Up-conversion Luminescence and Temperature Sensing Performance of Novel Ba3In（PO4）3∶Yb3+, Ho3+ Phosphor

GAO Huabo; CHEN Qi; CHEN Wenchao; MIN Xin; MA Bin

doi:10.37188/CJL.20230175

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Up-conversion Luminescence and Temperature Sensing Performance of Novel Ba₃In（PO₄）₃∶Yb³⁺, Ho³⁺ Phosphor

Synthesis and Properties of Materials | 更新时间：2023-11-27

- Up-conversion Luminescence and Temperature Sensing Performance of Novel Ba₃In（PO₄）₃∶Yb³⁺, Ho³⁺ Phosphor
  增强出版
- Chinese Journal of Luminescence Vol. 44, Issue 11, Pages: 1958-1966(2023)
- 作者机构：
  
  1.青海大学机械工程学院，青海西宁　810016
  2.中国地质大学（北京）材料科学与工程学院，北京　100083
- 作者简介：
- 基金信息：
  
  the Program of Science and Technology International Cooperation Project of Qinghai Province(2022⁃HZ⁃807);the National Natural Science Foundation of China(51802172)
- DOI：10.37188/CJL.20230175
  CLC： O482.31
- Published：05 November 2023，
  
  Received：07 August 2023，
  
  Revised：17 August 2023，
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高华波,陈奇,陈文超等.新型Ba₃In（PO₄）₃∶Yb³⁺,Ho³⁺荧光粉的上转换发光及其温度传感性能[J].发光学报,2023,44(11):1958-1966.

GAO Huabo,CHEN Qi,CHEN Wenchao,et al.Up-conversion Luminescence and Temperature Sensing Performance of Novel Ba₃In（PO₄）₃∶Yb³⁺, Ho³⁺ Phosphor[J].Chinese Journal of Luminescence,2023,44(11):1958-1966.
高华波,陈奇,陈文超等.新型Ba₃In（PO₄）₃∶Yb³⁺,Ho³⁺荧光粉的上转换发光及其温度传感性能[J].发光学报,2023,44(11):1958-1966. DOI： 10.37188/CJL.20230175.

GAO Huabo,CHEN Qi,CHEN Wenchao,et al.Up-conversion Luminescence and Temperature Sensing Performance of Novel Ba₃In（PO₄）₃∶Yb³⁺, Ho³⁺ Phosphor[J].Chinese Journal of Luminescence,2023,44(11):1958-1966. DOI： 10.37188/CJL.20230175.

摘要

采用高温固相法合成了一种新型的Yb

和Ho

共掺杂的Ba

In（PO

）

上转换荧光粉，并研究了其晶体结构、上转换发光及能量传递机制。在980 nm激光激发下，Yb

吸收能量并传递至Ho

；此外，激光功率对于荧光粉发光颜色无明显影响，发光颜色主要集中在橙黄色区域（0.543，0.452）。测得0.05Yb

和0.032Ho

掺杂的荧光粉的荧光寿命约为467.61 μs。还测量了该荧光粉温度依赖的发光光谱，并计算了其用作光学温度计的绝对灵敏度（

）和相对灵敏度（

）。结果表明，该荧光粉具有良好的热稳定性，423 K时的发射强度仍保持在室温的81.68%，

，

→

、

→

跃迁的Δ

分别约为0.19 eV和0.27 eV。此外，其

和

最大值分别为0.31%·K

-1

和0.09%·K

-1

（573 K）。

Abstract

In this work， a novel Yb

and Ho

co-doped Ba

In（PO

）

up-conversion phosphor was synthesized by high temperature solid-state method， and its crystal structure， up-conversion luminescence and energy transfer mechanism were studied. Under 980 nm laser excitation， Yb

absorbs energy and transfers to Ho

.In addition， the laser power has no significant effect on the luminescent color of the phosphor， and the luminescent color is mainly concentrated in the orange-red region （0.543， 0.452）. The fluorescence lifetime of 0.05Yb

and 0.032Ho

doped phosphor is about 467.61 μs. The temperature-dependent photoluminescence emission spectra of the phosphor were also measured， and the absolute sensitivity （

） and relative sensitivity （

） were calculated. The results show that the phosphor has good thermal stability， and the emission intensity at 423 K remains about 81.68% of that at room temperature. The Δ

，

→

，

→

transitions are 0.19 eV and 0.27 eV， respectively.In addition， the maximum

and

are 0.31%·K

-1

and 0.09%·K

-1

（573 K）， respectively.

