Calculation and Prediction of Quenching Concentration of Er<sup>3+</sup>-doped Germanate Glass

WAN Jie; OUYANG Sha; JI Yao; DUAN Taiyu; WANG Weichao

doi:10.37188/CJL.20230014

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Calculation and Prediction of Quenching Concentration of Er³⁺-doped Germanate Glass

Theoretical Calculation and Spectral Analysis | 更新时间：2023-10-27

- Calculation and Prediction of Quenching Concentration of Er³⁺-doped Germanate Glass
  增强出版
- Chinese Journal of Luminescence Vol. 44, Issue 6, Pages: 1032-1041(2023)
- 作者机构：
  
  华南理工大学物理与光电学院，发光材料与器件国家重点实验室，广东省光纤激光材料与应用技术重点实验室，广东广州　510640
- 作者简介：
- 基金信息：
  
  National Natural Science Foundation ofChina(52172003)
- DOI：10.37188/CJL.20230014
  CLC： O482.31
- Published：05 June 2023，
  
  Received：28 January 2023，
  
  Revised：10 February 2023，
- 稿件说明：
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万杰,欧阳莎,姬瑶等.Er³⁺掺杂锗酸盐激光玻璃猝灭浓度的计算与预测[J].发光学报,2023,44(06):1032-1041.

WAN Jie,OUYANG Sha,JI Yao,et al.Calculation and Prediction of Quenching Concentration of Er³⁺-doped Germanate Glass[J].Chinese Journal of Luminescence,2023,44(06):1032-1041.
万杰,欧阳莎,姬瑶等.Er³⁺掺杂锗酸盐激光玻璃猝灭浓度的计算与预测[J].发光学报,2023,44(06):1032-1041. DOI： 10.37188/CJL.20230014.

WAN Jie,OUYANG Sha,JI Yao,et al.Calculation and Prediction of Quenching Concentration of Er³⁺-doped Germanate Glass[J].Chinese Journal of Luminescence,2023,44(06):1032-1041. DOI： 10.37188/CJL.20230014.

摘要

稀土掺杂激光玻璃光纤是光纤激光器的核心增益介质，其中稀土离子掺杂浓度是决定激光玻璃增益特性的重要参数，如何快速有效地确定最佳掺杂浓度是稀土掺杂激光玻璃光纤的关键科学问题之一。本文以Er

掺杂锗酸盐激光玻璃为例，利用Er

：

13/2

→

15/2

跃迁的自发辐射跃迁寿命和实测寿命，预测了锗酸盐激光玻璃的猝灭浓度。研究表明，在该玻璃体系中，理论预测与实际值的最大绝对误差小于0.4%。对比唯象模型和有限扩散模型分别拟合多个样品发光强度和实测寿命确定猝灭浓度的方法，本文提出的方法仅需通过少量样品的测试参数即可确定激光玻璃猝灭浓度，简单快捷且计算误差小，对高增益激光玻璃与光纤研究具有指导意义。

Abstract

Rare-earth doped laser glass fiber is the core gain medium of fiber laser.The concentration of the rare-earth ions is one of the important parameters to determine the gain characteristics of laser glass. How to determine the quenching concentration（QC） of laser glass quickly and effectively is a key scientific problem. In this paper， the QC of Er

-doped germanate glass is predicted by using the spontaneous emission lifetime and the measured lifetime of the Er

：

13/2

→

15/2

transition. The results show that the maximum absolute error between the theoretical prediction and the actual value is less than 0.4%. Compared with the phenomenological model and finite diffusion model to determine the QC by fitting the luminescent intensity and measured lifetime of multiple experimental samples， our proposed method can determine the QC of laser glass by the test parameters of one or two samples， which is simple， fast and has little calculation error. It has a guiding significance for the research of high-gain laser glass and optical fiber.

