Efficient Organic Light-emitting Devices Based on Ultrathin Transparent Ag<sub>2</sub>O/Ag Anodes

CHEN Huanghuang; WANG Linjia; YIN Juan; LI Guogang; WU Zhijun

doi:10.37188/CJL.20230090

您当前的位置：

首页 >

文章列表页 >

Efficient Organic Light-emitting Devices Based on Ultrathin Transparent Ag₂O/Ag Anodes

Device Fabrication and Physics | 更新时间：2023-09-28

- Efficient Organic Light-emitting Devices Based on Ultrathin Transparent Ag₂O/Ag Anodes
  增强出版
- Chinese Journal of Luminescence Vol. 44, Issue 9, Pages: 1644-1649(2023)
- 作者机构：
  
  华侨大学信息科学与工程学院，福建省光传输与变换重点实验室，福建厦门　361021
- 作者简介：
- 基金信息：
  
  National Natural Science Foundation of China(12004121)
- DOI：10.37188/CJL.20230090
  CLC： TN383.1
- Published：05 September 2023，
  
  Received：12 April 2023，
  
  Revised：26 April 2023，
- 稿件说明：
移动端阅览
陈煌煌,王琳嘉,尹娟等.基于超薄透明Ag₂O/Ag阳极的高效有机电致发光器件[J].发光学报,2023,44(09):1644-1649.

CHEN Huanghuang,WANG Linjia,YIN Juan,et al.Efficient Organic Light-emitting Devices Based on Ultrathin Transparent Ag₂O/Ag Anodes[J].Chinese Journal of Luminescence,2023,44(09):1644-1649.
陈煌煌,王琳嘉,尹娟等.基于超薄透明Ag₂O/Ag阳极的高效有机电致发光器件[J].发光学报,2023,44(09):1644-1649. DOI： 10.37188/CJL.20230090.

CHEN Huanghuang,WANG Linjia,YIN Juan,et al.Efficient Organic Light-emitting Devices Based on Ultrathin Transparent Ag₂O/Ag Anodes[J].Chinese Journal of Luminescence,2023,44(09):1644-1649. DOI： 10.37188/CJL.20230090.

摘要

提出了一种通过在玻璃衬底表面引入氧化银种子层的方法，成功制备了具有良好表面、光学、电学特性的超薄透明导电Ag薄膜。首先，在玻璃衬底上用热沉积的方法生长1 nm Ag薄膜，然后对该薄膜进行空气等离子体处理，生成氧化银种子层，该种子层可抑制Ag原子的随机迁移，提高随后沉积Ag原子成核密度，从而促进Ag原子快速成膜。以该超薄透明氧化银/银薄膜为阳极，实现了一种高效磷光有机电致发光器件，器件的最大电流效率、功率效率分别为60.4 cd·A

-1

和63.2 lm·W

-1

，是常规ITO器件的1.45倍和1.60倍。该研究结果表明，以氧化银为种子层的超薄透明Ag薄膜是极具发展潜力的透明导电电极。

Abstract

This paper proposes a strategy to successfully realize ultra-thin transparent conductive Ag thin films with excellent surface， optical， and electrical properties by introducing a silver oxide seed layer onto the surface of a glass substrate. Firstly， a 1-nm-thick Ag film is evaporated onto a glass substrate by thermal deposition and then treated with oxygen plasma to generate a silver oxide seed layer. The seed layer can alleviate the random migration of Ag atoms and improve the nucleation density of the subsequently deposited Ag atoms， thus promoting the film formation of Ag atoms. An efficient phosphorescent organic light-emitting device was fabricated using the realized ultra-thin transparent silver oxide/silver film as an anode. The device's maximum current efficiency and power efficiency are 60.4 cd·A

-1

and 63.2 lm·W

-1

， respectively， 1.45 and 1.60 times higher than those of the conventional ITO-based devices. The results show that the ultra-thin transparent Ag thin film with silver oxide as a seed layer is a highly promising transparent conductive electrode.

