Ratiometric Photon-upconversion Cryometer Based on Er<sup>3+</sup>/Tm<sup>3+</sup> Partition Doped Nanostructure

WU Han; CHEN Haoran; XIE Xiaoyu; TU Langping; LI Qiqing; KONG Xianggui; CHANG Yulei

doi:10.37188/CJL.20230073

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Ratiometric Photon-upconversion Cryometer Based on Er³⁺/Tm³⁺ Partition Doped Nanostructure

Cover Story | 更新时间：2023-09-06

- Ratiometric Photon-upconversion Cryometer Based on Er³⁺/Tm³⁺ Partition Doped Nanostructure
  增强出版
- Chinese Journal of Luminescence Vol. 44, Issue 8, Pages: 1335-1343(2023)
- 作者机构：
  
  1.中国科学院长春光学精密机械与物理研究所发光学及应用国家重点实验室，吉林长春　130033
  2.中国科学院大学，北京　100049
- 作者简介：
- 基金信息：
  
  the National Key Research and Development Program of China(2021YFA0715603);The National Natural Science Foundation of China(62075217);Project of Science and Technology Agency, Jilin Province(20210101148JC;202512JC010475440;20230508104RC);The State Key Laboratory of Luminescence and Applications(SKLA⁃2019⁃02;SKLA⁃2020⁃09)
- DOI：10.37188/CJL.20230073
  CLC： O482.31
- Published：05 August 2023，
  
  Received：27 March 2023，
  
  Revised：11 April 2023，
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吴晗,陈浩然,解小雨等.Er³⁺/Tm³⁺分区掺杂结构的比率型光子上转换低温探针[J].发光学报,2023,44(08):1335-1343.

WU Han,CHEN Haoran,XIE Xiaoyu,et al.Ratiometric Photon-upconversion Cryometer Based on Er³⁺/Tm³⁺ Partition Doped Nanostructure[J].Chinese Journal of Luminescence,2023,44(08):1335-1343.
吴晗,陈浩然,解小雨等.Er³⁺/Tm³⁺分区掺杂结构的比率型光子上转换低温探针[J].发光学报,2023,44(08):1335-1343. DOI： 10.37188/CJL.20230073.

WU Han,CHEN Haoran,XIE Xiaoyu,et al.Ratiometric Photon-upconversion Cryometer Based on Er³⁺/Tm³⁺ Partition Doped Nanostructure[J].Chinese Journal of Luminescence,2023,44(08):1335-1343. DOI： 10.37188/CJL.20230073.

摘要

利用溶剂热法制备了六角相NaYF

∶20%Yb，2%Er@NaYF

@NaYbF

∶0.5%Tm@NaYF

多层核壳结构稀土掺杂上转换纳米粒子，研究其在低温场（10~295 K）及980 nm激发下分别来自于Er

的绿色与红色以及Tm

的蓝色发光的上转换发光性质。结果显示，绿光强度随温度升高呈现出先增后降的变化趋势，而蓝光强度随温度升高呈现热衰减的趋势。本工作利用发光强度比的测温方法实现了精准的温度测量，相对灵敏度可达3.2%·K

-1

。并通过改变外层发光壳层的厚度调节发光强度比，进一步应用于低温场光学防伪。

Abstract

Hexagonal phase NaYF

∶20%Yb，2%Er@NaYF

@NaYbF

∶0.5%Tm@NaYF

lanthanide-doped nano⁃particles with the core@multishell structure were synthesized by solvothermal method. The upconversion luminescence （UCL） properties of the materials at temperature from 10 K to 295 K were studied under 980 nm excitation. Green and red UCL from Er

and blue UCL from Tm

were observed in the visible light range. The luminescence intensity of green UCL first increased and then decreased， while the luminescence intensity of blue light showed a thermal attenuation trend with the temperature increase. The method of temperature-dependent luminescence intensity ratio （LIR） can be used in accurate temperature measurement， and the relative sensitivity is up to 3.2%·K

-1

. With various thicknesses of the outer luminescent shell， the different tendencies of LIR can be realized， which can be applied to cryogenic field anticounterfeiting.

