Near Infrared Optical Thermometry Along with Photothermal Conversion Ability Realized in BaY2O4∶Nd3+

XIANG Guotao; DING Yongxi; ZHANG Yu; LIU Tao; FU Yingxin; WU Hongxiu; YAO Lu; CHANG Ying

doi:10.37188/CJL.20230172

您当前的位置：

首页 >

文章列表页 >

Near Infrared Optical Thermometry Along with Photothermal Conversion Ability Realized in BaY₂O₄∶Nd³⁺

Synthesis and Properties of Materials | 更新时间：2023-11-01

- Near Infrared Optical Thermometry Along with Photothermal Conversion Ability Realized in BaY₂O₄∶Nd³⁺
  增强出版
- Chinese Journal of Luminescence Vol. 44, Issue 10, Pages: 1779-1785(2023)
- 作者机构：
  
  重庆邮电大学理学院，重庆　400065
- 作者简介：
- 基金信息：
  
  National Natural Science Foundation of China(11704054);Natural Science Foundation of Chongqing(CSTB2022NSCQ⁃MSX0366);Undergraduate Innovation and Entrepreneurship Training Plan Program of China(202210617017);Doctoral Through Train Scientific Research Project of Chongqing(sl202100000301);Science and Technology Research Program of Chongqing Municipal Education Commission(KJQN202100640)
- DOI：10.37188/CJL.20230172
  CLC： O482.31
- Received：25 July 2023，
  
  Revised：03 August 2023，
  
  Published：05 October 2023
- 稿件说明：
移动端阅览
相国涛,丁永希,张羽等.具有光热转换能力的近红外光学测温材料BaY₂O₄∶Nd³⁺[J].发光学报,2023,44(10):1779-1785.

XIANG Guotao,DING Yongxi,ZHANG Yu,et al.Near Infrared Optical Thermometry Along with Photothermal Conversion Ability Realized in BaY₂O₄∶Nd³⁺[J].Chinese Journal of Luminescence,2023,44(10):1779-1785.
相国涛,丁永希,张羽等.具有光热转换能力的近红外光学测温材料BaY₂O₄∶Nd³⁺[J].发光学报,2023,44(10):1779-1785. DOI： 10.37188/CJL.20230172.

XIANG Guotao,DING Yongxi,ZHANG Yu,et al.Near Infrared Optical Thermometry Along with Photothermal Conversion Ability Realized in BaY₂O₄∶Nd³⁺[J].Chinese Journal of Luminescence,2023,44(10):1779-1785. DOI： 10.37188/CJL.20230172.

摘要

光热治疗亟需一种准确、高效、分辨率高且适用于深层生物组织的测温手段以辅助其治疗过程。本文以高温固相法合成了BaY

∶Nd

材料，并基于Nd

：

3/2

的Stark劈裂能级实现了较为精准的光学测温。数据表明，其测温的绝对灵敏度、相对灵敏度及分辨率的最佳值可分别达到0.09%·K

-1

、0.69%·K

-1

和0.05 K，优于大多数同类型温度计的相应数值。与此同时，因该光学温度计的激发和发射波长均位于生物窗口之内，使其在生物组织中的穿透深度可达到8 mm。另外，该材料还具有一定的光热转换能力。上述结果表明， Nd

单掺的BaY

在深层组织的光热治疗方面具备一定的应用潜力。

Abstract

Photothermal therapy （PTT） is in dire need of an accurate， efficient and high-resolution thermometer working in the deep tissues to assist its treatment process. In this paper， the high temperature solid state method is employed to synthesize the BaY

∶Nd

powder， in which the thermally coupled Stark sublevels of Nd

：

3/2

are utilized to measure the temperature based on the fluorescence intensity ratio （FIR） technology. The optimal value of its absolute sensitivity， relative sensitivity and temperature resolution is 0.09%·K

-1

， 0.69%·K

-1

and 0.05 K， which are superior to majority of the same type thermometers. Moreover， the penetration depth of the present sample in the biological tissues can be reached to 8 mm， benefiting from the fact that its excitation and emission wavelength are all located in the biological windows. Beyond that， the sample owns photothermal conversion ability under the irradiation of 808 nm wavelength. All the findings show the potential of Nd

single-doped BaY

in deep-tissue PTT.

