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1.宁波大学高等技术研究院 红外材料及器件实验室, 浙江 宁波 315211
2.浙江省光电探测材料及器件重点实验室, 浙江 宁波 315211
3.之江实验室, 浙江 杭州 311121
Published:05 August 2023,
Received:21 March 2023,
Revised:30 March 2023,
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李赛辉,康世亮,陈智等.双波长泵浦含有Er3+∶NaYF4纳米晶氟氧化物微晶玻璃的上转换发光性能[J].发光学报,2023,44(08):1390-1397.
LI Saihui,KANG Shiliang,CHEN Zhi,et al.Up-conversion Luminescence Performance of Oxyfluoride Glass-ceramic Containing Er3+∶NaYF4 Nanocrystals Under Two-wavelength Excitation[J].Chinese Journal of Luminescence,2023,44(08):1390-1397.
李赛辉,康世亮,陈智等.双波长泵浦含有Er3+∶NaYF4纳米晶氟氧化物微晶玻璃的上转换发光性能[J].发光学报,2023,44(08):1390-1397. DOI: 10.37188/CJL.20230069.
LI Saihui,KANG Shiliang,CHEN Zhi,et al.Up-conversion Luminescence Performance of Oxyfluoride Glass-ceramic Containing Er3+∶NaYF4 Nanocrystals Under Two-wavelength Excitation[J].Chinese Journal of Luminescence,2023,44(08):1390-1397. DOI: 10.37188/CJL.20230069.
高效的光调制能够显著提高光转换效率和调节光响应速率,在光电子学领域中表现出巨大的应用潜力。然而,光子之间的弱相互作用对操纵光子⁃光子相互作用造成了巨大的障碍。本文采用850 nm和1 550 nm激光同时激发含有Er
3+
∶NaYF
4
纳米晶体的氧氟化物微晶玻璃,可以实现绿色上转换荧光的快⁃慢光调制。与两束单波长激发的发光强度之和相比,双波长同时激发的绿色上转换发光强度明显提高了一个数量级。值得注意的是,绿色上转换发光快⁃慢响应速率依赖于双波长激发的泵浦策略,显示出高达4倍的快⁃慢响应差异。研究表明,双波长激发绿色上转换发光的快⁃慢光调制在新型的全光开关中具有广阔的应用前景。
Efficient optical modulation enables a prominent improvement of optical conversion efficiency and regulation of optical response rate, which shows great potential in the field of optoelectronics. However, the weak interaction between photons poses a strong obstacle for manipulating photon-photon interactivity. Here, upon simultaneous excitation of 850 nm and 1 550 nm, a fast-slow optical modulation of green up-conversion luminescence in oxyfluoride glass ceramics containing Er
3+
∶NaYF
4
nanocrystals can be achieved. Compared with the sum of the luminescence intensity with two single-wavelength excitations, the green up-conversion luminescence intensity excited by simultaneous two-wavelength presents a significant increase by an order of magnitude. It is worth noting that the fast-slow response rate of green up-conversion luminescence relies on the pump strategy of two-wavelength excitation, showing as high as four times of the fast-slow response difference. The fast-slow optical modulation of green up-conversion luminescence under two-wavelength excitation may find potential applications in emerging all-optical switching.
微晶玻璃NaYF4纳米晶双波长泵浦上转换荧光
glass-ceramicsNaYF4 nanocrystalstwo-wavelength excitationup-conversion fluorescence
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