关键词

稀土纳米粒子发光强度比测温上转换发光低温场防伪

Keywords

rare-earth nanoparticlesluminescence intensity ratio（LIR） thermometryupconversion luminescence cryogenic fieldanticounterfeiting

references

RING E F J. The historical development of temperature measurement in medicine ［J］. Infrared Phys. Technol.， 2007， 49（3）： 297-301. doi: 10.1016/j.infrared.2006.06.029http://dx.doi.org/10.1016/j.infrared.2006.06.029

LI H Y， WEI F， LI Y Z， et al. Optical fiber sensor based on upconversion nanoparticles for internal temperature monitoring of Li-ion batteries ［J］. J. Mater. Chem. C， 2021， 9（41）： 14757-14765. doi: 10.1039/d1tc03701chttp://dx.doi.org/10.1039/d1tc03701c

XU M， ZOU X M， SU Q Q， et al. Ratiometric nanothermometer in vivo based on triplet sensitized upconversion ［J］. Nat. Commun.， 2018， 9（1）： 2698-1-7. doi: 10.1038/s41467-018-05160-1http://dx.doi.org/10.1038/s41467-018-05160-1

WANG X F， LIU Q， BU Y Y， et al. Optical temperature sensing of rare-earth ion doped phosphors ［J］. RSC Adv.， 2015， 5（105）： 86219-86236. doi: 10.1039/c5ra16986khttp://dx.doi.org/10.1039/c5ra16986k

MI C， ZHOU J J， WANG F， et al. Ultrasensitive ratiometric nanothermometer with large dynamic range and photostability ［J］. Chem. Mater.， 2019， 31（22）： 9480-9487. doi: 10.1021/acs.chemmater.9b03466http://dx.doi.org/10.1021/acs.chemmater.9b03466

WANG Q， LIAO M， LIN Q M， et al. A review on fluorescence intensity ratio thermometer based on rare-earth and transition metal ions doped inorganic luminescent materials ［J］. J. Alloys Compd.， 2021， 850： 156744-1-14. doi: 10.1016/j.jallcom.2020.156744http://dx.doi.org/10.1016/j.jallcom.2020.156744

XIE X Y， WANG W， CHEN H R， et al. CaGdF5 based heterogeneous core@shell upconversion nanoparticles for sensitive temperature measurement ［J］. RSC Adv.， 2023， 13（13）： 8535-8539. doi: 10.1039/d3ra00716bhttp://dx.doi.org/10.1039/d3ra00716b

PEIJZEL P S， MEIJERINK A， WEGH R T， et al. A complete 4fn energy level diagram for all trivalent lanthanide ions ［J］. J. Solid State Chem.， 2005， 178（2）： 448-453. doi: 10.1016/j.jssc.2004.07.046http://dx.doi.org/10.1016/j.jssc.2004.07.046

NIE J H， YING W T， FAN X M， et al. Cryogenic dependent energy manipulation in nonthermally coupled levels for multicolor upconversion luminescence ［J］. J. Phy. Chem. C， 2021， 125（34）： 19040-19047. doi: 10.1021/acs.jpcc.1c06701http://dx.doi.org/10.1021/acs.jpcc.1c06701

TU L P， WU K F， LUO Y S， et al. Significant enhancement of the upconversion emission in highly Er3+-doped nanoparticles at cryogenic temperatures ［J］. Angew. Chem. Int. Ed.， 2023， 62（7）： e202217100. doi: 10.1002/anie.202217100http://dx.doi.org/10.1002/anie.202217100

SUO H， ZHU Q， ZHANG X， et al. High-security anti-counterfeiting through upconversion luminescence ［J］. Mater. Today Phys.， 2021， 21： 100520. doi: 10.1016/j.mtphys.2021.100520http://dx.doi.org/10.1016/j.mtphys.2021.100520

