Temperature- and Concentration-dependent Luminescence and Fluorescence Dynamic Temperature Sensing of NaGd（MoO4）2∶Tb3+ Phosphors

BAI Haibin; CHEN Xin; SHA Xuezhu; GAO Duan; ZHANG Yinghui; ZHANG Xiangqing; CHEN Baojiu

doi:10.37188/CJL.20230165

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Temperature- and Concentration-dependent Luminescence and Fluorescence Dynamic Temperature Sensing of NaGd（MoO₄）₂∶Tb³⁺Phosphors

Synthesis and Properties of Materials | 更新时间：2023-11-01

- Temperature- and Concentration-dependent Luminescence and Fluorescence Dynamic Temperature Sensing of NaGd（MoO₄）₂∶Tb³⁺Phosphors
  增强出版
- Chinese Journal of Luminescence Vol. 44, Issue 10, Pages: 1770-1778(2023)
- 作者机构：
  
  大连海事大学理学院，辽宁大连　116026
- 作者简介：
- 基金信息：
  
  National Natural Science Foundation of China(11774042;52071048)
- DOI：10.37188/CJL.20230165
  CLC： O482.31
- Published：05 October 2023，
  
  Received：14 July 2023，
  
  Revised：24 July 2023，
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白海斌,陈昕,沙雪竹等.NaGd（MoO₄）₂∶Tb³⁺荧光粉的温度及浓度依赖发光与荧光动力学温度传感[J].发光学报,2023,44(10):1770-1778.

BAI Haibin,CHEN Xin,SHA Xuezhu,et al.Temperature- and Concentration-dependent Luminescence and Fluorescence Dynamic Temperature Sensing of NaGd（MoO₄）₂∶Tb³⁺Phosphors[J].Chinese Journal of Luminescence,2023,44(10):1770-1778.
白海斌,陈昕,沙雪竹等.NaGd（MoO₄）₂∶Tb³⁺荧光粉的温度及浓度依赖发光与荧光动力学温度传感[J].发光学报,2023,44(10):1770-1778. DOI： 10.37188/CJL.20230165.

BAI Haibin,CHEN Xin,SHA Xuezhu,et al.Temperature- and Concentration-dependent Luminescence and Fluorescence Dynamic Temperature Sensing of NaGd（MoO₄）₂∶Tb³⁺Phosphors[J].Chinese Journal of Luminescence,2023,44(10):1770-1778. DOI： 10.37188/CJL.20230165.

摘要

采用高温固相法制备了不同Tb

掺杂浓度的NaGd（MoO

）

∶Tb

荧光粉，XRD结果证实所制得样品为纯相。利用荧光光谱测量对该荧光粉的发光浓度猝灭进行了分析，证明荧光浓度猝灭是由Tb

离子间的交换相互作用所导致，并符合浓度猝灭的Ozawa模型。采用Auzel提出的自产生猝灭模型对Tb

的

能级荧光动力学进行了分析，结果表明该模型能够很好地解释荧光寿命对浓度的依赖关系。研究了Tb

的

能级的发光强度和荧光寿命对样品温度的依赖关系，提出了利用荧光寿命进行温度传感的方法，并对温度传感的绝对和相对灵敏度进行了分析。

Abstract

NaGd（MoO

）

∶Tb

phosphors with different Tb

concentrations were prepared by a high-temperature solid-state reaction method. The crystal structure analysis by means of X-ray diffraction （XRD） revealed that the samples prepared were pure-phased. Fluorescence spectroscopy measurements were utilized to investigate the phosphor's fluorescence quenching， and the results indicated that the fluorescence concentration quenching resulted from exchange interactions between Tb

ions， and the Ozawa model held for the fluorescence quenching process. The self-generated quenching model proposed by Auzel was used to analyze the

level fluorescence dynamics of Tb

， and it was found that the Auzel model can well explain the concentration dependence of fluorescence lifetime. The dependences of the luminescence intensity and lifetime of the

level of Tb

on the sample temperature were investigated. A method for temperature sensing using the fluorescence lifetime was proposed， and the absolute and relative sensitivities of temperature sensing were analyzed.

关键词

高温固相法浓度猝灭荧光衰减热猝灭温度传感

Keywords

solid-state reactionconcentration quenchingfluorescent decaythermal quenchingtemperature sensing

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Related Institution

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Department of Physics, Dalian Maritime University, Dalian 116026, China

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