Synthesis and Characterization of Aggregation-induced Red Emitter Based on Dibenzophenazine Core

XING Yifan; SHI Mingkai; LI Zhijun; LI Da; DONG Linlin; LUO Yang; ZHAO Shijie; XIE Tianyou; WANG Hua; GUO Kunpeng; MIAO Yanqin

doi:10.37188/CJL.20230096

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Synthesis and Characterization of Aggregation-induced Red Emitter Based on Dibenzophenazine Core

Synthesis and Properties of Materials | 更新时间：2023-09-28

- Synthesis and Characterization of Aggregation-induced Red Emitter Based on Dibenzophenazine Core
  增强出版
- Chinese Journal of Luminescence Vol. 44, Issue 9, Pages: 1588-1596(2023)
- 作者机构：
  
  1.太原理工大学新材料界面科学与工程教育部重点实验室，山西太原　030024
- 作者简介：
- 基金信息：
  
  国家自然科学基金(62074109;6207031407);Science and Technology Innovation Talent Team Project of Shanxi Province(202204051001013)
- DOI：10.37188/CJL.20230096
  CLC：
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XING Yifan, SHI Mingkai, LI Zhijun, et al. Synthesis and Characterization of Aggregation-induced Red Emitter Based on Dibenzophenazine Core. [J]. Chinese Journal of Luminescence 44(9):1588-1596(2023)
DOI：

XING Yifan, SHI Mingkai, LI Zhijun, et al. Synthesis and Characterization of Aggregation-induced Red Emitter Based on Dibenzophenazine Core. [J]. Chinese Journal of Luminescence 44(9):1588-1596(2023) DOI： 10.37188/CJL.20230096.

摘要

有机红光材料在全色显示、生物成像及荧光探针等方面有着重要的应用前景。本文以电子受体二苯并吩嗪为核，在其3，6位引入给电子基二苯胺衍生物，在其11，12位引入拉电子基吡啶，设计并合成了一种具有给⁃受体结构的化合物,DBPAP,。通过元素分析、核磁共振波谱和质谱对化合物的化学结构进行了表征与确认。荧光发射光谱表征发现，,DBPAP,在四氢呋喃和水的混合溶剂中随不良溶剂水含量增加呈现出典型的聚集诱导发光现象。基于其在固态下的有效红光发射，将,DBPAP,掺杂到PMMA中制备了红光LED器件。在3.8 V工作电压下，器件的最大发射波长为644 nm，CIE坐标为（0.58，0.35），最大亮度为1 616 cd·m,-2,。该工作为发展新型固态有机红光材料提供了重要思路。

Abstract

Organic red emitters have attracted significant research attention owing to their promising applications in panchromatic display， biological imaging， and fluorescent probes. Herein， a fluorescent compound ,DBPAP, was developed by introducing electron-donating group diphenylamine derivative at the positions of 3 and 6， and electron-withdrawing group pyridine at the positions of 11 and 12 of dibenzophenazine core. Its chemical structure was characterized and confirmed by elemental analysis， nuclear magnetic resonance spectroscopy and mass spectroscopy. Spectroscopic results showed that the addition of the poor solvent water to the tetrahydrofuran solution of ,DBPAP, caused obvious aggregation-induced emission （AIE） phenomenon. Based on its efficient red emission in solid state， LED devices based on ,DBPAP, doped PMMA were fabricated. The devices exhibited a red emission at 644 nm with Commission Internationale de L’Éclairage coordinates of （0.58， 0.35）， and a maximum brightness of 1 616 cd·m,-2, at a 3.8 V work voltage. This work provides a promising strategy for developing solid-state red emissive organics.

关键词

有机红光材料二苯并吩嗪给-受体聚集诱导发光红光LED

Keywords

organic red emittersdibenzophenazinedonor-acceptoraggregation-induced emissionred LED

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