LIU H M， YAN L， HUANG J S， et al. Ultrasensitive thermochromic upconversion in core-shell-shell nanoparticles for nanothermometry and anticounterfeiting ［J］. J. Phys. Chem. Lett.， 2022， 13（10）： 2306-2312. doi: 10.1021/acs.jpclett.2c00005http://dx.doi.org/10.1021/acs.jpclett.2c00005

ZHOU S S， DENG K M， WEI X T， et al. Upconversion luminescence of NaYF4∶Yb3+， Er3+ for temperature sensing ［J］. Opt. Commun.， 2013， 291： 138-142. doi: 10.1016/j.optcom.2012.11.005http://dx.doi.org/10.1016/j.optcom.2012.11.005

SUYVER J F， GRIMM J， KRÄMER K W， et al. Highly efficient near-infrared to visible up-conversion process in NaYF4∶Er3+， Yb3+ ［J］. J. Lumin.， 2005， 114（1）： 53-59. doi: 10.1016/j.jlumin.2004.11.012http://dx.doi.org/10.1016/j.jlumin.2004.11.012

XIE X Y， LI Q Q， CHEN H， et al. Manipulating the injected energy flux via host-sensitized nanostructure for improving multiphoton upconversion luminescence of Tm3+ ［J］. Nano Lett.， 2022， 22（13）： 5339-5347. doi: 10.1021/acs.nanolett.2c01324http://dx.doi.org/10.1021/acs.nanolett.2c01324

WANG X F， WANG Y， MARQUES-HUESO J， et al. Improving optical temperature sensing performance of Er3+ doped Y2O3 microtubes via co-doping and controlling excitation power ［J］. Sci. Rep.， 2017， 7（1）： 758-1-13. doi: 10.1038/s41598-017-00838-whttp://dx.doi.org/10.1038/s41598-017-00838-w

LU H Y， MENG R， HAO H Y， et al. Stark sublevels of Er3+-Yb3+ codoped Gd2（WO4）3 phosphor for enhancing the sensitivity of a luminescent thermometer ［J］. RSC Adv.， 2016， 6（62）： 57667-57671. doi: 10.1039/c6ra10138khttp://dx.doi.org/10.1039/c6ra10138k

ZHENG S H， CHEN W B， TAN D Z， et al. Lanthanide-doped NaGdF4 core-shell nanoparticles for non-contact self-referencing temperature sensors ［J］. Nanoscale， 2014， 6（11）： 5675-5679. doi: 10.1039/c4nr00432ahttp://dx.doi.org/10.1039/c4nr00432a

KACZMAREK A M， LIU Y Y， WANG C H， et al. Grafting of a Eu3+-tfac complex on to a Tb3+-metal organic framework for use as a ratiometric thermometer ［J］. Dalton Trans.， 2017， 46（37）： 12717-12723. doi: 10.1039/c7dt02042bhttp://dx.doi.org/10.1039/c7dt02042b

HAOUARI M， MAAOUI A， SAAD N， et al. Optical temperature sensing using green emissions of Er3+ doped fluoro-tellurite glass ［J］. Sens. Actuators A： Phys.， 2017， 261： 235-242. doi: 10.1016/j.sna.2017.04.012http://dx.doi.org/10.1016/j.sna.2017.04.012

KACZMAREK A M， KACZMAREK M K， VAN DEUN R. Er3+-to-Yb3+ and Pr3+-to-Yb3+ energy transfer for highly efficient near-infrared cryogenic optical temperature sensing ［J］. Nanoscale， 2019， 11（3）： 833-837. doi: 10.1039/c8nr08348ghttp://dx.doi.org/10.1039/c8nr08348g

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⁰

Ratiometric Photon-upconversion Cryometer Based on Er3+/Tm3+ Partition Doped Nanostructure

DOI：10.37188/CJL.20230073

摘要

Abstract

关键词

Keywords

references

Ratiometric Photon-upconversion Cryometer Based on Er³⁺/Tm³⁺ Partition Doped Nanostructure