关键词

荧光粉上转换发光温度传感性能

Keywords

phosphorup-conversion luminescencetemperature sensing performance

references

ZHOU J， LIU Q， FENG W， et al. Upconversion luminescent materials： Advances and applications ［J］. Chem. Rev.， 2015， 115（1）： 395-465. doi: 10.1021/cr400478fhttp://dx.doi.org/10.1021/cr400478f

KORE B P， KUMAR A， ERASMUS L， et al. Energy transfer mechanisms and optical thermometry of BaMgF4∶Yb3+， Er3+ phosphor ［J］. Inorg. Chem.， 2018， 57（1）： 288-299. doi: 10.1021/acs.inorgchem.7b02436http://dx.doi.org/10.1021/acs.inorgchem.7b02436

LOO J F C， CHIEN Y H， YIN F， et al. Upconversion and downconversion nanoparticles for biophotonics and nanomedicine ［J］. Coord. Chem. Rev.， 2019， 400： 213042. doi: 10.1016/j.ccr.2019.213042http://dx.doi.org/10.1016/j.ccr.2019.213042

LIAN H Z， HOU Z Y， SHANG M M， et al. Rare earth ions doped phosphors for improving efficiencies of solar cells ［J］. Energy， 2013， 57： 270-283. doi: 10.1016/j.energy.2013.05.019http://dx.doi.org/10.1016/j.energy.2013.05.019

钱幸璐. 基于荧光体材料制备白光LED器件研究［D］. 上海：上海应用技术大学， 2020.

QIAN X L. Research on White LED Devices Based on Phosphor Materials ［D］. Shanghai： Shanghai Institute of Technology， 2020. （in Chinese）

DU P P， MA J， ZHU Q， et al. Phase evolution， structure， and up-/down-conversion luminescence of Li6CaLa2Nb2O12∶Yb3+/RE3+ phosphors （RE=Ho， Er， Tm）［J］. J. Am. Ceram. Soc.， 2020， 103（4）： 2674-2685. doi: 10.1111/jace.16977http://dx.doi.org/10.1111/jace.16977

ANSARI A A， MUTHUMAREESWARAN M R， LV R C. Coordination chemistry of the host matrices with dopant luminescent Ln3+ ion and their impact on luminescent properties ［J］. Coord. Chem. Rev.， 2022， 466： 214584. doi: 10.1016/j.ccr.2022.214584http://dx.doi.org/10.1016/j.ccr.2022.214584

HU J S， BIAN X M， WANG R N， et al. Giant enhancement in upconversion luminescence of β-Ba2ScAlO5∶Yb3+/Er3+ phosphor by the intermediate band through Ca2+ doping ［J］. Chem. Mater.， 2022， 34（7）： 3089-3098. doi: 10.1021/acs.chemmater.1c04142http://dx.doi.org/10.1021/acs.chemmater.1c04142

LI M J， YANG Z W， REN Y T， et al. Reversible modulated upconversion luminescence of MoO3∶Yb3+，Er3+ thermochromic phosphor for switching devices ［J］. Inorg. Chem.， 2019， 58（10）： 6950-6958. doi: 10.1021/acs.inorgchem.9b00526http://dx.doi.org/10.1021/acs.inorgchem.9b00526

FU Y， WANG X J， LIU S， et al. Multicolor upconversion emission and highly optical temperature sensing based on lanthanide-doped double perovskite Sr2LaNbO6 phosphors ［J］. Ceram. Int.， 2023， 49（6）： 9574-9583. doi: 10.1016/j.ceramint.2022.11.127http://dx.doi.org/10.1016/j.ceramint.2022.11.127

SAMAL S K， PUSHPENDRA， YADAV J， et al. Upconversion properties of Er， Yb co-doped KBi（MoO4）2 nanomaterials for optical thermometry ［J］. Ceram. Int.， 2023， 49（12）： 20051-20060. doi: 10.1016/j.ceramint.2023.03.127http://dx.doi.org/10.1016/j.ceramint.2023.03.127

GUPTA I， SINGH S， BHAGWAN S， et al. Rare earth （RE） doped phosphors and their emerging applications： A review ［J］. Ceram. Int.， 2021， 47（14）： 19282-19303. doi: 10.1016/j.ceramint.2021.03.308http://dx.doi.org/10.1016/j.ceramint.2021.03.308

YANG X N， LI X， LI Y C， et al. Effect of energy transfer and local crystal field perturbation on the thermometric sensitivity of Ga-Tb-Eu ternary emission system ［J］. Ceram. Int.， 2022， 48（1）： 684-693. doi: 10.1016/j.ceramint.2021.09.148http://dx.doi.org/10.1016/j.ceramint.2021.09.148

GAO H B， MOLOKEEV M S， CHEN Q， et al. Effect of ligand environment of rare-earth ions on temperature measurement performance of SrAO4∶xEu3+ （A = Mo and W） phosphors ［J］. Ceram. Int.， 2022， 48（24）： 36835-36844. doi: 10.1016/j.ceramint.2022.08.247http://dx.doi.org/10.1016/j.ceramint.2022.08.247

