子Eu⁃（BFA）

@PMMA，对Eu（BFA）

@PMMA的结构和荧光性能进行了详细的探究，并且将其用于肿瘤标志物唾液酸（SA）的传感检测应用。研究结果表明，SA能对Eu（BFA）

@PMMA的荧光产生明显的猝灭效果。此外，在最佳激发波长为325 nm时进行荧光性能对比实验发现Eu（BFA）

@PMMA对SA具有较强的选择性和抗干扰能力，且检出限较低。

Abstract

In this paper， a polymer-based rare earth hybrid probe functionalized by Eu

was designed and synthesized. The coordination reaction between benzoyl trifluoroacetone （BFA） and lanthanide Eu

was used to obtain the complex Eu（BFA）

， which was further prepared by polymerization with MMA monomer to obtain polymer hybrid probe Eu（BFA）

@PMMA. The structure and fluorescence properties of Eu（BFA）

@PMMA were investigated in detail. It is also used in the sensor detection of tumor marker sialic acid （SA）. The results showed that SA can produce a significant quenching effect on the fluorescence of Eu（BFA）

@PMMA. In addition， fluorescence properties contrast experiments at excitation wavelength of 325 nm showed that Eu（BFA）

@PMMA had strong selectivity and anti-interference ability for SA， and the detection limit was low.

关键词

镧系配合物杂化探针唾液酸荧光传感

Keywords

lanthanide complexeshybrid probessialic acidfluorescence sensing

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Related Institution

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⁰

Preparation and Sensing Detection Application of Lanthanide Eu3+/PMMA Polymer Hybrid Probe

DOI：10.37188/CJL.20230179

摘要

Abstract

关键词

Keywords

references

Preparation and Sensing Detection Application of Lanthanide Eu³⁺/PMMA Polymer Hybrid Probe