关键词

Keywords

references

LI X S ， LOVELL J F ， YOON J ， et al . Clinical development and potential of photothermal and photodynamic therapies for cancer ［J］. Nat. Rev. Clin. Oncol. ， 2020 ， 17 （ 11 ）： 657 - 674 . doi: 10.1038/s41571-020-0410-2 http://dx.doi.org/10.1038/s41571-020-0410-2

GAO G ， SUN X B ， LIANG G L . Nanoagent-promoted mild-temperature photothermal therapy for cancer treatment ［J］. Adv. Funct. Mater. ， 2021 ， 31 （ 25 ）： 2100738 . doi: 10.1002/adfm.202100738 http://dx.doi.org/10.1002/adfm.202100738

WEI W F ， ZHANG X Y ， ZHANG S ， et al . Biomedical and bioactive engineered nanomaterials for targeted tumor photothermal therapy： a review ［J］. Mater. Sci. Eng. C ， 2019 ， 104 ： 109891 . doi: 10.1016/j.msec.2019.109891 http://dx.doi.org/10.1016/j.msec.2019.109891

LIU H J ， WANG M M ， HU X X ， et al . Enhanced photothermal therapy through the in situ activation of a temperature and redox dual-sensitive nanoreservoir of triptolide ［J］. Small ， 2020 ， 16 （ 38 ）： 2003398 . doi: 10.1002/smll.202003398 http://dx.doi.org/10.1002/smll.202003398

WANG Y F ， DU W ， ZHANG T ， et al . A self-evaluating photothermal therapeutic nanoparticle ［J］. ACS Nano ， 2020 ， 14 （ 8 ）： 9585 - 9593 . doi: 10.1021/acsnano.9b10144 http://dx.doi.org/10.1021/acsnano.9b10144

CAO J K ， CHEN W P ， XU D K ， et al . Wide-range thermometry based on green up-conversion of Yb 3+ /Er 3+ co-doped KLu 2 F 7 transparent bulk oxyfluoride glass ceramics ［J］. J. Lumin. ， 2018 ， 194 ： 219 - 224 . doi: 10.1016/j.jlumin.2017.10.020 http://dx.doi.org/10.1016/j.jlumin.2017.10.020

RUIZ D ， DEL ROSAL B ， ACEBRÓN M ， et al . Ag/Ag 2 S nanocrystals for high sensitivity near-infrared luminescence nanothermometry ［J］. Adv. Funct. Mater. ， 2017 ， 27 （ 6 ）： 1604629 . doi: 10.1002/adfm.201604629 http://dx.doi.org/10.1002/adfm.201604629

LIU S F ， CUI J ， JIA J J ， et al . High sensitive Ln 3+ /Tm 3+ /Yb 3+ （ Ln 3+ = Ho 3+ ， Er 3+ ） tri-doped Ba 3 Y 4 O 9 upconverting optical thermometric materials based on diverse thermal response from non-thermally coupled energy levels ［J］. Ceram. Int. ， 2019 ， 45 （ 1 ）： 1 - 10 . doi: 10.1016/j.ceramint.2018.09.162 http://dx.doi.org/10.1016/j.ceramint.2018.09.162

XIANG G T ， LIU X T ， XIA Q ， et al . Deep-tissue temperature sensing realized in BaY 2 O 4 ∶Yb 3+ /Er 3+ with ultrahigh sensitivity and extremely intense red upconversion luminescence ［J］. Inorg. Chem. ， 2020 ， 59 （ 15 ）： 11054 - 11060 . doi: 10.1021/acs.inorgchem.0c01543 http://dx.doi.org/10.1021/acs.inorgchem.0c01543

JI Y ， XU W ， DING N ， et al . Huge upconversion luminescence enhancement by a cascade optical field modulation strategy facilitating selective multispectral narrow-band near-infrared photodetection ［J］. Light Sci. Appl. ， 2020 ， 9 （ 1 ）： 184 . doi: 10.1038/s41377-020-00418-0 http://dx.doi.org/10.1038/s41377-020-00418-0

SHOU K Q ， QU C R ， SUN Y ， et al . Multifunctional biomedical imaging in physiological and pathological conditions using a NIR-II probe ［J］. Adv. Funct. Mater. ， 2017 ， 27 （ 23 ）： 1700995 . doi: 10.1002/adfm.201700995 http://dx.doi.org/10.1002/adfm.201700995

ZHAN Q Q ， QIAN J ， LIANG H J ， et al . Using 915 nm laser excited Tm 3+ /Er 3+ /Ho 3+ -doped NaYbF 4 upconversion nanoparticles for in vitro and deeper in vivo bioimaging without overheating irradiation ［J］. ACS Nano ， 2011 ， 5 （ 5 ）： 3744 - 3757 . doi: 10.1021/nn200110j http://dx.doi.org/10.1021/nn200110j