关键词

锗酸盐玻璃稀土离子Er3+猝灭浓度理论计算

Keywords

germanate glassrare-earth ionsEr3+quenching concentrationtheoretical calculation

references

WANG W C， ZHOU B， XU S H， et al. Recent advances in soft optical glass fiber and fiber lasers ［J］. Prog. Mater. Sci.， 2019， 101： 90-171. doi: 10.1016/j.pmatsci.2018.11.003http://dx.doi.org/10.1016/j.pmatsci.2018.11.003

ZERVAS M N， CODEMARD C A. High power fiber lasers： a review ［J］. IEEE J. Sel. Top. Quant. Electron.， 2014， 20（5）： 0904123-1-23. doi: 10.1109/jstqe.2014.2321279http://dx.doi.org/10.1109/jstqe.2014.2321279

张炳涛，陈月娥，赵兹罡，等. 有源光纤的进展与应用［J］. 应用物理， 2018， 8（5）： 256-268. doi: 10.12677/APP.2018.85032http://dx.doi.org/10.12677/APP.2018.85032

ZHANG B T， CHEN Y E， ZHAO Z G， et al. Progress and applications of active optical Fibers ［J］. Appl. Phys.， 2018， 8（5）： 256-268. （in Chinese）. doi: 10.12677/APP.2018.85032http://dx.doi.org/10.12677/APP.2018.85032

SNOEKS E， KIK P G， POLMAN A. Concentration quenching in erbium implanted alkali silicate glasses ［J］. Opt. Mater.， 1996， 5（3）： 159-167. doi: 10.1016/0925-3467(95)00063-1http://dx.doi.org/10.1016/0925-3467(95)00063-1

MYSLINSKI P， NGUYEN D， CHROSTOWSKI J. Effects of concentration on the performance of erbium-doped fiber amplifiers ［J］. J. Lightwave Technol.， 1997， 15（1）： 112-120. doi: 10.1109/50.552118http://dx.doi.org/10.1109/50.552118

HOUDE-WALTER S N， PETERS P M， STEBBINS J F， et al. Hydroxyl-contents and hydroxyl-related concentration quenching in erbium-doped aluminophosphate， aluminosilicate and fluorosilicate glasses ［J］. J. Non. Cryst. Solids， 2001， 286（1-2）： 118-131. doi: 10.1016/s0022-3093(00)00445-2http://dx.doi.org/10.1016/s0022-3093(00)00445-2

VAN UITERT L G. Characterization of energy transfer interactions between rare earth ions ［J］. J. Electrochem. Soc.， 1967， 114（10）： 1048. doi: 10.1149/1.2424184http://dx.doi.org/10.1149/1.2424184

AUZEL F， BONFIGLI F， GAGLIARI S， et al. The interplay of self-trapping and self-quenching for resonant transitions in solids； role of a cavity ［J］. J. Lumin.， 2001， 94-95： 293-297. doi: 10.1016/s0022-2313(01)00308-8http://dx.doi.org/10.1016/s0022-2313(01)00308-8

AUZEL F， BALDACCHINI G， LAVERSENNE L， et al. Radiation trapping and self-quenching analysis in Yb3+， Er3+， and Ho3+ doped Y2O3 ［J］. Opt. Mater.， 2003， 24（1-2）： 103-109. doi: 10.1016/s0925-3467(03)00112-5http://dx.doi.org/10.1016/s0925-3467(03)00112-5

PUGLIESE D， BOETTI N G， LOUSTEAU J， et al. Concentration quenching in an Er-doped phosphate glass for compact optical lasers and amplifiers ［J］. J. Alloys Compd.， 2016， 657： 678-683. doi: 10.1016/j.jallcom.2015.10.126http://dx.doi.org/10.1016/j.jallcom.2015.10.126

GEBAVI H， MILANESE D， LIAO G H， et al. Spectroscopic investigation and optical characterization of novel highly thulium doped tellurite glasses ［J］. J. Non Cryst. Solids， 2009， 355（9）： 548-555. doi: 10.1016/j.jnoncrysol.2009.01.016http://dx.doi.org/10.1016/j.jnoncrysol.2009.01.016

RAVAGL A， BOETTI N G， CRUZ F A G， et al. Structural and spectral characterisation of Er3+ and Nd3+ doped Ga-La-S-Se glasses ［J］. RSC Adv.， 2018， 8（48）： 27556-27564.

