Effect of Aqueous Electrolyte Ions on Electrochromic Properties of Amorphous WO<sub>3</sub>

XING Kaixiao; LYU Zhe; LI Yantao; LYU Ying; LI Pan; YAN Jingyu; LIU Bin; LI Shengze; LIU Xingyuan

doi:10.37188/CJL.20230050

您当前的位置：

首页 >

文章列表页 >

Effect of Aqueous Electrolyte Ions on Electrochromic Properties of Amorphous WO₃

Synthesis and Properties of Materials | 更新时间：2023-09-06

- Effect of Aqueous Electrolyte Ions on Electrochromic Properties of Amorphous WO₃
  增强出版
- Chinese Journal of Luminescence Vol. 44, Issue 8, Pages: 1404-1412(2023)
- 作者机构：
  
  1.中国科学院长春光学精密机械与物理研究所发光学及应用国家重点实验室，吉林长春　130033
  2.中国科学院大学，北京　100049
  3.吉林大学数学学院，吉林长春　130012
- 作者简介：
- 基金信息：
  
  Outstanding Young Scientific and Technological Talents Project of Jilin Province （Applied Technology）(20230508109RC);National Natural Science Foundation of China(61875195)
- DOI：10.37188/CJL.20230050
  CLC：
扫描看全文
邢开笑,吕哲,李颜涛等.水系电解质离子对无定形WO₃电致变色性能的影响[J].发光学报,2023,44(08):1404-1412.

XING Kaixiao,LYU Zhe,LI Yantao,et al.Effect of Aqueous Electrolyte Ions on Electrochromic Properties of Amorphous WO₃[J].Chinese Journal of Luminescence,2023,44(08):1404-1412.
邢开笑,吕哲,李颜涛等.水系电解质离子对无定形WO₃电致变色性能的影响[J].发光学报,2023,44(08):1404-1412. DOI： 10.37188/CJL.20230050.

XING Kaixiao,LYU Zhe,LI Yantao,et al.Effect of Aqueous Electrolyte Ions on Electrochromic Properties of Amorphous WO₃[J].Chinese Journal of Luminescence,2023,44(08):1404-1412. DOI： 10.37188/CJL.20230050.

摘要

WO,3,是理想的无机电致变色材料，其电致变色机制是在电压作用下发生可逆的氧化还原反应，并伴随着电解质离子在材料内部的嵌入和脱出。本文研究了含有Li,+,、Zn,2+,、Al,3+,的三种水系电解质对无定形WO,3,电致变色性能的影响。结果表明，当以Al,3+ ,作为嵌入离子时，WO,3,获得了最好的电致变色性能，包括快响应速度（着色响应时间2.8 s，褪色响应时间1.1 s）、大光学对比度（700 nm处达83.4%）、优异的循环稳定性（连续循环 1 000次仅衰减2.8%）、高着色效率（74.7 cm,2,·C,-1,），其综合性能在已报道的WO,3,电致变色器件中处于较高水平。机制研究发现，Al,3+,水系电解质溶液中性能的提升得益于快速的离子传输动力学。这些结果将为高性能电致变色器件构建和电解质优选提供简单有效的指导。

Abstract

WO,3, is an ideal inorganic electrochromic material. Its electrochromic mechanism is reversible redox reaction under the driving of voltage， accompanied by the insertion and extraction of counterions in the material. In this paper， we investigated the electrochromic properties of amorphous WO,3, in three aqueous electrolyte solutions of Li， Zn and Al. WO,3, achieves the best electrochromic performances when Al,3+, was used as insertion ions， including fast response speed （2.8 s for coloring and 1.1 s for decolorization）， large optical contrast （83.4% at 700 nm）， good cycling stability （2.8% decay for 1 000 successive cycles）， high coloration efficiency （74.7 cm,2,·C,-1,）， and its comprehensive performance is at high level among the reported WO,3, electrochromic devices. Mechanistic studies have revealed that the enhanced performance in Al,3+, electrolytes is due to the fast ion transport kinetics. These results will provide a simple and effective guidance for the construction of high-performance electrochromic devices and the optimization of electrolytes.