XIANG G T ， YANG M L ， LIU Z ， et al . Near-infrared-to-near-infrared optical thermometer BaY 2 O 4 ∶Yb 3+ /Nd 3+ assembled with photothermal conversion performance ［J］. Inorg. Chem. ， 2022 ， 61 （ 13 ）： 5425 - 5432 . doi: 10.1021/acs.inorgchem.2c00432 http://dx.doi.org/10.1021/acs.inorgchem.2c00432

XIANG G T ， YANG M L ， XIA Q ， et al . Ultrasensitive optical thermometer based on abnormal thermal quenching Stark transitions operating beyond 1 500 nm ［J］. J. Am. Ceram. Soc. ， 2021 ， 104 （ 11 ）： 5784 - 5793 . doi: 10.1111/jace.17981 http://dx.doi.org/10.1111/jace.17981

WAWRZYNCZYK D ， BEDNARKIEWICZ A ， NYK M ， et al . Neodymium （III） doped fluoride nanoparticles as non-contact optical temperature sensors ［J］. Nanoscale ， 2012 ， 4 （ 22 ）： 6959 - 6961 . doi: 10.1039/c2nr32203j http://dx.doi.org/10.1039/c2nr32203j

KOLESNIKOV I E ， KALINICHEV A A ， KUROCHKIN M A ， et al . YVO 4 ∶Nd 3+ nanophosphors as NIR-to-NIR thermal sensors in wide temperature range ［J］. Sci. Rep. ， 2017 ， 7 （ 1 ）： 18002 . doi: 10.1038/s41598-017-18295-w http://dx.doi.org/10.1038/s41598-017-18295-w

QUINTANILLA M ， ZHANG Y ， LIZ-MARZÁN L M . Subtissue plasmonic heating monitored with CaF 2 ∶Nd 3+ ，Y 3+ nanothermometers in the second biological window ［J］. Chem. Mater. ， 2018 ， 30 （ 8 ）： 2819 - 2828 . doi: 10.1021/acs.chemmater.8b00806 http://dx.doi.org/10.1021/acs.chemmater.8b00806

ROCHA U ， SILVA C JDA ， SILVA W F ， et al . Subtissue thermal sensing based on neodymium-doped LaF 3 nanoparticles ［J］. ACS Nano ， 2013 ， 7 （ 2 ）： 1188 - 1199 . doi: 10.1021/nn304373q http://dx.doi.org/10.1021/nn304373q

BENAYAS A ， DEL ROSAL B ， PÉREZ-DELGADO A ， et al . Nd∶YAG near-infrared luminescent nanothermometers ［J］. Adv. Opt. Mater. ， 2015 ， 3 （ 5 ）： 687 - 694 . doi: 10.1002/adom.201400484 http://dx.doi.org/10.1002/adom.201400484

Views

322

下载量

CSCD

Alert me when the article has been cited

提交

Tools

Publicity Resources

Temperature Sensing Properties in NaScF₄∶Yb³⁺/Er³⁺ Nanoparticles

Upconversion Luminescence Properties of β-NaYF₄:Yb³⁺/Er³⁺@β-NaYF₄:Yb³⁺

Preparation, Luminescence and Thermal Stability of Li⁺/La³⁺ Co-doped Single-phased BaSi₂O₅: Eu²⁺ Green Emitting Phosphors for White LEDs

Characterization and Storage Property of Dy³⁺ Doped C12A7 X-ray Phosphors with Yellowish-green Emission

Related Author

CHANG Ying

YAO Lu

WU Hong-xiu

XIANG Guo-tao

DING Yong-xi

ZHANG Yu

LIU Tao

FU Ying-xin

Related Institution

Department of Mathematics and Physics， Chongqing University of Posts and Telecommunications， 2 Chongwen Road

Department of Mathematics and Physics, Chongqing University of Posts and Telecommunications

School of Physics, Northeast Normal University, Changchun 130024, China

School of Physics, Northeast Normal University

AI问答

Address：No.3888 Dong Nanhu Road, Changchun, Jilin, China Postal code：130033
Tel：0431-86176862 Email：fgxbt@126.com
Technical support is provided by Beijing Founder electronics co., LTD 吉ICP备11002662号-17 京公网安备11010802024621
It is recommended to read the content of this site in Chrome&IE9+. Please switch to extreme mode in browser 360.
Cookies We use cookies to help provide and enhance our service and tailor content. By continuing, you agree to the use of cookies.

⁰