黄莉蕾，陈继勤，赵渭忠，等. RE∶YAG晶体中掺杂离子（Ho， Nd， Tm）的最佳浓度［J］. 量子电子学， 1995， 12（2）： 227-231.

HUANG L L， CHEN J Q， ZHAO W Z， et al. The optimal concentrations of doped rare-earth ions Nd， Ho， Tm in RE∶ YAG crystals ［J］. Chin. J. Quant. Electron.， 1995， 12（2）： 227-231. （in Chinese）

黄莉蕾，陈晓竹. 激光晶体YAG中Er3+离子最佳掺杂浓度［J］. 中国计量学院学报， 1996（2）： 15-20.

HUANG L L， CHEN X Z. Optimal concentrations doped Er3+ ions in YAG laser crystal ［J］. J. China Inst. Metrol.， 1996（2）： 15-20. （in Chinese）

胡晓，洪方煜，邬良能. 四能级和准四能级激活离子的最佳掺杂浓度［J］. 物理学报， 2002， 51（9）： 2002-2010. doi: 10.7498/aps.51.2002http://dx.doi.org/10.7498/aps.51.2002

HU X， HONG F Y， WU L N. Optimal concentration of active particles in four-level and quasi-four-level laser systems ［J］. Acta Phys. Sinica， 2002， 51（9）： 2002-2010. （in Chinese）. doi: 10.7498/aps.51.2002http://dx.doi.org/10.7498/aps.51.2002

徐淑君，陈静，陈礼元，等. 效应面优化模型获取Y4GeO8∶Bi3+，Eu3+红色荧光粉掺杂浓度［J］. 发光学报， 2022， 43（5）： 633-641. doi: 10.37188/cjl.20220021http://dx.doi.org/10.37188/cjl.20220021

XU S J， CHEN J， CHEN L Y， et al. Optimal doping content of red emitting Y4GeO8∶Bi3+，Eu3+ phosphor designed by response surface methodology ［J］. Chin. J. Lumin.， 2022， 43（5）： 633-641. （in Chinese）. doi: 10.37188/cjl.20220021http://dx.doi.org/10.37188/cjl.20220021

WEN X， TANG G W， YANG Q， et al. Highly Tm3+ doped germanate glass and its single mode fiber for 2.0 μm laser ［J］. Sci. Rep.， 2016， 6： 20344-1-10. doi: 10.1038/srep20344http://dx.doi.org/10.1038/srep20344

LIPINSKA K， CAVALLO F， AYITOU A J L， et al. Quench-free enhanced emission in cluster-free Er-doped heavy metal oxide glasses ［J］. Opt. Mater. Express， 2019， 9（3）： 1072-1084. doi: 10.1364/ome.9.001072http://dx.doi.org/10.1364/ome.9.001072

房喻，王辉. 荧光寿命测定的现代方法与应用［J］. 化学通报， 2001， 64（10）： 631-636. doi: 10.3969/j.issn.0441-3776.2001.10.006http://dx.doi.org/10.3969/j.issn.0441-3776.2001.10.006

FANG Y， WANG H. Fluorescence lifetime measurements： modern methods and applications ［J］. Chemistry， 2001， 64（10）： 631-636. （in Chinese）. doi: 10.3969/j.issn.0441-3776.2001.10.006http://dx.doi.org/10.3969/j.issn.0441-3776.2001.10.006

CAMPBELL J H， SURATWALA T I. Nd-doped phosphate glasses for high-energy/high-peak-power lasers ［J］. J. Non. Cryst. Solids， 2000， 263-264： 318-341. doi: 10.1016/s0022-3093(99)00645-6http://dx.doi.org/10.1016/s0022-3093(99)00645-6

