浏览全部资源
扫码关注微信
1.长春师范大学 物理学院, 吉林 长春 130032
2.中国科学院长春光学精密机械与物理研究所 发光学及应用国家重点实验室, 吉林 长春 130033
Published:05 November 2023,
Received:20 June 2023,
Revised:07 July 2023,
扫 描 看 全 文
李敏,孙晓园,范小暄等.Sr6Lu2Al4O15∶Tb3+荧光粉的发光特性[J].发光学报,2023,44(11):1940-1949.
LI Min,SUN Xiaoyuan,FAN Xiaoxuan,et al.Photoluminescence Properties of Sr6Lu2Al4O15∶Tb3+ Phosphor[J].Chinese Journal of Luminescence,2023,44(11):1940-1949.
李敏,孙晓园,范小暄等.Sr6Lu2Al4O15∶Tb3+荧光粉的发光特性[J].发光学报,2023,44(11):1940-1949. DOI: 10.37188/CJL.20230147.
LI Min,SUN Xiaoyuan,FAN Xiaoxuan,et al.Photoluminescence Properties of Sr6Lu2Al4O15∶Tb3+ Phosphor[J].Chinese Journal of Luminescence,2023,44(11):1940-1949. DOI: 10.37188/CJL.20230147.
采用高温固相法制备了颜色可调的Sr
6
Lu
2-2
x
Al
4
O
15
∶
x
Tb
3+
荧光粉,并研究了其晶体结构、发光特性和浓度猝灭机理。研究了Tb
3+
浓度对样品发光性质的影响。在紫外光激发下,当
x
=0.01时,Tb
3+
的
5
D
3
⁃
7
F
6
跃迁强度最强,峰值位于381 nm;当
x
=0.15时,Tb
3+
的
5
D
4
⁃
7
F
5
跃迁强度最强,峰值位于545 nm。随着Tb
3+
掺杂浓度的升高,样品的发光颜色从蓝光变为黄绿光。分析了Sr
6
Lu
2-2
x
Al
4
O
15
∶
x
Tb
3+
荧光粉的浓度猝灭机理。测量了荧光粉的荧光寿命、热稳定性、量子效率。结果表明,Sr
6
Lu
2-2
x
Al
4
O
15
∶
x
Tb
3+
是一种新型的发光颜色可调的荧光粉。
The phosphors Sr
6
Lu
2-2
x
Al
4
O
15
∶
x
Tb
3+
were synthesized through the solid-state reaction technique. The structure, photoluminescence properties and concentration quenching mechanisms were researched. The dependence of photoluminescence intensities on Tb
3+
concentration was studied. Upon excitation with UV excitation, when the doping concentration
x
=0.01, the strongest peak located around 381 nm, which arise from
5
D
3
-
7
F
6
transition of Tb
3+
; when the doping concentration
x
=0.15, the strongest peak located around 545 nm, which arise from
5
D
4
-
7
F
5
transition of Tb
3+
. The luminescence color changes from blue to yellowish green by adjusting the doping concentration of Tb
3+
. The concentration quenching mechanisms of Sr
6
Lu
2-2
x
Al
4
O
15
∶
x
Tb
3+
were studied. The lifetime, thermal stability and quantum efficiency were measured. The Sr
6
Lu
2-2
x
Al
4
O
15
∶
x
Tb
3+
phosphor is a novel color-tunable phosphor.