HUA Y B， YU J S. Strong green emission of erbium（Ⅲ）-activated La2MgTiO6 phosphors for solid-state lighting and optical temperature sensors ［J］. ACS Sustainable Chem. Eng.， 2021， 9（14）： 5105-5115. doi: 10.1021/acssuschemeng.0c09375http://dx.doi.org/10.1021/acssuschemeng.0c09375

LIU W G， WANG X J， ZHU Q， et al. Upconversion luminescence and favorable temperature sensing performance of eulytite-type Sr3Y（PO4）3∶Yb3+/Ln3+ phosphors （Ln=Ho， Er， Tm）［J］. Sci. Technol. Adv. Mater.， 2019， 20（1）： 949-963. doi: 10.1080/14686996.2019.1659090http://dx.doi.org/10.1080/14686996.2019.1659090

ZHENG T， ZHOU L H， QIU X J， et al. Er3+， Yb3+ co-doped Sr3（PO4）2 phosphors： A ratiometric luminescence thermometer based on stark levels with tunable sensitivity ［J］. J. Lumin.， 2020， 227： 117517. doi: 10.1016/j.jlumin.2020.117517http://dx.doi.org/10.1016/j.jlumin.2020.117517

ZHANG G Q， MOLOKEEV M S， MA Q C， et al. Structural analysis and optical temperature sensing performance of Eu3+-doped Ba3In（PO4）3 ［J］. CrystEngComm， 2020， 22（35）： 5809-5817. doi: 10.1039/d0ce00997khttp://dx.doi.org/10.1039/d0ce00997k

LEI Z H， LIU R H， SUN L J， et al. An up-conversion Ba3In（PO4）3∶Er3+/Yb3+ phosphor that enables multi-mode temperature measurements and wide-gamut ‘temperature mapping’ ［J］. Dalton Trans.， 2023， 52（29）： 10155-10164. doi: 10.1039/d3dt01575khttp://dx.doi.org/10.1039/d3dt01575k

ZHANG J， ZHANG Y Q， JIANG X M. Investigations on upconversion luminescence of K3Y（PO4）2∶Yb3+-Er3+/Ho3+/Tm3+ phosphors for optical temperature sensing ［J］. J. Alloys Compd.， 2018， 748： 438-445. doi: 10.1016/j.jallcom.2018.03.127http://dx.doi.org/10.1016/j.jallcom.2018.03.127

KHAJURIA P， BEDYAL A K， MANHAS M， et al. Spectral， surface and thermometric investigations of upconverting Er3+/Yb3+ co-doped Na3Y（PO4）2 phosphor ［J］. J. Alloys Compd.， 2021， 877： 160327. doi: 10.1016/j.jallcom.2021.160327http://dx.doi.org/10.1016/j.jallcom.2021.160327

朱浩天. 三种稀土磷酸盐基上转换发光材料的制备及性能研究［D］. 贵州：贵州师范大学， 2022.

ZHU H T. Preparation and Properties of Three Rare Earth Phosphate⁃based Up⁃conversion Luminescent Materials ［D］. Guizhou： Guizhou Normal University， 2022. （in Chinese）

Bruker AXS TOPAS V4： General profile and structure analysis software for powder diffraction data.⁃User's Manual ［M］. Bruker AXS， Karlsruhe， Germany. 2008.

SUN Z S， NING Q X， ZHOU W Y， et al. Structural and spectroscopic investigation of an efficient and broadband NIR phosphor InBO3∶Cr3+ and its application in NIR pc-LEDs ［J］. Ceram. Int.， 2021， 47（10）： 13598-13603. doi: 10.1016/j.ceramint.2021.01.218http://dx.doi.org/10.1016/j.ceramint.2021.01.218

GENG X， XIE Y， CHEN S S， et al. Enhanced local symmetry achieved zero-thermal-quenching luminescence characteristic in the Ca2InSbO6∶Sm3+ phosphors for w-LEDs ［J］. Chem. Eng. J.， 2021， 410： 128396. doi: 10.1016/j.cej.2020.128396http://dx.doi.org/10.1016/j.cej.2020.128396

WANG Q， WANG S W， PANG R， et al. Two-site occupation in Cr3+-activated BaIn2（P2O7）2 phosphor for broadband near-infrared thermometry and LED applications ［J］. Mater. Res. Bull.， 2023， 163： 112222. doi: 10.1016/j.materresbull.2023.112222http://dx.doi.org/10.1016/j.materresbull.2023.112222

ZHANG J L， ZHAO W R， ZHANG X L， et al. Ultra-broadband near-infrared emission in the double-perovskite Ca2InTaO6∶Cr3+ phosphor for light-emitting-diode applications ［J］. J. Lumin.， 2023， 255： 119581. doi: 10.1016/j.jlumin.2022.119581http://dx.doi.org/10.1016/j.jlumin.2022.119581

