Up-conversion Luminescence and Temperature Sensing Performance of Novel Ba3In（PO4）3∶Yb3+, Ho3+ Phosphor

GAO Huabo; CHEN Qi; CHEN Wenchao; MIN Xin; MA Bin

doi:10.37188/CJL.20230175

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Up-conversion Luminescence and Temperature Sensing Performance of Novel Ba₃In（PO₄）₃∶Yb³⁺, Ho³⁺ Phosphor

Synthesis and Properties of Materials | 更新时间：2023-11-27

- Up-conversion Luminescence and Temperature Sensing Performance of Novel Ba₃In（PO₄）₃∶Yb³⁺, Ho³⁺ Phosphor
  增强出版
- Chinese Journal of Luminescence Vol. 44, Issue 11, Pages: 1958-1966(2023)
- 作者机构：
  
  1.青海大学机械工程学院，青海西宁　810016
  2.中国地质大学（北京）材料科学与工程学院，北京　100083
- 作者简介：
- 基金信息：
  
  the Program of Science and Technology International Cooperation Project of Qinghai Province(2022⁃HZ⁃807);the National Natural Science Foundation of China(51802172)
- DOI：10.37188/CJL.20230175
  CLC：
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高华波,陈奇,陈文超等.新型Ba₃In（PO₄）₃∶Yb³⁺,Ho³⁺荧光粉的上转换发光及其温度传感性能[J].发光学报,2023,44(11):1958-1966.

GAO Huabo,CHEN Qi,CHEN Wenchao,et al.Up-conversion Luminescence and Temperature Sensing Performance of Novel Ba₃In（PO₄）₃∶Yb³⁺, Ho³⁺ Phosphor[J].Chinese Journal of Luminescence,2023,44(11):1958-1966.
高华波,陈奇,陈文超等.新型Ba₃In（PO₄）₃∶Yb³⁺,Ho³⁺荧光粉的上转换发光及其温度传感性能[J].发光学报,2023,44(11):1958-1966. DOI： 10.37188/CJL.20230175.

GAO Huabo,CHEN Qi,CHEN Wenchao,et al.Up-conversion Luminescence and Temperature Sensing Performance of Novel Ba₃In（PO₄）₃∶Yb³⁺, Ho³⁺ Phosphor[J].Chinese Journal of Luminescence,2023,44(11):1958-1966. DOI： 10.37188/CJL.20230175.

摘要

采用高温固相法合成了一种新型的Yb,3+,和Ho,3+,共掺杂的Ba,3,In（PO,4,）,3,上转换荧光粉，并研究了其晶体结构、上转换发光及能量传递机制。在980 nm激光激发下，Yb,3+,吸收能量并传递至Ho,3+,；此外，激光功率对于荧光粉发光颜色无明显影响，发光颜色主要集中在橙黄色区域（0.543，0.452）。测得0.05Yb,3+,和0.032Ho,3+,掺杂的荧光粉的荧光寿命约为467.61 μs。还测量了该荧光粉温度依赖的发光光谱，并计算了其用作光学温度计的绝对灵敏度（,S,a,）和相对灵敏度（,S,r,）。结果表明，该荧光粉具有良好的热稳定性，423 K时的发射强度仍保持在室温的81.68%，,5,S,2,，,5,F,4,→,5,I,8,、,5,F,5,→,5,I,8,跃迁的Δ,E,分别约为0.19 eV和0.27 eV。此外，其,S,a,和,S,r,最大值分别为0.31%·K,-1,和0.09%·K,-1,（573 K）。

Abstract

In this work， a novel Yb,3+, and Ho,3+, co-doped Ba,3,In（PO,4,）,3, up-conversion phosphor was synthesized by high temperature solid-state method， and its crystal structure， up-conversion luminescence and energy transfer mechanism were studied. Under 980 nm laser excitation， Yb,3+, absorbs energy and transfers to Ho,3+,.In addition， the laser power has no significant effect on the luminescent color of the phosphor， and the luminescent color is mainly concentrated in the orange-red region （0.543， 0.452）. The fluorescence lifetime of 0.05Yb,3+, and 0.032Ho,3+, doped phosphor is about 467.61 μs. The temperature-dependent photoluminescence emission spectra of the phosphor were also measured， and the absolute sensitivity （,S,a,） and relative sensitivity （,S,r,） were calculated. The results show that the phosphor has good thermal stability， and the emission intensity at 423 K remains about 81.68% of that at room temperature. The Δ,E, of ,5,S,2,，,5,F,4,→,5,I,8,，,5,F,5,→,5,I,8, transitions are 0.19 eV and 0.27 eV， respectively.In addition， the maximum ,S,a, and ,S,r, are 0.31%·K,-1, and 0.09%·K,-1, （573 K）， respectively.

关键词

荧光粉上转换发光温度传感性能

Keywords

phosphorup-conversion luminescencetemperature sensing performance

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