荧光粉光致发光颜色可调Tb3+掺杂
phosphorsphotoluminescencecolor-tunableTb3+ doped
ZHAO H Y, XIA J L, YIN D D, et al. Rare earth incorporated electrode materials for advanced energy storage [J]. Coord. Chem. Rev., 2019, 390: 32-49. doi: 10.1016/j.ccr.2019.03.011http://dx.doi.org/10.1016/j.ccr.2019.03.011
CHEN Y, ZHANG D L, PENG Z, et al. Review of research on the rare-earth doped piezoelectric materials [J]. Front. Mater., 2021, 8: 679167. doi: 10.3389/fmats.2021.679167http://dx.doi.org/10.3389/fmats.2021.679167
ZHANG H, ZHANG H Q, PAN A Z, et al. Rare earth-free luminescent materials for WLEDs: recent progress and perspectives [J]. Adv. Mater. Technol., 2021, 6(1): 2000648. doi: 10.1002/admt.202000648http://dx.doi.org/10.1002/admt.202000648
ESCUDERO A, BECERRO A I, CARRILLO-CARRIÓN C, et al. Rare earth based nanostructured materials: synthesis, functionalization, properties and bioimaging and biosensing applications [J]. Nanophotonics, 2017, 6(5): 881-921. doi: 10.1515/nanoph-2017-0007http://dx.doi.org/10.1515/nanoph-2017-0007
CANG L M, QIAN Z Y, WANG J P, et al. Applications and functions of rare-earth ions in perovskite solar cells [J]. Chin. Phys. B, 2022, 31 (3): 038402. doi: 10.1088/1674-1056/ac373ahttp://dx.doi.org/10.1088/1674-1056/ac373a
WANG S Y, SUN Q, LI B, et al. High-efficiency and thermal-stable tunable blue-green-emitting Ca3Lu(AlO)3(Bo3)4∶Ce3+, Tb3+ phosphors for near-UV-excited white LEDs [J]. Dyes Pigm., 2018, 157: 314-320. doi: 10.1016/j.dyepig.2018.05.010http://dx.doi.org/10.1016/j.dyepig.2018.05.010
谢会东, 谭玉荣, 苏彬彬, 等. La2-x-yMgTiO6∶xDy3+, yEu3+白色荧光粉的荧光性能及能量传递 [J]. 发光学报, 2019, 40 (6): 713-718. doi: 10.3788/fgxb20194006.0713http://dx.doi.org/10.3788/fgxb20194006.0713
XIE H D, TAN Y R, SU B B, et al. Luminescent properties and energy transfer of La2-x-yMgTiO6∶xDy3+, yEu3+ white phosphors [J]. Chin. J. Lumin., 2019, 40(6): 713-718. (in Chinese). doi: 10.3788/fgxb20194006.0713http://dx.doi.org/10.3788/fgxb20194006.0713
JIA Z W, YUAN C X, LIU Y F, et al. Strategies to approach high performance in Cr3+-doped phosphors for high-power NIR-LED light sources [J]. Light Sci. Appl., 2020, 9: 86. doi: 10.1038/s41377-020-0326-8http://dx.doi.org/10.1038/s41377-020-0326-8
王林香, 庹娟, 叶颖, 等. Li+, Zn2+, Mg2+掺杂Lu2O3∶Er3+荧光粉的制备及发光特性 [J]. 中国光学, 2019, 12 (1): 112-121. doi: 10.3788/CO.20191201.0112http://dx.doi.org/10.3788/CO.20191201.0112
WANG L X, TUO J, YE Y, et al. Preparation and luminescence properties of Li+, Zn2+, Mg2+ doped Lu2O3∶Er3+ phosphors [J]. Chin. Opt., 2019, 12(1): 112-121. (in Chinese). doi: 10.3788/CO.20191201.0112http://dx.doi.org/10.3788/CO.20191201.0112
章伟, 何梦婷, 乔旭升, 等. Mn4+激活的典型LED红色荧光粉研究进展 [J]. 发光学报, 2021, 42 (9): 1345-1364. doi: 10.37188/CJL.20210148http://dx.doi.org/10.37188/CJL.20210148
ZHANG W, HE M T, QIAO X S, et al. Research progress of Mn4+ activated typical LED red phosphors [J]. Chin. J. Lumin., 2021, 42 (9): 1345-1364. (in Chinese). doi: 10.37188/CJL.20210148http://dx.doi.org/10.37188/CJL.20210148