关键词

氧化银空气等离子体透明阳极有机电致发光器件

Keywords

Ag2Oair plasmatransparent anodeorganic light⁃emitting device（OLED）

references

邹建华，朱冠成，王磊，等. 有机电致发光器件及显示驱动研究进展［J］. 发光学报， 2023， 44（1）： 198-217. doi: 10.37188/CJL.20220322http://dx.doi.org/10.37188/CJL.20220322

ZOU J H， ZHU G C， WANG L， et al. Research progress on organic light-emitting diodes and display drive ［J］. Chin. J. Lumin.， 2023， 44（1）： 198-217. （in Chinese）. doi: 10.37188/CJL.20220322http://dx.doi.org/10.37188/CJL.20220322

刘萍，李宇，韦闯闯，等. 界面调控对柔性量子点电致发光器件性能的影响［J］. 发光学报， 2023， 44（4）： 641-656. doi: 10.37188/cjl.20220345http://dx.doi.org/10.37188/cjl.20220345

LIU P， LI Y， WEI C C， et al. Effects of interface regulation on performances of flexible quantum dot electroluminescent devices ［J］. Chin. J. Lumin.， 2023， 44（4）： 641-656. （in Chinese）. doi: 10.37188/cjl.20220345http://dx.doi.org/10.37188/cjl.20220345

吴晓晓，李福山，吴薇，等. 基于石墨烯/PEDOT∶PSS叠层薄膜的柔性OLED器件［J］. 发光学报， 2014， 35（4）： 486-490. doi: 10.3788/fgxb20143504.0486http://dx.doi.org/10.3788/fgxb20143504.0486

WU X X， LI F S， WU W， et al. Flexible organic light emitting diodes based on double-layered graphene/PEDOT∶PSS conductive film ［J］. Chin. J. Lumin.， 2014， 35（4）： 486-490. （in Chinese）. doi: 10.3788/fgxb20143504.0486http://dx.doi.org/10.3788/fgxb20143504.0486

TIAN Y， WANG T， ZHU Q X， et al. High-performance transparent PEDOT∶PSS/CNT films for OLEDs ［J］. Nanomaterials， 2021， 11（8）： 2067. doi: 10.3390/nano11082067http://dx.doi.org/10.3390/nano11082067

杨桢林，费纯纯，成程，等. 柔性有机发光二极管柔性电极薄膜的研究进展［J］. 发光学报， 2019， 40（2）： 238-256. doi: 10.3788/fgxb20194002.0238http://dx.doi.org/10.3788/fgxb20194002.0238

YANG Z L， FEI C C， CHENG C， et al. Review of flexible electrode film for flexible organic light-emitting diodes ［J］. Chin. J. Lumin.， 2019， 40（2）： 238-256. （in Chinese）. doi: 10.3788/fgxb20194002.0238http://dx.doi.org/10.3788/fgxb20194002.0238

BI Y G， LIU Y F， ZHANG X L， et al. Ultrathin metal films as the transparent electrode in ITO-free organic optoelectronic devices ［J］. Adv. Opt. Mater.， 2019， 7（6）： 1800778-1-23. doi: 10.1002/adom.201800778http://dx.doi.org/10.1002/adom.201800778

SCHUBERT S， MEISS J， MÜLLER-MESKAMP L， et al. Improvement of transparent metal top electrodes for organic solar cells by introducing a high surface energy seed layer ［J］. Adv. Energy Mater.， 2013， 3（4）： 438-443. doi: 10.1002/aenm.201200903http://dx.doi.org/10.1002/aenm.201200903

LIU S H， LIU W B， YU J， et al. Silver/germanium/silver： an effective transparent electrode for flexible organic light-emitting devices ［J］. J. Mater. Chem. C， 2014， 2（5）： 835-840. doi: 10.1039/c3tc31927jhttp://dx.doi.org/10.1039/c3tc31927j

许君君，黄金华，盛伟，等. 超薄金属透明导电膜及其应用研究进展［J］. 材料导报， 2019， 33（11）： 1875-1881. doi: 10.11896/cldb.18040164http://dx.doi.org/10.11896/cldb.18040164

XU J J， HUANG J H， SHENG W， et al. Research progress on ultrathin metal transparent conductive films and their applications ［J］. Mater. Rep.， 2019， 33（11）： 1875-1881. （in Chinese）. doi: 10.11896/cldb.18040164http://dx.doi.org/10.11896/cldb.18040164

HAN Y C， LIM M S， PARK J H， et al. ITO-free flexible organic light-emitting diode using ZnS/Ag/MoO3 anode incorporating a quasi-perfect Ag thin film ［J］. Org. Electron.， 2013， 14（12）： 3437-3443. doi: 10.1016/j.orgel.2013.09.014http://dx.doi.org/10.1016/j.orgel.2013.09.014

ZHANG C， ZHAO D W， GU D E， et al. An ultrathin， smooth， and low-loss Al-doped Ag film and its application as a transparent electrode in organic photovoltaics ［J］. Adv. Mater.， 2014， 26（32）： 5696-5701. doi: 10.1002/adma.201306091http://dx.doi.org/10.1002/adma.201306091