刘永皓，徐权. 不同Er3+离子掺杂浓度下硼铋酸盐玻璃荧光浓度猝灭研究［J］. 齐齐哈尔大学学报， 2010， 26（2）： 41-45. doi: 10.3969/j.issn.1007-984X.2010.02.011http://dx.doi.org/10.3969/j.issn.1007-984X.2010.02.011

LIU Y H， XU Q. The effect of Er3+ concentrations on the fluorescence concentration quenching in bismuth borate glasses ［J］. J. Qiqihar Univ.， 2010， 26（2）： 41-45. （in Chinese）. doi: 10.3969/j.issn.1007-984X.2010.02.011http://dx.doi.org/10.3969/j.issn.1007-984X.2010.02.011

RISEBERG L A， MOOS H W. Multiphonon orbit-lattice relaxation of excited states of rare-earth ions in crystals ［J］. Phys. Rev.， 1968， 174（2）： 429-438. doi: 10.1103/physrev.174.429http://dx.doi.org/10.1103/physrev.174.429

INOKUTI M， HIRAYAMA F. Influence of energy transfer by the exchange mechanism on donor luminescence ［J］. J. Chem. Phys.， 1965， 43（6）： 1978-1989. doi: 10.1063/1.1697063http://dx.doi.org/10.1063/1.1697063

BURSHTEIN A I. Hopping mechanism of energy transfer ［J］. Sov. J. Exp. Theor. Phys.， 1972， 35（5）： 882-885.

CARNALL W T， FIELDS P R， WYBOURNE B G. Spectral intensities of the trivalent lanthanides and actinides in solution. I. Pr3+， Nd3+， Er3+， Tm3+， and Yb3+ ［J］. J. Chem. Phys.， 1965， 42（11）： 3797-3806. doi: 10.1063/1.1695840http://dx.doi.org/10.1063/1.1695840

KESAVULU C R， SREEDHAR V B， JAYASANKAR C K， et al. Structural， thermal and spectroscopic properties of highly Er3+-doped novel oxyfluoride glasses for photonic application ［J］. Mater. Res. Bull.， 2014， 51： 336-344. doi: 10.1016/j.materresbull.2013.12.023http://dx.doi.org/10.1016/j.materresbull.2013.12.023

ZHAO Y G， SHI D M. Effect of alkali metal oxides R2O（R=Na， K） on 1.53 μm luminescence of Er3+-doped Ga2O3-GeO2 glasses for optical amplification ［J］. J. Rare Earths， 2013， 31（9）： 857-863. doi: 10.1016/s1002-0721(12)60370-6http://dx.doi.org/10.1016/s1002-0721(12)60370-6

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Related Author

WAN Jie

OUYANG Sha

JI Yao

DUAN Taiyu

WANG Weichao

WAN Jie

WANG Weichao

ZHAO Cheng-zhou

Related Institution

State Key Laboratory of Luminescent Materials and Devices， Guangdong Provincial Key Laboratory ofFiber Laser Materials and Applied Techniques， School of Physics and Optoelectronics， South China University of Technology

University of Chinese Academy of Sciences, Beijing 100049, China

State Key Laboratory of Luminescence and Applications, Changchun Institute of Optics, Fine Mechanics and Physics, Chinese Academy of Sciences, Changchun 130033, China

Key Laboratory of Rare Earth Optoelectronic Materials and Deices of Zhejiang Province， Institute of Optoelectronic Materials and Devices， College of Optical and Electronic Technology， China Jiliang University

Department of Physics， University of Science and Technology of China

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Calculation and Prediction of Quenching Concentration of Er3+-doped Germanate Glass

DOI：10.37188/CJL.20230014

摘要

Abstract

关键词

Keywords

references

Calculation and Prediction of Quenching Concentration of Er³⁺-doped Germanate Glass