WU X L, JI X Y, WANG Z L, et al. Improving thermal stability and quantum efficiency through solid solution for Ce3+-activated (Ba1-xSrx)3Y2(BO3)4 phosphors [J]. J. Alloys Compd., 2021, 855: 157520. doi: 10.1016/j.jallcom.2020.157520http://dx.doi.org/10.1016/j.jallcom.2020.157520
QIAO X B, SEO H J. Phase transition, structural and spectroscopic properties of Ba3Y(BO3)3 phosphor [J]. J. Alloys Compd., 2015, 637: 504-508. doi: 10.1016/j.jallcom.2015.03.040http://dx.doi.org/10.1016/j.jallcom.2015.03.040
张家骅, 吕伟, 郝振东, 等. 利用能量传递实现可调全色单一白光BaMg2Al6Si9O30∶Eu2+, Tb3+, Mn2+荧光粉 (特邀) [J]. 中国光学, 2012, 5(3): 203-208. doi: 10.3969/j.issn.2095-1531.2012.03.003http://dx.doi.org/10.3969/j.issn.2095-1531.2012.03.003
ZHANG J H, LÜ W, HAO Z D, et al. Color-tunable white-light emitting BaMg2Al6Si9O30∶Eu2+, Tb3+, Mn2+ phosphors via energy transfer (Invited) [J]. Chin. Opt., 2012, 5(3): 203-208. (in Chinese). doi: 10.3969/j.issn.2095-1531.2012.03.003http://dx.doi.org/10.3969/j.issn.2095-1531.2012.03.003
KHAN W U, ZHOU L, LI X H, et al. Single phase white LED phosphor Ca3YAl3B4O15∶Ce3+, Tb3+, Sm3+ with superior performance: Color-tunable and energy transfer study [J]. Chem. Eng. J., 2021, 410: 128455. doi: 10.1016/j.cej.2021.128455http://dx.doi.org/10.1016/j.cej.2021.128455
YANG C, LIU Q S, HUANG D X, et al. Study on the mechanism of improved luminescence in SrB2Si2O8∶Ce3+/Tb3+ phosphor [J]. J. Lumin., 2019, 214: 116541. doi: 10.1016/j.jlumin.2019.116541http://dx.doi.org/10.1016/j.jlumin.2019.116541
ZHANG Y, ZHANG X J, ZHANG H R, et al. Enhanced absorption of Sr3Lu2 (BO3)4∶Ce3+, Tb3+ phosphor with energy transfer for UV-pumped white LEDs [J]. J. Alloys Compd., 2019, 789: 215-220. doi: 10.1016/j.jallcom.2019.03.088http://dx.doi.org/10.1016/j.jallcom.2019.03.088
尹学爱, 吕树臣. Sr0.3Ca0.7MoO4∶Tb3+,Eu3+荧光粉的颜色可调发光和温度传感特性 [J]. 发光学报, 2023, 44 (4): 607-614.
YIN X A, LYU S C. Color-tunable luminescence and temperature sensing behavior of Sr0.3Ca0.7MoO4∶Tb3+,Eu3+ phosphor [J]. Chin. J. Lumin., 2023, 44(4): 607-614. (in Chinese)
冷稚华, 谭哲, 刘书宏. 发光颜色可调的Ba3YB9O18∶Tb3+, Eu3+荧光粉及能量传递 [J]. 发光学报, 2021, 42 (1): 83-90.
LENG Z H, TAN Z, LIU S H. Tunable photoluminescence properties and energy transfer of Ba3YB9O18∶Tb3+,Eu3+ phosphors [J]. Chin. J. Lumin., 2021, 42(1): 83-90. (in Chinese)
HU X F, YAN S R, MA L, et al. Preparation of LaPO4∶Ce, Tb phosphor with different morphologies and their fluorescence properties [J]. Powder Technol., 2009, 192(1): 27-32. doi: 10.1016/j.powtec.2008.11.006http://dx.doi.org/10.1016/j.powtec.2008.11.006
XIA T, CAO W H, LUO X X, et al. Combustion synthesis and spectra characteristic of Gd2O2S∶Tb3+ and La2O2S∶Eu3+ X-ray phosphors [J]. J. Mater. Res., 2005, 20(9): 2274-2278. doi: 10.1557/jmr.2005.0301http://dx.doi.org/10.1557/jmr.2005.0301
PARK B K, LEE S S, KANG J K, et al. Single-step solid-state synthesis of CeMgAl11O19∶Tb phosphor [J]. Bull. Korean Chem. Soc., 2007, 28(9): 1467-1471.