关键词

电致变色WO3水系电解质稳定性无定形

Keywords

electrochromicWO3aqueous electrolytesstabilityamorphous

references

GRANQVIST C G， ARVIZU M A， PEHLIVAN İ B， et al. Electrochromic materials and devices for energy efficiency and human comfort in buildings： a critical review ［J］. Electrochim. Acta， 2018， 259： 1170-1182. doi: 10.1016/j.electacta.2017.11.169http://dx.doi.org/10.1016/j.electacta.2017.11.169

GRANQVIST C G. Electrochromics for smart windows： oxide-based thin films and devices ［J］. Thin Solid Films， 2014， 564： 1-38. doi: 10.1016/j.tsf.2014.02.002http://dx.doi.org/10.1016/j.tsf.2014.02.002

CAI G F， EH A L S， JI L， et al. Recent advances in electrochromic smart fenestration ［J］. Adv. Sustainable Syst.， 2017， 1（12）： 1700074. doi: 10.1002/adsu.201700074http://dx.doi.org/10.1002/adsu.201700074

GU C， JIA A B， ZHANG Y M， et al. Emerging electrochromic materials and devices for future displays ［J］. Chem. Rev.， 2022， 122（18）： 14679-14721. doi: 10.1021/acs.chemrev.1c01055http://dx.doi.org/10.1021/acs.chemrev.1c01055

YU H T， SHAO S， YAN L J， et al. Side-chain engineering of green color electrochromic polymer materials： toward adaptive camouflage application ［J］. J. Mater. Chem. C， 2016， 4（12）： 2269-2273. doi: 10.1039/c6tc00197ahttp://dx.doi.org/10.1039/c6tc00197a

WEN R T， GRANQVIST C G， NIKLASSON G A. Eliminating degradation and uncovering ion-trapping dynamics in electrochromic WO3 thin films ［J］. Nat. Mater.， 2015， 14（10）： 996-1001. doi: 10.1038/nmat4368http://dx.doi.org/10.1038/nmat4368

DONG W J， LV Y， ZHANG N， et al. Trifunctional NiO-Ag-NiO electrodes for ITO-free electrochromic supercapacitors ［J］. J. Mater. Chem. C， 2017， 5（33）： 8408-8414. doi: 10.1039/c7tc03120chttp://dx.doi.org/10.1039/c7tc03120c

CAO S， ZHANG S L， ZHANG T R， et al. A visible light-near-infrared dual-band smart window with internal energy storage ［J］. Joule， 2019， 3（4）： 1152-1162. doi: 10.1016/j.joule.2018.12.010http://dx.doi.org/10.1016/j.joule.2018.12.010

THAKUR V K， DING G Q， MA J， et al. Hybrid materials and polymer electrolytes for electrochromic device applications ［J］. Adv. Mater.， 2012， 24（30）： 4071-4096. doi: 10.1002/adma.201200213http://dx.doi.org/10.1002/adma.201200213

WAGEMAKER M， KENTGENS A P M， MULDER F M. Equilibrium lithium transport between nanocrystalline phases in intercalated TiO2 anatase ［J］. Nature， 2002， 418（6896）： 397-399. doi: 10.1038/nature00901http://dx.doi.org/10.1038/nature00901

YAO Y J， ZHAO Q， WEI W， et al. WO3 quantum-dots electrochromism ［J］. Nano Energy， 2020， 68： 104350-1-8. doi: 10.1016/j.nanoen.2019.104350http://dx.doi.org/10.1016/j.nanoen.2019.104350

YOO S J， LIM J W， SUNG Y E， et al. Fast switchable electrochromic properties of tungsten oxide nanowire bundles ［J］. Appl. Phys. Lett.， 2007， 90（17）： 173126-1-3. doi: 10.1063/1.2734395http://dx.doi.org/10.1063/1.2734395

LI F， MA D Y， QIAN J H， et al. One-step hydrothermal growth and electrochromic properties of highly stable prussian green film and device ［J］. Sol. Energy Mater. Sol. Cells， 2019， 192： 103-108. doi: 10.1016/j.solmat.2018.12.024http://dx.doi.org/10.1016/j.solmat.2018.12.024

DING Y L， WANG M Y， MEI Z Y， et al. Different ion-based electrolytes for electrochromic devices： a review ［J］. Sol. Energy Mater. Sol. Cells， 2022， 248： 112039-1-5. doi: 10.1016/j.solmat.2022.112037http://dx.doi.org/10.1016/j.solmat.2022.112037

WU W T， WU L Q， MA H L， et al. Electrochromic devices constructed with water-in-salt electrolyte enabling energy-saving and prolonged optical memory effect ［J］. Chem. Eng. J.， 2022， 446： 137122-1-9. doi: 10.1016/j.cej.2022.137122http://dx.doi.org/10.1016/j.cej.2022.137122

TIAN Y Y， ZHANG W K， CONG S， et al. Unconventional aluminum ion intercalation/deintercalation for fast switching and highly stable electrochromism ［J］. Adv. Funct. Mater.， 2015， 25（36）： 5833-5839. doi: 10.1002/adfm.201502638http://dx.doi.org/10.1002/adfm.201502638

