Near infrared optical thermometer BaY2O4: Nd3+ assembled with photothermal conversion property

XIANG Guo-tao; DING Yong-xi; ZHANG Yu; LIU Tao; FU Ying-xin; WU Hong-xiu; YAO Lu; CHANG Ying

doi:10.37188/CJL.20230172

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Near infrared optical thermometer BaY₂O₄: Nd³⁺ assembled with photothermal conversion property

更新时间：2023-08-09

- Near infrared optical thermometer BaY₂O₄: Nd³⁺ assembled with photothermal conversion property
  增强出版
- Chinese Journal of Luminescence Pages: 1-7(2023)
- 作者机构：
  
  1.重庆邮电大学理学院，重庆　400065
- 作者简介：
- 基金信息：
  
  National Natural Science Foundation of China(11704054);Natural Science Foundation of Chongqing(CSTB2022NSCQ-MSX0366);Undergraduate Innovation and Entrepreneurship Training Plan Program of China(202210617017)
- DOI：10.37188/CJL.20230172
  CLC：
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XIANG Guo-tao, DING Yong-xi, ZHANG Yu, et al. Near infrared optical thermometer BaY₂O₄: Nd³⁺ assembled with photothermal conversion property. [J/OL]. Chinese Journal of Luminescence 1-7(2023)
DOI：

XIANG Guo-tao, DING Yong-xi, ZHANG Yu, et al. Near infrared optical thermometer BaY₂O₄: Nd³⁺ assembled with photothermal conversion property. [J/OL]. Chinese Journal of Luminescence 1-7(2023) DOI： 10.37188/CJL.20230172.

摘要

光热治疗亟需一种准确、高效、分辨率高且适用于深层生物组织的测温手段以辅助其治疗过程。本文以高温固相法合成了BaY,2,O,4,： Nd,3+,材料，并基于Nd,3+,： ,4,F,3/2,的Stark劈裂能级实现了较为精准的光学测温。数据表明，其测温的绝对灵敏度、相对灵敏度及分辨率的最佳值可分别达到0.09% ,K,-1,、0.69% ,K,-1,和0.05 ,K,，优于大多数同类型温度计的相应数值。与此同时，因该光学温度计的激发和发射波长均位于生物窗口之内，使其在生物组织中的穿透深度可达到8 mm。另外，该材料还具有一定的光热转换能力。以上结果表明， Nd,3+,单掺的BaY,2,O,4,在深层组织的光热治疗方面具备一定的应用潜力。

Abstract

Photothermal therapy （PTT） is in dire need of an accurate， efficient and high-resolution thermometer working in the deep tissues to assist its treatment process. In this paper， the high temperature solid state method is employed to synthesize the BaY,2,O,4,： Nd,3+, powder， in which the thermally coupled Stark sublevels of Nd,3+,： ,4,F,3/2, are utilized to measure the temperature based on the fluorescence intensity ratio （,FIR,） technology. The optimal value of its absolute sensitivity， relative sensitivity and temperature resolution is 0.09% ,K,-1,， 0.69% ,K,-1, and 0.05 ,K,， which are superior to majority of the same type thermometers. Moreover， the penetration depth of the present sample in the biological tissues can be reached to 8 mm， benefiting from the fact that its excitation and emission wavelength are all located in the biological windows. Beyond that， the sample owns photothermal conversion ability under the irradiation of 808 nm wavelength. All the findings show the potential of Nd,3+, single-doped BaY,2,O,4, in deep-tissue PTT.

关键词

稀土离子光热治疗光学测温光热转换BaY2O4： Nd3+

Keywords

rare earthrare earthphotothermal therapyoptical thermometryphotothermal conversionBaY2O4： Nd3+

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Department of Mathematics and Physics, Chongqing University of Posts and Telecommunications

School of Physics, Northeast Normal University, Changchun 130024, China

School of Physics, Northeast Normal University

State Key Laboratory of Luminescence and Applications, Changchun Institute of Optics, Fine Mechanics and Physics, Chinese Academy of Sciences

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