YIN L J, XIE W J, WANG M, et al. Insight into the evolution mechanism of carbon film and Eu valence in carbon coated BaMgAl10O17∶Eu2+ phosphor annealed in air [J]. Ceram. Int., 2018, 44(8): 8898-8903. doi: 10.1016/j.ceramint.2018.02.080http://dx.doi.org/10.1016/j.ceramint.2018.02.080
ZHANG J C, ZHOU M J, LIU B T, et al. The ultraviolet irradiation degradation of fluorescent lamp used BaMgAl10O17∶Eu2+, Mn2+ phosphor [J]. J. Lumin., 2012, 132(8): 1949-1952. doi: 10.1016/j.jlumin.2012.03.033http://dx.doi.org/10.1016/j.jlumin.2012.03.033
WANG L, SETO T, WANG Y H. A new efficient deep-red-emission phosphor Al2O3∶Cr3+/Y3Al5O12∶Ce3+ for plant growth [J]. Dalton Trans., 2021, 50(10): 3542-3549. doi: 10.1039/d0dt04244ghttp://dx.doi.org/10.1039/d0dt04244g
WANG C H, GUO D F, LI Z F, et al. Crystal structure of Sr6Y2Al4O15:XRD refinements and first-principle calculations [J]. J. Solid State Chem., 2012, 192: 195-200. doi: 10.1016/j.jssc.2012.04.018http://dx.doi.org/10.1016/j.jssc.2012.04.018
YANG J K, DING J W, XIAO S G, et al. Luminescence properties of Yb3+/Ho3+ co-doped Sr3YAl2O7.5 and Sr3LuAl2O7.5 powders [J]. J. Alloys Compd., 2013, 577: 86-89. doi: 10.1016/j.jallcom.2013.04.188http://dx.doi.org/10.1016/j.jallcom.2013.04.188
TAO Z X, ZHANG W Q, QIN L, et al. A yellow-emitting nanophosphor of Ce3+-activated aluminate Sr3LuAl2O7.5 [J]. J. Alloys Compd., 2014, 588: 540-545. doi: 10.1016/j.jallcom.2013.11.128http://dx.doi.org/10.1016/j.jallcom.2013.11.128
WANG Y C, DING J Y, LI Y Y, et al. A novel single-phase warm white emission phosphor Sr3YAl2O7.5∶Bi3+, Eu3+ with energy transfer for UV white LEDs [J]. RSC Adv., 2016, 6(48): 42618-42626. doi: 10.1039/c6ra05445ehttp://dx.doi.org/10.1039/c6ra05445e
DALAL H, SEHRAWAT P, SHEORAN M, et al. Optical, crystallographic and Judd-Ofelt analysis of europium doped Sr6Y2Al4O15 nanocrystals for NUV-WLED fabrication [J]. J. Mater. Sci. Mater. Electron., 2022, 33(2): 767-781. doi: 10.1007/s10854-021-07347-7http://dx.doi.org/10.1007/s10854-021-07347-7
HAYNES W M. CRC Handbook of Chemistry and Physics [M]. 95th ed. Boca Raton: CRC Press, 2014: 120. doi: 10.1201/b17118http://dx.doi.org/10.1201/b17118
曹铷, 田莲花. Tb3+和Ce3+在Sr7Zr (PO4)6基质中能量传递及发光特性研究 [J]. 发光学报, 2017, 38(4): 450-456.
CAO R, TIAN L H. Luminescence properties and energy transfer between Ce3+ and Tb3+ in Sr7Zr(PO4)6 [J]. Chin. J. Lumin., 2017, 38 (4): 450-456. (in Chinese)
朱宪忠, 储成林. Tb3+在Lu3Ga5O12中的光致发光性质及浓度猝灭机制 [J]. 硅酸盐学报, 2015, 43(7): 963-968. doi: 10.14062/j.issn.0454-5648.2015.07.18http://dx.doi.org/10.14062/j.issn.0454-5648.2015.07.18
ZHU X Z, CHU C L. Photoluminescent properties and mechanism of concentration quenching of Tb3+ in Lu3Ga5O12 [J]. J. Chin. Ceram. Soc., 2015, 43 (7): 963-968. (in Chinese). doi: 10.14062/j.issn.0454-5648.2015.07.18http://dx.doi.org/10.14062/j.issn.0454-5648.2015.07.18
叶博, 李贵花, 王荣荣, 等. Na3Sc2 (BO3)3∶Tb3+反热猝灭荧光粉制备及其发光性能 [J]. 发光学报, 2023, 44 (4): 598-606. doi: 10.37188/cjl.20220342http://dx.doi.org/10.37188/cjl.20220342