XIAO L L， LV Y， DONG W J， et al. Dual-functional WO3 nanocolumns with broadband antireflective and high-performance flexible electrochromic properties ［J］. ACS Appl. Mater. Interfaces， 2016， 8（40）： 27107-27114. doi: 10.1021/acsami.6b08895http://dx.doi.org/10.1021/acsami.6b08895

张观广，倪浩智，张啸尘，等. 旋涂法制备WO3薄膜电致变色性能［J］. 发光学报， 2019， 40（2）： 183-188. doi: 10.3788/fgxb20194002.0183http://dx.doi.org/10.3788/fgxb20194002.0183

ZHANG G G， NI H Z， ZHANG X C， et al. Electrochromic properties of WO3 film by spin-coating ［J］. Chin. J. Lumin.， 2019， 40（2）： 183-188. （in Chinese）. doi: 10.3788/fgxb20194002.0183http://dx.doi.org/10.3788/fgxb20194002.0183

WANG J H， SHAO J D， YI K， et al. Layer uniformity of glancing angle deposition ［J］. Vacuum， 2005， 78（1）： 107-111. doi: 10.1016/j.vacuum.2004.12.019http://dx.doi.org/10.1016/j.vacuum.2004.12.019

刘岩，吕营，何龙桂，等. 新型无铟透明导电-电致变色双功能MoO3/Ag/MoO3薄膜的制备及性能研究［J］. 发光学报， 2016， 37（2）： 187-191. doi: 10.3788/fgxb20163702.0187http://dx.doi.org/10.3788/fgxb20163702.0187

LIU Y， LYU Y， HE L G， et al. Preparation and properties of new type of transparent conductive and electrochromic bi-functional indium-free MoO3/Ag/MoO3 thin films ［J］. Chin. J. Lumin.， 2016， 37（2）： 187-191. （in Chinese）. doi: 10.3788/fgxb20163702.0187http://dx.doi.org/10.3788/fgxb20163702.0187

GUO J J， WANG M， DIAO X G， et al. Prominent electrochromism achieved using aluminum ion insertion/extraction in amorphous WO3 films ［J］. J. Phys. Chem. C， 2018， 122（33）： 19037-19043. doi: 10.1021/acs.jpcc.8b05692http://dx.doi.org/10.1021/acs.jpcc.8b05692

LI H L， LV Y， ZHANG X， et al. High-performance ITO-free electrochromic films based on bi-functional stacked WO3/Ag/WO3 structures ［J］. Sol. Energy Mater. Sol. Cells， 2015， 136： 86-91. doi: 10.1016/j.solmat.2015.01.002http://dx.doi.org/10.1016/j.solmat.2015.01.002

WEN R T， MALMGREN S， GRANQVIST C G， et al. Degradation dynamics for electrochromic WO3 films under extended charge insertion and extraction： unveiling physicochemical mechanisms ［J］. ACS Appl. Mater. Interfaces， 2017， 9（14）： 12872-12877. doi: 10.1021/acsami.7b01324http://dx.doi.org/10.1021/acsami.7b01324

Views

下载量

CSCD

Alert me when the article has been cited

提交

Tools

Publicity Resources

Flexible Reflectance-type Electrochromic Devices Based on Cr/Ag/WO₃ Thin Films

Progress of Two-dimensional Perovskite Solar Cells Based on Aromatic Organic Spacers

Degradation Mechanism of Organic Light-emitting Diodes

Related Author

No data

Related Institution

Institute of Polymer Chemistry， College of Chemistry， Nankai University

State Key Laboratory of Luminescent Materials and Devices， South China University of Technology

State Key Laboratory for Artificial Microstructures and Mesoscopic Physics， Department of Physics， Peking University

College of Physics and Electronic Engineering， Taishan University， Taian

College of Optical and Electronic Technology， China Jiliang University

Address：No.3888 Dong Nanhu Road, Changchun, Jilin, China Postal code：130033
Tel：0431-86176862 Email：fgxbt@126.com
Technical support is provided by Beijing Founder electronics co., LTD 吉ICP备11002662号-17 京公网安备11010802024621
It is recommended to read the content of this site in Chrome&IE9+. Please switch to extreme mode in browser 360.
Cookies We use cookies to help provide and enhance our service and tailor content. By continuing, you agree to the use of cookies.

⁰

Effect of Aqueous Electrolyte Ions on Electrochromic Properties of Amorphous WO3

DOI：10.37188/CJL.20230050

摘要

Abstract

关键词

Keywords

references

Effect of Aqueous Electrolyte Ions on Electrochromic Properties of Amorphous WO₃