Structure-property Relationship of Organic Electroluminescent Materials with Dimeric Quinoline Structure

LIU Tengxiao

doi:10.37188/CJL.20230139

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Structure-property Relationship of Organic Electroluminescent Materials with Dimeric Quinoline Structure

Synthesis and Properties of Materials | 更新时间：2026-09-12

- Structure-property Relationship of Organic Electroluminescent Materials with Dimeric Quinoline Structure
  增强出版
- Chinese Journal of Luminescence Vol. 44, Issue 10, Pages: 1803-1810(2023)
- 作者机构：
  
  长江工程职业技术学院，湖北武汉　430200
- 作者简介：
- 基金信息：
  
  Natural Science Foundation of Zhejiang Provincial(LQ19E030015)
- DOI：10.37188/CJL.20230139
  CLC： O482.31
- Received：29 May 2023，
  
  Revised：2023-06-15，
  
  Published：05 October 2023
- 稿件说明：
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刘腾霄.具有二聚喹啉结构的有机电致发光材料的构性关系[J].发光学报,2023,44(10):1803-1810.

LIU Tengxiao.Structure-property Relationship of Organic Electroluminescent Materials with Dimeric Quinoline Structure[J].Chinese Journal of Luminescence,2023,44(10):1803-1810.
刘腾霄.具有二聚喹啉结构的有机电致发光材料的构性关系[J].发光学报,2023,44(10):1803-1810. DOI： 10.37188/CJL.20230139.

LIU Tengxiao.Structure-property Relationship of Organic Electroluminescent Materials with Dimeric Quinoline Structure[J].Chinese Journal of Luminescence,2023,44(10):1803-1810. DOI： 10.37188/CJL.20230139.

摘要

采用Suzuki耦合反应将两个喹啉受体连接在一起成为电子受体（acceptor），通过连接给电子能力不同的给体基团（donor），合成出三个新型的线性二聚体发光材料：BtCzPPQ、DCPPQ和PZPPQ。三个材料均具有良好的刚性、热稳定性（

220 ℃），以及较高的光致发光量子产率（70%以上）。通过对材料轨道分布、热稳定性、光物理性质的表征，分析了分子的刚性、线性长度和给受体基团等结构因素对材料电致发光性能的影响。

Abstract

Three novel linear dimeric luminescent materials， BtCzPPQ， DCPPQ and PZPPQ， were synthesized by linking two quinoline receptors together into an electron acceptor （A） using the Suzuki coupling reaction， and by linking donor groups （D） with different electronic donated moiety. All the three materials have good rigidity， thermal stability （

220 ℃）， and high photoluminescence quantum yields （PLQYs more than 70%）. The effects of structural factors such as the rigidity of molecules， linear length， and the donor group on the electroluminescence properties of the materials were analyzed by characterizing the orbital distribution， thermal stability， and photophysical properties of the materials.

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