XU X X， SHAO Q Y， YAO L Q， et al. Highly efficient and thermally stable Cr3+-activated silicate phosphors for broadband near-infrared LED applications ［J］. Chem. Eng. J.， 2020， 383： 123108. doi: 10.1016/j.cej.2019.123108http://dx.doi.org/10.1016/j.cej.2019.123108

DONG X R， CUI X Y， FU Z L， et al. Study on preparation and luminescent properties of Eu3+-doped LaAlO3 and GdAlO3 ［J］. Mater. Res. Bull.， 2012， 47（2）： 212-216. doi: 10.1016/j.materresbull.2011.11.046http://dx.doi.org/10.1016/j.materresbull.2011.11.046

SHI X F， MOLOKEEV M S， WANG X J， et al. Crystal structure of NaLuW2O8·2H2O and down/upconversion luminescence of the derived NaLu（WO4）2∶Yb/Ln phosphors （Ln = Ho， Er， Tm）［J］. Inorg. Chem.， 2018， 57（17）： 10791-10801. doi: 10.1021/acs.inorgchem.8b01427http://dx.doi.org/10.1021/acs.inorgchem.8b01427

HUA Y B， RAN W G， YU J S. Excellent photoluminescence and cathodoluminescence properties in Eu3+-activated Sr2LaNbO6 materials for multifunctional applications ［J］. Chem. Eng. J.， 2021， 406： 127154. doi: 10.1016/j.cej.2020.127154http://dx.doi.org/10.1016/j.cej.2020.127154

GAO H B， MOLOKEEV M S， CHEN Q， et al. Novel AMoO4∶Eu3+ （A = Ca and Ba） optical thermometer： Investigation of effect of local ionic coordination environment on optical performance and temperature measurement sensitivity ［J］. Ceram. Int.， 2023， 49（16）： 26803-26810. doi: 10.1016/j.ceramint.2023.05.217http://dx.doi.org/10.1016/j.ceramint.2023.05.217

HUA Y B， YU J S. Broadband near-ultraviolet excited La2Mo2O9∶Eu3+ red-emitting phosphors with high color purity for solid-state lighting ［J］. J. Alloys Compd.， 2019， 783： 969-976. doi: 10.1016/j.jallcom.2018.12.279http://dx.doi.org/10.1016/j.jallcom.2018.12.279

SAIDI K， DAMMAK M. Upconversion luminescence and optical temperature sensing characteristics of Er3+/Yb3+ codoped Na3Gd（PO4）2 phosphors ［J］. J. Solid State Chem.， 2021， 300： 122214. doi: 10.1016/j.jssc.2021.122214http://dx.doi.org/10.1016/j.jssc.2021.122214

ZHANG J， HUA Z H. Effect of dopant contents on upconversion luminescence and temperature sensing behavior in Ca3La6Si6O24∶Yb3+-Er3+/Ho3+ phosphors ［J］. J. Lumin.， 2018， 201： 217-223. doi: 10.1016/j.jlumin.2018.04.063http://dx.doi.org/10.1016/j.jlumin.2018.04.063

PANDEY A， RAI V K. Improved luminescence and temperature sensing performance of Ho3+-Yb3+-Zn2+∶Y2O3 phosphor ［J］. Dalton Trans.， 2013， 42（30）： 11005-11011. doi: 10.1039/c3dt50592hhttp://dx.doi.org/10.1039/c3dt50592h

WANG X F， LIU Q， BU Y Y， et al. Optical temperature sensing of rare-earth ion doped phosphors ［J］. RSC Adv.， 2015， 5（105）： 86219-86236. doi: 10.1039/c5ra16986khttp://dx.doi.org/10.1039/c5ra16986k

CHAI X N， LI J， WANG X S， et al. Upconversion luminescence and temperature-sensing properties of Ho3+/Yb3+-codoped ZnWO4 phosphors based on fluorescence intensity ratios ［J］. RSC Adv.， 2017， 7（64）： 40046-40052. doi: 10.1039/c7ra05846bhttp://dx.doi.org/10.1039/c7ra05846b

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Related Author

CHEN Qi

CHEN Wenchao

MIN Xin

MA Bin

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LIU Rui

WANG Pengfei

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Related Institution

School of Chemistry， Fuzhou University

CAS Key Laboratory of Design and Assembly of Functional Nanostructures， Fujian Institute of Research on the Structure of Matter， Chinese Academy of Sciences

Fujian College， University of Chinese Academy of Sciences

School of Science， Shenyang Ligong University， Shenyang 110159， China

State Key Laboratory of Luminescence and Applications， Changchun Institute of Optics， Fine Mechanics and Physics， Chinese Academy of Sciences， Changchun 130033， China

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