Research Progress on Organic-Inorganic Hybrid Cuprous Halide Scintillators

ZHANG Jiabei; WANG Chao; XIAO Jiawen; QU Yao; YAN Zhengguang

doi:10.37188/CJL.20230108

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Research Progress on Organic-Inorganic Hybrid Cuprous Halide Scintillators

更新时间：2023-06-13

- Research Progress on Organic-Inorganic Hybrid Cuprous Halide Scintillators
  增强出版
- Chinese Journal of Luminescence Pages: 1-16(2023)
- 作者机构：
  
  1.北京工业大学材料与制造学部，北京朝阳　100124
- 作者简介：
- 基金信息：
  
  Beijing Natural Science Foundation(2222050);National Natural Science Foundation of China(12174016)
- DOI：10.37188/CJL.20230108
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ZHANG Jiabei, WANG Chao, XIAO Jiawen, et al. Research Progress on Organic-Inorganic Hybrid Cuprous Halide Scintillators. [J/OL]. Chinese Journal of Luminescence 1-16(2023)
DOI：

ZHANG Jiabei, WANG Chao, XIAO Jiawen, et al. Research Progress on Organic-Inorganic Hybrid Cuprous Halide Scintillators. [J/OL]. Chinese Journal of Luminescence 1-16(2023) DOI： 10.37188/CJL.20230108.

摘要

近年来，有机-无机杂化金属卤化物材料由于其优异的光电性质引起了研究人员的广泛关注。其中低维铜（I）基卤化物作为高效发光材料的代表，在照明与显示、辐射探测等领域表现出良好的应用前景。有机无机杂化铜（I）基卤化物的组成和结构丰富多变，给研究人员提供了巨大的研究空间。本文综述了有机-无机杂化铜（I）基卤化物作为发光材料的研究进展，并以［CuX,n,］（X=Cl，Br，I）结构单元及其连接方式为依据，对离子型有机-无机杂化铜（I）基卤化物进行了系统地分类，总结了其组成-结构-性质之间的构效关系。讨论了有机-无机杂化铜（I）基卤化物的发光机制和光物理过程，并重点归纳了用于X射线探测的有机-无机杂化铜（I）基卤化物闪烁体的最新进展。最后，对这一新兴的研究领域做出了展望。

Abstract

In recent years， organic inorganic hybrid metal halide materials have attracted great attention due to their excellent luminescent properties. In particular， low-dimensional copper （I） based halides， as a representative of highly efficient luminescent materials， show great potential in scintillators for radiation detection. In this paper， the research of organic inorganic hybrid copper （I） based halides as luminescent materials is reviewed. Based on the ［CuX,n,］（X=Cl， Br， I） structural unit and its connection modes， ionic organic inorganic hybrid copper （I） based halides are systematically classified， and the relationship between their composition， structure， and properties is discussed. We focus on the photophysical process and luminescence mechanism of organic-inorganic hybrid copper （I） based halides. Finally， we summarize the latest progress in organic inorganic hybrid copper （I） based halide scintillators for X-ray detection， and make a prospect for this novel research perspective.

关键词

有机-无机杂化铜（I）基卤化物低维结构发光材料闪烁体

Keywords

organic inorganic hybrid copper （I） based halidesluminescent materialsscintillators

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