HUANG J H， LIU X H， LU Y H， et al. Seed-layer-free growth of ultra-thin Ag transparent conductive films imparts flexibility to polymer solar cells ［J］. Sol. Energy Mater. Sol. Cells， 2018， 184： 73-81. doi: 10.1016/j.solmat.2018.04.002http://dx.doi.org/10.1016/j.solmat.2018.04.002

ZHAO G Q， SHEN W F， JEONG E， et al. Ultrathin silver film electrodes with ultralow optical and electrical losses for flexible organic photovoltaics ［J］. ACS Appl. Mater. Interfaces， 2018， 10（32）： 27510-27520. doi: 10.1021/acsami.8b08578http://dx.doi.org/10.1021/acsami.8b08578

ANTHONY M T， SEAH M P. XPS： energy calibration of electron spectrometers. Ⅰ： an absolute， traceable energy calibration and the provision of atomic reference line energies ［J］. Surf. Interface Anal.， 1984， 6（3）： 95-106. doi: 10.1002/sia.740060302http://dx.doi.org/10.1002/sia.740060302

TJENG L H， MEINDERS M B J， VAN ELP J， et al. Electronic structure of Ag2O ［J］. Phys. Rev. B， 1990， 41（5）： 3190-3199.

曹修东，张会红，田野，等. 基于表面等离子体共振效应的荧光太阳集光器制备及其性能［J］. 发光学报， 2022， 43（3）： 396-403. doi: 10.37188/cjl.20210387http://dx.doi.org/10.37188/cjl.20210387

CAO X D， ZHANG H H， TIAN Y， et al. Preparation and performance of luminescent solar concentrator based on surface plasmon resonance effect ［J］. Chin. J. Lumin.， 2022， 43（3）： 396-403. （in Chinese）. doi: 10.37188/cjl.20210387http://dx.doi.org/10.37188/cjl.20210387

SALANECK W R. Classical ultraviolet photoelectron spectroscopy of polymers ［J］. J. Electron. Spectrosc. Relat. Phenom.， 2009， 174（1-3）： 3-9. doi: 10.1016/j.elspec.2009.03.024http://dx.doi.org/10.1016/j.elspec.2009.03.024

于荣梅，濮春英，殷复荣，等. 超低效率滚降顶发射白光有机电致发光器件［J］. 发光学报， 2022， 43（1）： 77-84. doi: 10.37188/CJL.20210325http://dx.doi.org/10.37188/CJL.20210325

YU R M， PU C Y， YIN F R， et al. Ultra-low efficiency roll-off top-emitting white organic light-emitting diodes ［J］. Chin. J. Lumin.， 2022， 43（1）： 77-84. （in Chinese）. doi: 10.37188/CJL.20210325http://dx.doi.org/10.37188/CJL.20210325

Views

178

下载量

CSCD

Alert me when the article has been cited

提交

Tools

Publicity Resources

Highly Efficient Narrow Emission Blue OLED Devices Based on Dinaphtho[2,3-B∶2′,3′-D]furan Moiety

Synthesis and Luminescence Property of Four Phosphorescent Iridium(Ⅲ) Pyrazine Complexes

Preparation of Transparent Conductive Praseodymium Titanate Doped Indium Oxide Film and Its Application in Organic Opto-electronic Devices

High-performance Organic Light-emitting Diodes Based on ILTO Thin Film

Related Author

CHENG Huanghuang

WANG Linjia

YIN Juan

LI Guo-gang

WU Zhijun

PENG Qiming

WANG Xiaowei

YUAN Jiangbo

Related Institution

College of Information Science and Engineering， Fujian Provincial Key Laboratory of Light Propagation and Transformation， Huaqiao University

Institute of Advanced Materials， Nanjing Tech University

Xi’an Manareco New Materials Co.， Ltd.

College of Chemistry and Molecular Engineering, Peking University

State Key Laboratory Base of Novel Functional Materials and Preparation Science, Faculty of Materials Science and Chemical Engineering, Ningbo University

Address：No.3888 Dong Nanhu Road, Changchun, Jilin, China Postal code：130033
Tel：0431-86176862 Email：fgxbt@126.com
Technical support is provided by Beijing Founder electronics co., LTD 吉ICP备11002662号-17 京公网安备11010802024621
It is recommended to read the content of this site in Chrome&IE9+. Please switch to extreme mode in browser 360.
Cookies We use cookies to help provide and enhance our service and tailor content. By continuing, you agree to the use of cookies.

⁰

Efficient Organic Light-emitting Devices Based on Ultrathin Transparent Ag2O/Ag Anodes

DOI：10.37188/CJL.20230090

摘要

Abstract

关键词

Keywords

references

Efficient Organic Light-emitting Devices Based on Ultrathin Transparent Ag₂O/Ag Anodes