YE B, LI G H, WANG R R, et al. Preparation and luminescence properties for Na3Sc2 (BO3)3∶Tb3+ phosphors with anti-thermal-quenching phenomenon [J]. Chin. J. Limin., 2023, 44(4): 598-606. (in Chinese). doi: 10.37188/cjl.20220342http://dx.doi.org/10.37188/cjl.20220342
ZHANG Z Y, ZHANG Y H, LI X L, et al. VUV⁃UV luminescence of magnetoplumbite: (Sr0.96-xBa0.04)Al12-yMgyO19∶Tbx [J]. J. Lumin., 2008, 128(3): 476-480. doi: 10.1016/j.jlumin.2007.09.021http://dx.doi.org/10.1016/j.jlumin.2007.09.021
HUANG X Y, LIANG J, RTIMI S, et al. Ultra-high color rendering warm-white light-emitting diodes based on an efficient green-emitting garnet phosphor for solid-state lighting [J]. Chem. Eng. J., 2021, 405: 126950. doi: 10.1016/j.cej.2020.126950http://dx.doi.org/10.1016/j.cej.2020.126950
WANG S Y, DEVAKUMAR B, SUN Q, et al. Highly efficient near-UV-excitable Ca2YHf2Al3O12∶Ce3+, Tb3+ green-emitting garnet phosphors with potential application in high color rendering warm-white LEDs [J]. J. Mater. Chem. C, 2020, 8(13): 4408-4420. doi: 10.1039/d0tc00130ahttp://dx.doi.org/10.1039/d0tc00130a
LI L, TANG X H, WU Z J, et al. Simultaneously tuning emission color and realizing optical thermometry via efficient Tb3+→Eu3+ energy transfer in whitlockite-type phosphate multifunctional phosphors [J]. J. Alloys Compd., 2019, 780: 266-275. doi: 10.1016/j.jallcom.2018.11.378http://dx.doi.org/10.1016/j.jallcom.2018.11.378
LI B, HUANG X Y, GUO H, et al. Energy transfer and tunable photoluminescence of LaBWO6∶Tb3+, Eu3+ phosphors for near-UV white LEDs [J]. Dyes Pigm., 2018, 150: 67-72. doi: 10.1016/j.dyepig.2017.11.003http://dx.doi.org/10.1016/j.dyepig.2017.11.003
ANNADURAI G, JAYACHANDIRAN M, KENNEDY S M M, et al. Synthesis and photoluminescence properties of Ba2CaZn2Si6O17∶Tb3+ green phosphor [J]. Mater. Sci. Eng. B, 2016, 208: 47-52. doi: 10.1016/j.mseb.2016.02.008http://dx.doi.org/10.1016/j.mseb.2016.02.008
YAHIAOUI Z, HASSAIRI M A, DAMMAK M, et al. Tunable luminescence and energy transfer properties in YPO4∶Tb3+, Eu3+/Tb3+ phosphors [J]. J. Lumin., 2018, 194: 96-101. doi: 10.1016/j.jlumin.2017.10.001http://dx.doi.org/10.1016/j.jlumin.2017.10.001
张思远. 稀土离子的光谱学 [M]. 北京: 科学出版社, 2008: 140.
ZHANG S Y. Spectorscopy of Rare Earth Ions [M]. Beijing: Science Press, 2008: 140. (in Chinese)
欧奕意, 王笑军, 梁宏斌. K3La(PO4)2基质中Tb3+的发光和能量传递 [J]. 发光学报, 2022, 43(9): 1350-1360.
OU Y Y, WANG X J, LIANG H B. Luminescence and energy transfer of Tb3+ in K3La(PO4)2 [J]. Chin. J. Lumin., 2022, 43(9): 1350-1360. (in Chinese)
BLASSE G. Energy transfer in oxidic phosphors [J]. Phys. Lett. A, 1968, 28(6): 444-445. doi: 10.1016/0375-9601(68)90486-6http://dx.doi.org/10.1016/0375-9601(68)90486-6
DEXTER D L. A theory of sensitized luminescence in solids [J]. J. Chem. Phys., 1953, 21(5): 836-850. doi: 10.1063/1.1699044http://dx.doi.org/10.1063/1.1699044
0
Views
97
下载量
0
CSCD
Publicity Resources
Related Articles
Related Author
Related Institution