Eu<sup>3+</sup> Doping Induced Phase Transition in CsAgCl<sub>2</sub> and Its Optical Temperature Sensing Properties

ZHAO Mengzhen; LI Chao; ZHANG Feng; WAN Bingyi; LI Bing; LIU Jie; WANG Feijiu

doi:10.37188/CJL.20230129

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Eu³⁺ Doping Induced Phase Transition in CsAgCl₂ and Its Optical Temperature Sensing Properties

Synthesis and Properties of Materials | 更新时间：2023-11-27

- Eu³⁺ Doping Induced Phase Transition in CsAgCl₂ and Its Optical Temperature Sensing Properties
  增强出版
- Chinese Journal of Luminescence Vol. 44, Issue 11, Pages: 1950-1957(2023)
- 作者机构：
  
  1.河南大学未来技术学院，光伏材料省重点实验室，河南开封　475001
  2.河南大学拓扑功能材料研究中心，河南开封　475001
- 作者简介：
- 基金信息：
  
  the National Natural Science Foundation of China(52002114;12174086);the Natural Science Foundation of Henan Province(232300421201)
- DOI：10.37188/CJL.20230129
  CLC： O482.31
- Published：05 November 2023，
  
  Received：12 May 2023，
  
  Revised：29 May 2023，
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赵梦真,李超,张凤等.Eu³⁺掺杂诱导CsAgCl₂相变及其光学温度传感性质[J].发光学报,2023,44(11):1950-1957.

ZHAO Mengzhen,LI Chao,ZHANG Feng,et al.Eu³⁺ Doping Induced Phase Transition in CsAgCl₂ and Its Optical Temperature Sensing Properties[J].Chinese Journal of Luminescence,2023,44(11):1950-1957.
赵梦真,李超,张凤等.Eu³⁺掺杂诱导CsAgCl₂相变及其光学温度传感性质[J].发光学报,2023,44(11):1950-1957. DOI： 10.37188/CJL.20230129.

ZHAO Mengzhen,LI Chao,ZHANG Feng,et al.Eu³⁺ Doping Induced Phase Transition in CsAgCl₂ and Its Optical Temperature Sensing Properties[J].Chinese Journal of Luminescence,2023,44(11):1950-1957. DOI： 10.37188/CJL.20230129.

摘要

相变是调节材料性能的一种有效方法，在介电、光电、光致发光等领域有着广泛的应用。本文采用水热法合成未知相CsAgCl

，并通过升温和Eu

掺杂将CsAgCl

从未知相转变为正交相。制备的Eu

掺杂的CsAgCl

具有较高的光学温度灵敏度，在荧光强度模式和荧光寿命模式下的最大相对灵敏度分别为3.63%·K

-1

和3.20%·K

-1

。结果表明，CsAgCl

是一种很有前途的高灵敏度光学温度传感材料。

Abstract

Phase transition is an effective way to regulate performance of materials and has been wildly applied in dielectric， photo-electricity and photoluminescence fields. Here， we report the hydrothermal synthesis of unknown phase CsAgCl

and the phase transition of CsAgCl

from unknown phase to orthogonal phase

via

annealing and Eu

doping strategies. The as-prepared Eu

doping CsAgCl

exhibits high optical temperature sensitivities with the maximum relative sensitivity values of 3.63%·K

-1

and 3.20%·K

-1

for emission intensity mode and decay lifetime mode， respectively. These results indicate that CsAgCl

is a promising candidate to be used as a high-sensitive optical temperature sensing material.

关键词

相变光学温度传感水热合成CsAgCl2Eu3+掺杂

Keywords

phase transitionoptical temperature sensinghydrothermal synthesisCsAgCl2Eu3+ doping

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⁰

Eu3+ Doping Induced Phase Transition in CsAgCl2 and Its Optical Temperature Sensing Properties

DOI：10.37188/CJL.20230129

摘要

Abstract

关键词

Keywords

references

Eu³⁺ Doping Induced Phase Transition in CsAgCl₂ and Its Optical Temperature Sensing Properties